# US 10,310,352 B2 · Electrochromic system containing an insulating protective layer and method for controlling photochromic darkening

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- Number: US 10,310,352 B2
- Document ID: US10310352B2
- Status: Granted
- Kind: B2
- Application number: 15/418,083
- Filed: 2017-01-27
- Published: 2017-08-03
- Granted: 2019-06-04
- Earliest claimed: 2016-02-01
- Assignees: Heliotrope Technologies, Inc.
- Applicants: Heliotrope Technologies, Inc.
- Inventors: Guillermo Garcia; Sourav Basu; Jason Holt
- Web page: https://patentgrep.com/patent/US10310352B2

## CPC

- G02F 1/163: Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
- G02F 1/1508: {using a solid electrolyte}
- G02F 1/1533: {structural features not otherwise provided for}
- G02F 1/157: Structural association of cells with optical devices, e.g. reflectors or illuminating devices
- G02F 2201/346: distributed (Bragg) reflector
- G02F 2203/055: wavelength filtering
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS

## Abstract

An electrochromic system and method for controlling photochromic darkening of an electrochromic device, the system including an EC device, a control unit, a voltage detector, and a power supply. The EC device includes a working electrode, a counter electrode, a solid-state polymer electrolyte disposed therebetween, and an ionically conductive and electrically insulating protective layer disposed between the electrolyte and the working electrode. The control unit is configured to control a sweep voltage applied between the working and counter electrodes, such that the sweep voltage is applied when an open circuit voltage (OCV) between the working and counter electrodes is less than a threshold voltage.

## Claims

### Claim 1

An electrochromic (EC) system comprising:
an EC device comprising:
a light transmissive first substrate;
a working electrode disposed over the first substrate;
a counter electrode;
a solid state electrolyte disposed between the counter electrode and the working electrode;
a light transmissive second substrate disposed over the counter electrode; and
an ionically conductive and electrically insulating protective layer disposed between the electrolyte and the working electrode; and
a control unit configured to selectively apply a sweep voltage between the working and counter electrodes, such that the sweep voltage is applied when an open circuit voltage (OCV) between the working and counter electrodes is less than a threshold voltage.

### Claim 2 (depends on 1)

The EC system of claim 1, wherein the protective layer comprises tantalum oxide.

### Claim 3 (depends on 1)

The EC system of claim 1, wherein the protective layer comprises tantalum pentoxide (Ta2O5).

### Claim 4 (depends on 1)

The EC system of claim 1, further comprising a voltage detector configured to detect the OCV,
wherein the control unit is configured to apply the sweep voltage when the voltage detector detects that the OCV is below the threshold voltage.

### Claim 5 (depends on 1)

The EC system of claim 1, wherein the threshold voltage is between 0V and −2V, and the sweep voltage is a positive voltage.

### Claim 6 (depends on 1)

The EC system of claim 1, wherein the control unit is configured to:
determine an amount of time since a voltage was applied to the EC device to change a transmissivity thereof; and
apply the sweep voltage to the EC device, if determined amount of time exceeds a threshold time period.

### Claim 7 (depends on 1)

The EC system of claim 1, wherein the control unit is configured to periodically apply the sweep voltage between the working and counter electrodes, such that a open circuit voltage between the working and counter electrodes is changed from a negative voltage below the threshold voltage to a positive voltage.

### Claim 8 (depends on 1)

The EC system of claim 1, wherein the control unit is configured to:
control the sweep voltage, such that the magnitude of the sweep voltage is greater than the magnitude of the OCV;
control the sweep voltage, such that the sweep voltage applies a saturation current ranging from about 10 to 30 μA/cm2 between the working and counter electrodes; and
control the sweep voltage, such that the sweep voltage is applied at a frequency ranging from about 1 day to about 3 days.

### Claim 9 (depends on 1)

The EC system of claim 1, wherein the control unit is configured to control the sweep voltage, such that the sweep voltage is applied only at night.

### Claim 10 (depends on 1)

The EC system of claim 1, wherein the control unit is configured to control the sweep voltage, such that the sweep voltage is applied only on weekends, on holidays, or on weekends and holidays.

### Claim 11 (depends on 1)

The EC system of claim 1, further comprising a power source electrically connected to the EC device and configured to generate the sweep voltage,
wherein the control unit is configured to control the power source to control the application of the sweep voltage.

### Claim 12 (depends on 1)

The EC system of claim 1, wherein the control unit is configured to control the sweep voltage, such that the sweep voltage ranges from about 0.5 volts to about 5 volts.

### Claim 13 (depends on 1)

The EC system of claim 1, further comprising a Bragg reflector configured to selectively reflect UV radiation away from the working electrode.