# US 10,309,262 B2 · Complex supercritical CO2 generation system

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- Number: US 10,309,262 B2
- Document ID: US10309262B2
- Status: Granted
- Kind: B2
- Application number: 15/698,518
- Filed: 2017-09-07
- Published: 2018-07-19
- Granted: 2019-06-04
- Earliest claimed: 2017-01-16
- Assignees: Doosan Heavy Industries Construction Co., Ltd
- Applicants: Doosan Heavy Industries & Construction Co., Ltd
- Inventors: Byoung Gu Bak; Seung Gyu Kang; Jeong Ho Hwang; Eung Chan Lee; Cheol Rae Jeong
- Web page: https://patentgrep.com/patent/US10309262B2

## CPC

- F01K 25/103: {Carbon dioxide (F01K25/065 takes precedence)}
- F02C 1/04: the working fluid being heated indirectly {(in a fluidised-bed combustor F02C3/205)}
- F02C 1/10: Closed cycles
- F01K 7/16: the engines being only of turbine type (the engines using steam of critical or overcritical pressure F01K7/32; the engines being of extraction or non-condensing type F01K7/34)
- F01K 7/32: the engines using steam of critical or overcritical pressure
- F05D 2260/213: by the provision of a heat exchanger within the cooling circuit
- F01K: STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES (gas-turbine or jet-propulsion plants F02; nuclear power plants, engine arrangements therein G21D)
- F02C: GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS (construction of turbines F01D; jet-propulsion plants F02K; construction of compressors or fans F04; generating combustion products of high pressure or high velocity F23R; using gas turbines in compression refrigeration plants F25B11/00)
- F05D: INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS

## Abstract

The present invention relates to a complex supercritical CO2 generation system capable of increasing the heat exchange efficiency to improve a system output. According to the present invention, a complex generation system of a bottoming cycle and a topping cycle is configured, a flow rate of a cold side outlet of a bottoming cycle recuperators provided in parallel is branched to be supplied to a recuperator of a topping cycle provided in series, thereby increasing heat exchange efficiency of the topping cycle.

## Claims

### Claim 1

A complex supercritical CO2 generation system, comprising:
a bottoming cycle including
a compressor that compresses a working fluid,
a lower heat exchanger unit having a plurality of heat exchangers that are supplied with heat from an external heat source to heat the working fluid,
a lower turbine unit having a plurality of turbines that are driven by the working fluid,
a lower recuperator unit having a plurality of recuperators that are installed in parallel to each other and exchange heat between the working fluid having passed through the lower turbine unit and the working fluid having passed through the compressor to cool the working fluid having passed through the lower turbine unit, and
a pre-cooler that cools the working fluid primarily cooled by the lower recuperator unit and supplies the pre-cooled working fluid to the compressor; and
a topping cycle including
an upper heat exchanger unit that is supplied with the heat from the external heat source to heat the working fluid,
an upper turbine unit that is driven by the working fluid, and
an upper recuperator unit having a plurality of recuperators that are installed in series with each other and exchange heat between the working fluid having passed through the upper turbine unit and the working fluid supplied from the bottoming cycle to cool the working fluid having passed through the upper turbine unit, the working fluid cooled by the upper recuperator unit being supplied to the bottoming cycle,
wherein the bottoming cycle and the topping cycle share the compressor and the pre-cooler of the bottoming cycle.

### Claim 2 (depends on 1)

The complex supercritical CO2 generation system of claim 1, wherein the bottoming cycle branches the working fluid at a downstream end of the compressor and supplies the branched working fluid to the topping cycle and the topping cycle recuperates the working fluid branched from the bottoming cycle using the upper recuperator unit and then supplies the recuperated working fluid to the upper turbine unit.

### Claim 3 (depends on 2)

The complex supercritical CO2 generation system of claim 2, wherein some of the working fluid recuperated by a cold side recuperator among the recuperators of the lower recuperator unit in the bottoming cycle is branched and supplied to the topping cycle, and the topping cycle recuperates the working fluid branched from the bottoming cycle using a cold side recuperator among the recuperators of the upper recuperator unit, mixes the recuperated working fluid with the working fluid supplied from the cold side recuperator of the bottoming cycle to the topping cycle, and supplies the mixed working fluid to a hot side recuperator among the recuperators of the upper recuperator unit.

### Claim 4 (depends on 3)

The complex supercritical CO2 generation system of claim 3, wherein the working fluid supplied to the hot side recuperator through the cold side recuperator of the topping cycle is recuperated by the hot side recuperator, reheated by a high temperature heater, and then supplied to the upper turbine unit, and the working fluid expanded by passing through the upper turbine unit is cooled by sequentially passing through the hot side recuperator and the cold side recuperator of the upper recuperator unit and then supplied to an upstream end of the pre-cooler of the bottoming cycle.

### Claim 5 (depends on 4)

The complex supercritical CO2 generation system of claim 4, wherein the lower heat exchanger unit of the bottoming cycle includes a low temperature heater and a mid-temperature heater that exchange heat with low temperature and mid-temperature waste heat gases, the upper heat exchanger unit of the topping cycle includes the high temperature heater that exchanges heat with high temperature waste heat gas, and the waste heat gas sequentially passes through the high temperature heater, the mid-temperature heater, and the low temperature heater.

### Claim 6 (depends on 5)

The complex supercritical CO2 generation system of claim 5, wherein the bottoming cycle further includes a first separator that branches the working fluid compressed by the compressor to the low temperature heater and the lower recuperator unit, respectively, a second separator that branches the working fluid branched to the lower recuperator unit to a hot side recuperator and a cold side recuperator, respectively, among the plurality of recuperators of the lower recuperator unit, and a third separator that is provided between the first separator and the compressor to branch the working fluid compressed by the compressor to the topping cycle and the first separator, respectively.

### Claim 7 (depends on 6)

The complex supercritical CO2 generation system of claim 6, wherein the lower turbine unit of the bottoming cycle includes a first turbine and a second turbine, the working fluid recuperated by the hot side recuperator of the lower recuperator unit is supplied to the second turbine, some of the working fluid recuperated by the cold side recuperator of the lower recuperator unit is supplied to the topping cycle and some thereof is branched to be supplied to the mid-temperature heater, the working fluid branched to the mid-temperature heater is mixed with the working fluid heated by the low temperature heater to be supplied to the mid-temperature heater, and the working fluid supplied to the mid-temperature heater is heated by the mid-temperature heater and then supplied to the first turbine.

### Claim 8 (depends on 2)

The complex supercritical CO2 generation system of claim 2, wherein the working fluid supplied to a hot side recuperator through a cold side recuperator of the topping cycle is recuperated by the hot side recuperator, reheated by the upper heat exchanger unit, and then supplied to the upper turbine unit, and the working fluid expanded by passing through the upper turbine unit is cooled by sequentially passing through the hot side recuperator and the cold side recuperator and then supplied to an upstream end of the pre-cooler of the bottoming cycle.

### Claim 9 (depends on 8)

The complex supercritical CO2 generation system of claim 8, wherein the topping cycle further includes a separator that branches some of the working fluid cooled by sequentially passing through the hot side recuperator and the cold side recuperator, a second compressor that compresses the working fluid branched from the separator, and a mixer that is provided at a downstream end of the second compressor and the working fluid branched from the bottoming cycle and supplied to the cold side recuperator of the topping cycle and the working fluid having passed through the second compressor are mixed with each other by the mixer of the topping cycle to be supplied to the hot side recuperator.

### Claim 10 (depends on 9)

The complex supercritical CO2 generation system of claim 9, wherein the lower heat exchanger unit of the bottoming cycle includes a low temperature heater and a mid-temperature heater that exchange heat with low temperature and mid-temperature waste heat gases, the upper heat exchanger unit of the topping cycle includes a high temperature heater that exchanges heat with high temperature waste heat gas, and the waste heat gas sequentially passes through the high temperature heater, the mid-temperature heater, and the low temperature heater.

### Claim 11 (depends on 10)

The complex supercritical CO2 generation system of claim 10, wherein the bottoming cycle further includes a first separator that branches the working fluid compressed by the compressor to the low temperature heater and the lower recuperator unit, respectively, a second separator that branches the working fluid branched to the lower recuperator unit to a hot side recuperator and a cold side recuperator, respectively, among the recuperators of the lower recuperator unit, and a third separator that is provided between the first separator and the compressor to branch the working fluid compressed by the compressor to the topping cycle and the first separator, respectively.

### Claim 12 (depends on 11)

The complex supercritical CO2 generation system of claim 11, wherein the lower turbine unit of the bottoming cycle includes a first turbine and a second turbine, the working fluid recuperated by the hot side recuperator of the lower recuperator unit is supplied to the second turbine, the working fluid branched to the mid-temperature heater is mixed with the working fluid heated by the low temperature heater to be supplied to the mid-temperature heater, and the working fluid supplied to the mid-temperature heater is heated by the mid-temperature heater and then supplied to the first turbine.

### Claim 13 (depends on 12)

The complex supercritical CO2 generation system of claim 12, wherein the working fluids expanded by passing through the first and second turbines are cooled by the hot side and cold side recuperators of the lower recuperator unit, respectively, and the working fluids cooled by the hot side and cold side recuperators of the lower recuperator unit are mixed with the working fluid supplied from the topping cycle to be supplied to the pre-cooler.

### Claim 14

A complex supercritical CO2 generation system, comprising:
a bottoming cycle including
a compressor unit having a plurality of compressors that compress a working fluid,
a lower heat exchanger unit having a plurality of heat exchangers that are supplied with heat from an external heat source to heat the working fluid,
a lower turbine unit having a plurality of turbines that are driven by the working fluid,
a lower recuperator unit having a plurality of recuperators that are installed in parallel to each other and exchange heat between the working fluid having passed through the lower turbine unit and the working fluid having passed through the compressor to cool the working fluid having passed through the lower turbine unit, and
a pre-cooler unit having a plurality of pre-coolers that cool the working fluid primarily cooled by the lower recuperator unit and supply the pre-cooled working fluid to the compressor; and
a topping cycle including
an upper heat exchanger unit that is supplied with the heat from the external heat source to heat the working fluid,
an upper turbine unit that is driven by the working fluid, and
an upper recuperator unit having a plurality of recuperators that are installed in series with each other and exchange heat between the working fluid having passed through the upper turbine unit and the working fluid supplied from the bottoming cycle to cool the working fluid having passed through the upper turbine unit, the working fluid cooled by the upper recuperator unit being supplied to the bottoming cycle,
wherein the bottoming cycle and the topping cycle share the compressor and the pre-cooler of the bottoming cycle.

### Claim 15 (depends on 14)

The complex supercritical CO2 generation system of claim 14, wherein the bottoming cycle branches the working fluid at a downstream end of a first compressor of the compressor unit and supplies the branched working fluid to the topping cycle, the topping cycle recuperates the working fluid branched from the bottoming cycle using the upper recuperator unit and then supplies the recuperated working fluid to the upper turbine unit, the lower heat exchanger unit of the bottoming cycle includes first to third heaters that exchange heat with low temperature and mid-temperature waste heat gases, the upper heat exchanger unit of the topping cycle includes a high temperature heater that exchanges heat with high temperature waste heat gas, and the waste heat gas sequentially passes through the high temperature heater and the first to third heaters.

### Claim 16 (depends on 15)

The complex supercritical CO2 generation system of claim 15, wherein the topping cycle further includes a mixer to which some of the working fluid branched from one of the recuperators of the lower recuperator unit in the bottoming cycle is supplied, the working fluid branched to the mixer is mixed with the working fluid recuperated by a cold side recuperator of the recuperators of the topping cycle, recuperated by a hot side recuperator among the recuperators of the topping cycle, reheated by the high temperature heater, and then supplied to the upper turbine unit, and the topping cycle sequentially passes the working fluid, which is expanded by passing through the upper turbine unit, through the hot side recuperator and the cold side recuperator of the upper recuperator unit and cools the working fluid and then supplies the cooled working fluid to an upstream end of the pre-cooler unit of the bottoming cycle.

### Claim 17 (depends on 16)

The complex supercritical CO2 generation system of claim 16, wherein the compressor unit of the bottoming cycle further includes a second compressor, the pre-cooler unit includes a first pre-cooler and a second pre-cooler, the working fluid supplied from the topping cycle is mixed by a mixer provided at a downstream end of the second pre-cooler to be supplied to the second pre-cooler, and the working fluid branched at a discharge end of the second pre-cooler is supplied to the first pre-cooler and the second compressor.

### Claim 18 (depends on 17)

The complex supercritical CO2 generation system of claim 17, wherein the lower recuperator unit of the bottoming cycle includes first to third recuperators, the working fluid compressed by the second compressor is supplied to the third heater, the working fluid heated by the third heater is mixed with the working fluid recuperated by the third recuperator to be supplied to the second heater, and the working fluid heated by the second heater is mixed with some of the working fluid recuperated by the second recuperator to be supplied to the first heater and then heated by the first heater to be supplied to a hot side turbine among the turbines in the lower turbine unit.

### Claim 19 (depends on 18)

The complex supercritical CO2 generation system of claim 18, wherein the bottoming cycle further includes a first separator that branches the working fluid compressed by the first compressor to the first recuperator and the second recuperator, respectively, a second separator that branches the working fluid branched to the second recuperator to the second recuperator and the third recuperator, respectively, and a third separator that is provided between the first separator and the first compressor to branch the working fluid having passed through the first compressor to the topping cycle and the first separator, respectively.

### Claim 20 (depends on 19)

The complex supercritical CO2 generation system of claim 19, wherein the lower turbine unit of the bottoming cycle includes first to third turbines, the working fluid recuperated by the first recuperator of the lower recuperator unit is supplied to the second turbine, some of the working fluid recuperated by the second recuperator of the lower recuperator unit is supplied to the topping cycle and some thereof is branched to be supplied to the first heater and the third turbine, respectively, the working fluid recuperated by the third recuperator of the lower recuperator unit is supplied to the second heater to be mixed with the working fluid having passed through the third heater, and the working fluids expanded by passing through the first to third turbines are cooled by the first to third recuperators, respectively, and mixed with each other with the working fluid supplied from the topping cycle to be supplied to the second pre-cooler.