# US 10,310,333 B2 · Double-sided pressure-sensitive-adhesive-layer-attached polarizing film, and image display device

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- Number: US 10,310,333 B2
- Document ID: US10310333B2
- Status: Granted
- Kind: B2
- Application number: 15/579,645
- Filed: 2016-06-14
- Published: 2018-06-07
- Granted: 2019-06-04
- Earliest claimed: 2015-06-15
- Assignees: Nitto Denko Corporation
- Applicants: Nitto Denko Corporation
- Inventors: Atsushi Yasui; Shou Takarada; Shinya Yamamoto; Ryohei Sawazaki
- Web page: https://patentgrep.com/patent/US10310333B2

## CPC

- C09J 7/22: Plastics; Metallised plastics
- B32B 27/00: Layered products comprising {a layer of} synthetic resin {(fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18)}
- B32B 27/30: comprising vinyl {(co)polymers; comprising acrylic (co)polymers}
- C09J 7/385: {Acrylic polymers}
- C09J 133/06: of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J 133/08: Homopolymers or copolymers of acrylic acid esters
- G02B 1/16: having an anti-static effect, e.g. electrically conducting coatings
- G02B 5/3016: {involving passive liquid crystal elements (optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528)}
- G02B 5/3033: {in the form of a thin sheet or foil, e.g. Polaroid}
- G02F 1/1333: Constructional arrangements; {Manufacturing methods}(G02F1/135, G02F1/136 take precedence)
- G02F 1/13338: {Input devices, e.g. touch panels}
- G02F 1/1335: Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F 1/133528: {Polarisers}
- G02F 1/133711: {by organic films, e.g. polymeric films}
- H10K 59/8791: {Arrangements for improving contrast, e.g. preventing reflection of ambient light}
- C09J 2203/318: for the production of liquid crystal displays
- C09J 2301/124: the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
- C09J 2433/00: Presence of (meth)acrylic polymer
- G02B 1/00: Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02F 2202/28: Adhesive materials or arrangements
- C09J: ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES (preparation of glue or gelatine C09H)
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES

## Abstract

A double-sided pressure-sensitive adhesive-layer-attached polarizing film has a polarizing film nearest to a viewer-side of an image display device among at least one polarizing film, a pressure-sensitive adhesive layer A located on the viewer-side, and a pressure-sensitive adhesive layer B on a side of the polarizing film that is opposite to the pressure-sensitive adhesive layer A. The pressure-sensitive adhesive layers A and B are equipped with separators SA and SB, respectively. The polarizing film is a single-side protected polarizing film having a polarizer of 15 μm or less thickness and having a transparent protective film on only a single side of the polarizer. The pressure-sensitive adhesive layer B is located on the polarizer side of the single-side protected polarizing film. The pressure-sensitive adhesive layer A has a thickness of 25 μm or more; and the pressure-sensitive adhesive layer B has a thickness of 25 μm or less.

## Claims

### Claim 1

A double-sided pressure-sensitive adhesive-layer-attached polarizing film, comprising a polarizing film nearest to a viewer-side of an image display device among at least one polarizing film used in the device, a pressure-sensitive adhesive layer A located on the viewer-side of the polarizing film, and a pressure-sensitive adhesive layer B on a side of the polarizing film that is opposite to the pressure-sensitive adhesive layer A, the pressure-sensitive adhesive layer A being equipped with a separator SA and the pressure-sensitive adhesive layer B being equipped with a separator SB;
wherein the polarizing film is a single-side protected polarizing film having a polarizer of 15 μm or less thickness and having a transparent protective film on only a single side of the polarizer, and the pressure-sensitive adhesive layer B is located on the polarizer side of the single-side protected polarizing film;
the pressure-sensitive adhesive layer A has a thickness of 25 μm or more; and
the pressure-sensitive adhesive layer B has a thickness of 25 μm or less.

### Claim 2 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the pressure-sensitive adhesive layer B is bonded directly to the polarizer of the single-side protected polarizing film.

### Claim 3 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the pressure-sensitive adhesive layer B is bonded to the polarizer of the single-side protected polarizing film to interpose a functional layer of 15 μm or less thickness between the layer B and the polarizer.

### Claim 4 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the pressure-sensitive adhesive layer A has a storage modulus of 0.05 MPa or more at 23° C.

### Claim 5 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the edge of the pressure-sensitive adhesive layer A is at least partially positioned inside an end side of the plane of the single-side protected polarizing film.

### Claim 6 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the separator SA is higher in peel strength than the separator SB.

### Claim 7 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the separator SA has a thickness of 40 μm or more, and further has a separator peel strength of 0.1 N/50-mm or more.

### Claim 8 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the transparent protective film of the single-side protected polarizing film, over this transparent protective film the pressure-sensitive adhesive layer A being laminated, is subjected to easy facilitating treatment.

### Claim 9 (depends on 1)

The double-sided pressure-sensitive-adhesive-layer-attached polarizing film according to claim 1, wherein the pressure-sensitive adhesive layer A and the pressure-sensitive adhesive layer B each is obtained from an acrylic pressure-sensitive adhesive comprising, as a base polymer, a (meth)acryl-based polymer containing, as a monomer unit, an alkyl (meth)acrylate;
the (meth)acryl-based polymer of the pressure-sensitive adhesive layer A comprises, as the monomer unit, 30% by weight or more of 2-ethylhexyl acrylate; and
the (meth)acryl-based polymer of the pressure-sensitive adhesive layer B comprises, as the monomer unit, butyl acrylate in a most proportion.

### Claim 10 (depends on 1)

The double-sided pressure-sensitive-adhesive-layer-attached polarizing film according to claim 1, wherein the pressure-sensitive adhesive layer A and the pressure-sensitive adhesive layer B each is obtained from an acrylic pressure-sensitive adhesive comprising, as a base polymer, a (meth)acryl-based polymer containing an alkyl (meth)acrylate as a monomer unit; and
at least one of the (meth) acryl-based polymer of the pressure-sensitive adhesive layer A, and the (meth) acryl-based polymer of the pressure-sensitive adhesive layer B comprises, as a monomer unit, at least one of (meth)acrylic acid and a cyclic nitrogen-containing monomer.

### Claim 11 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the pressure-sensitive adhesive layer A is a layer irradiated with an active energy ray to be increased in storage modulus.

### Claim 12 (depends on 1)

The double-sided pressure-sensitive adhesive-layer-attached polarizing film according to claim 1, wherein the pressure-sensitive adhesive layer A comprises an ultraviolet absorbent.

### Claim 13 (depends on 1)

An image display device, comprising at least one double-sided pressure-sensitive-adhesive-layer-attached polarizing films;
wherein the double-sided pressure-sensitive-adhesive-layer-attached polarizing film nearest to a viewer-side of an image display device among at least one polarizing film used in the device, is the double-sided-pressure-sensitive-adhesive-layer-attached polarizing film according to claim 1; and
the pressure-sensitive adhesive layer A of the double-sided pressure-sensitive-adhesive-layer-attached polarizing film is positioned at the viewer-side, and the pressure-sensitive adhesive layer B of the double-sided pressure-sensitive-adhesive-layer-attached polarizing film is positioned at a display section side of the device.

### Claim 14 (depends on 13)

The image display device according to claim 13, which is applied to an in-cell or on-cell touch-sensor built-in liquid crystal display device.
