# US 10,311,760 B1 · Infrared ink labeling system

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- Number: US 10,311,760 B1
- Document ID: US10311760B1
- Status: Granted
- Kind: B1
- Application number: 15/707,933
- Filed: 2017-09-18
- Granted: 2019-06-04
- Earliest claimed: 2017-05-31
- Assignees: Amazon Technologies, Inc.
- Applicants: Amazon Technologies, Inc.
- Inventors: Nicholas Charles McMahon; Tomer Anor; Jeremy Samuel De Bonet; Oded Maron
- Web page: https://patentgrep.com/patent/US10311760B1

## CPC

- G09F 3/0297: {including a machine-readable marking, e.g. a bar code (digitally marked record carriers in general G06K19/00)}
- B41J 2/02: generating a continuous ink jet
- B41J 2/2107: {characterised by the ink properties (supplying ink in a solid state B41J2/17593)}
- B41J 2/2114: {Ejecting specialized liquids, e.g. transparent or processing liquids (B41J2/211 takes precedence)}
- B41J 3/4075: {Tape printers; Label printers}
- B41M 3/14: Security printing {(securities B42D25/29)}
- B41M 3/144: {using fluorescent, luminescent or iridescent effects}
- C09D 11/10: based on artificial resins
- C09D 11/322: Pigment inks
- C09D 11/328: characterised by dyes
- G06Q 10/08: Logistics, e.g. warehousing, loading or distribution; Inventory or stock management
- G09F 2003/0213: {Concealed data}
- G09F: DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41M: PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING, (correction of typographical errors B41J; processes for applying transfer pictures or the like B44C1/16; fluid media for correction of typographical errors by coating C09D10/00; printing textiles D06P)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- G06Q: INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR

## Abstract

An ink that is detectable using infrared (IR) light may be used to apply machine readable codes, such as a barcode. The indicia, once applied, may be either invisible or difficult to detect with visible light, such as with the human eye. The ink may include one or more materials such as titanium dioxide (TiO2), particles of acrylonitrile butadiene styrene (ABS), metals, and so forth. These materials may be used to enhance one or more of the reflectivity to IR light or the fluorescence of the ink under IR light. The fluorescent ink may be deposited in a single pass, or as part of a two-pass process in which a reflective substrate, such as a resin with encapsulated TiO2, is applied and then the fluorescent ink is deposited atop the substrate. The markings are machine readable even when overprinting markings that are readable under visible light.

## Claims

### Claim 1

A system comprising:
a continuous inkjet printer configured to produce a mark with a single pass using an ink, the ink comprising:
a dye that upon excitation at a wavelength of between 800 nanometers and 830 nanometers fluoresces at a wavelength of between 840 and 860 nanometers;
rutile titanium dioxide particles that reflect infrared light with a wavelength of between 800 and 870 nanometers; and
a first computing device comprising:
a first memory, storing first computer-executable instructions; and
a hardware processor to execute the first computer-executable instructions to:
direct the continuous inkjet printer to print the mark on an item using the ink.

### Claim 2 (depends on 1)

The system of claim 1, wherein the titanium dioxide particles have an average size of between 405 nm and 425 nm.

### Claim 3 (depends on 1)

The system of claim 1, the ink further comprising a resin.

### Claim 4 (depends on 1)

The system of claim 1, wherein the rutile titanium dioxide particles are encapsulated within a polymer.

### Claim 5

A system comprising:
an ink comprising:
a dye that upon excitation at a wavelength of between 800 nanometers and 830 nanometers fluoresces at a wavelength of between 840 and 860 nanometers;
a first material that reflects infrared light with a wavelength of between 800 and 870 nanometers, wherein the first material comprises particles having an average size of between 405 nm and 425 nm;
a tank to contain the ink;
a first device to deposit the ink on a surface of an item; and
a first computing device comprising:
a first memory, storing first computer-executable instructions; and
a hardware processor to execute the first computer-executable instructions to:
direct the first device to form a mark on the item using the ink.

### Claim 6 (depends on 5)

The system of claim 5, wherein the first material comprises titanium dioxide.

### Claim 7 (depends on 5)

The system of claim 5, the ink further comprising a resin.

### Claim 8 (depends on 5)

The system of claim 5, wherein the first material comprises one or more metals.

### Claim 9 (depends on 5)

The system of claim 5, wherein the first device comprises one or more of:
a continuous inkjet printhead, or
a drop-on-demand printhead.

### Claim 10 (depends on 5)

The system of claim 5, further comprising:
a second device to deposit a reflective material on the surface of the item;
a computing device in communication with the first device and a second device, wherein the computing device directs the second device to deposit the reflective material on the surface of the item and then directs the first device to deposit the ink on top of the reflective material.

### Claim 11 (depends on 10)

The system of claim 10, wherein the reflective material comprises one or more of:
titanium dioxide particles encapsulated within a polymer, or
a mixed metal oxide encapsulated within the polymer.

### Claim 12 (depends on 10)

The system of claim 10, the second device comprising one or more of:
a spray nozzle to spray the reflective material onto the surface of the item; or
a roller comprising a roller frame that supports a roller cover, wherein the roller cover rotates with respect to the roller frame, absorbs at least a portion of the reflective material, and transfers at least a portion of the reflective material to the surface of the item.

### Claim 13

A method comprising:
placing ink on a surface of an item, the ink comprising:
a dye that fluoresces to emit photons in a first range of wavelengths when excited by incident photons at a second range of wavelengths; and
a reflective material that reflects at least some photons within each of the first range of wavelengths and the second range of wavelengths, wherein the reflective material comprises particles having an average size of between 405 nanometers and 425 nanometers.

### Claim 14 (depends on 13)

The method of claim 13, wherein the first range of wavelengths extends from 840 nanometers to 860 nanometers and the second range of wavelengths extends from 800 to 830 nanometers; and wherein the ink, after placement on the surface of the item, exhibits a transmittance of greater than 80% to visible light.

### Claim 15 (depends on 13)

The method of claim 13, wherein the dye exhibits an excitation wavelength that differs from the emission wavelength by at least 30 nanometers.

### Claim 16 (depends on 13)

The method of claim 13, wherein the reflective material comprises titanium dioxide.

### Claim 17 (depends on 13)

The method of claim 13, the ink further comprising a resin.

### Claim 18 (depends on 13)

The method of claim 13, wherein the reflective material comprises one or more metals.

### Claim 19 (depends on 13)

The method of claim 13, further comprising:
placing, before the ink, a second reflective material on the surface of the item; and
wherein at least a portion of the ink is placed atop the reflective material.

### Claim 20 (depends on 19)

The method of claim 19, wherein the second reflective material comprises titanium dioxide.