# US 10,309,183 B2 · Internally degradable plugs for downhole use > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,309,183 B2 - Document ID: US10309183B2 - Status: Granted - Kind: B2 - Application number: 14/535,418 - Filed: 2014-11-07 - Published: 2015-06-11 - Granted: 2019-06-04 - Earliest claimed: 2013-11-08 - Assignees: Weatherford Technology Holdings, LLC - Applicants: Weatherford/Lamb, Inc. - Inventors: I. Marc Cutler - Web page: https://patentgrep.com/patent/US10309183B2 ## CPC - E21B 33/12: Packers; Plugs (used for cementing E21B33/134, E21B33/16) - E21B 43/261: {Separate steps of (1) cementing, plugging or consolidating and (2) fracturing or attacking the formation} - E21B 34/142: {unsupported or free-falling elements, e.g. balls, plugs, darts or pistons} - E21B 2200/08: Down-hole devices using materials which decompose under well-bore conditions - E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS ## Abstract Plugs for deployment downhole include a body composed of a first material and include an activating element disposed internally in the body. The activating element has an agent configured to degrade the body. However, the agent is kept from degrading the body until occurrence of an activating trigger. The activating element can include a shell enclosing the agent therein and keeping the agent from reacting with the body's material. The shell can be composed of a breachable material that is breached to allow the agent to react with the first material. To breach the shell, the activating element can further include a breaching element that breaches the shell in response to the activating trigger. ## Claims ### Claim 1 A plug for downhole deployment, comprising: an outer body of the plug composed of a first material and having an interior and an exterior; and at least one shell disposed in the interior of the outer body and composed of a second material, the at least one shell defining a hollow containing at least one activating agent, the second material of the at least one shell being breachable; and at least one breaching body disposed in the outer body and composed of a solid material, the at least one breaching body being in breaching contact with the at least one shell, the at least one activating agent releasable from the at least one breached shell, the first material of the outer body being degradable by the at least one released activating agent acting from the interior of the outer body toward the exterior of the outer body. ### Claim 2 (depends on 1) The plug of claim 1, wherein the outer body is selected from the group consisting of a ball, a fracture ball, a trip ball, an opening plug, a closing plug, a dart, a cone, a cylinder, and a wiper. ### Claim 3 (depends on 1) The plug of claim 1, wherein the first material is selected from the group consisting of metallic material, aluminum, aluminum alloy, zinc alloy, magnesium alloy, steel, brass, aluminum bronze, metallic nanostructure material, cast iron, non-metallic material, ceramic, plastic, composite material, phenolic, polyamide-imide, polyether ether ketone, polyglycolic acid, thermoset, and thermoplastic. ### Claim 4 (depends on 1) The plug of claim 1, wherein the second material is selected from the group consisting of glass, wax, an ionic salt, calcium carbonate, metallic material, non-metallic material, ceramic, plastic, composite material, phenolic, polyamide-imide, polyether ether ketone, polyglycolic acid, thermoset, and thermoplastic. ### Claim 5 (depends on 1) The plug of claim 1, wherein the at least one activating agent is selected from the group consisting of an acid, a base, a solvent, a hydrocarbon, a hydrocarbon wax, a salt (ionic compound), an organic compound, a heat reactive material, an exothermal reacting compound, peroxide and sulfuric acid, water and strong acid, water and an anhydrous salt, water and calcium chloride, and water and calcium carbide. ### Claim 6 (depends on 1) The plug of claim 1, further comprising a sensor element disposed in the interior of the outer body and escapable from the degraded first material. ### Claim 7 (depends on 1) The plug of claim 1, wherein the at least one breaching body is disposed in the interior of the outer body in breaching contact with the at least one shell. ### Claim 8 (depends on 7) The plug of claim 7, wherein the at least one breaching body disposed in the interior of the outer body is disposed exterior to the at least one shell. ### Claim 9 (depends on 8) The plug of claim 8, wherein a portion of the at least one breaching body is disposed at the exterior of the outer body. ### Claim 10 (depends on 7) The plug of claim 7, wherein the at least one breaching body is disposed in the hollow of the at least one shell in breaching contact with the at least one shell. ### Claim 11 (depends on 1) The plug of claim 1, wherein the at least one shell comprises a first shell and a second shell, and wherein the at least one activating agent comprises a first agent in the first shell and a second agent in the second shell. ### Claim 12 (depends on 11) The plug of claim 11, wherein the first and second agents interact in contact with one another. ### Claim 13 (depends on 11) The plug of claim 11, wherein the first agent breaches the second shell, and wherein the second agent interacts with the first material of the outer body. ### Claim 14 (depends on 1) The plug of claim 1, wherein the outer body defines a pocket from the exterior to the interior in which the at least one shell is disposed, and wherein the outer body comprises a filler disposed in the pocket at the exterior and enclosing the at least one shell in the interior. ### Claim 15 (depends on 1) The plug of claim 1, wherein the at least one shell is breachable in response to one or more of a trigger, an impact, a temperature, a pressure, a deformation, a time interval, a chemical reaction, an exothermic reaction, an expansion, and a contraction. ### Claim 16 (depends on 1) The plug of claim 1, wherein the solid material comprises a different material than the first material. ### Claim 17 (depends on 1) The plug of claim 1, wherein the at least one breaching body defines a hollow containing the at least one activating agent. ### Claim 18 A downhole method, comprising: deploying a plug downhole, the plug comprising an outer body, at least one shell, and at least one breaching body, the outer body composed of a first material and having an interior and an exterior, the at least one shell disposed in the interior of the outer body and composed of a second material, the at least one shell defining at least one hollow containing at least one activating agent, the at least one breaching body disposed in the outer body and composed of a solid material, the at least one breaching body being in breaching contact with the at least one shell; exposing the plug to a trigger; releasing the at least one activating agent in the interior of the plug in response to the exposure by breaching the at least one shell in the interior of the plug with the at least one breaching body; and degrading the outer body from the interior of the outer body toward the exterior of the outer body with the at least one released activating agent. ### Claim 19 (depends on 18) The method of claims 18, wherein exposing the plug to the trigger comprises exposing the plug to one or more of an impact, a temperature, a pressure, a deformation, a time interval, a chemical reaction, an exothermic reaction, an expansion, and a contraction. ### Claim 20 (depends on 18) The method of claim 18, wherein breaching the at least one shell in the interior of the plug comprises breaking, cracking, dissolving, rupturing, melting, eroding, eating away, or compromising integrity of the at least one shell. ### Claim 21 (depends on 18) The method of claim 18, wherein the at least one breaching body is disposed in the interior of the outer body. ### Claim 22 (depends on 21) The method of claim 21, wherein the at least one breaching body is disposed in the at least one hollow of the at least one shell. ### Claim 23 (depends on 21) The method of claim 21, wherein releasing the at least one activating agent from the at least one breached shell further comprises releasing a first of the at least one activating agent from a first of the at least one shell and releasing a second of the at least one activating agent from a second of the at least one shell. ### Claim 24 (depends on 23) The method of claim 23, wherein degrading the outer body from the interior of the outer body toward the exterior of the outer body with the at least one released activating agent comprises interacting the first and second agents in contact with one another. ### Claim 25 (depends on 23) The method of claim 23, wherein releasing the at least one activating agent from the at least one breached shell comprises breaching the second shell with the first agent and interacting the second agent with the outer body. ### Claim 26 (depends on 18) The method of claim 18, wherein degrading the outer body from the interior of the outer body toward the exterior of the outer body with the at least one released activating agent comprises dissolving, eroding, eating away, cracking, breaking into pieces, collapsing, imploding, or melting material of the outer body. ### Claim 27 A plug for downhole deployment, comprising: a body of the plug composed of a first material and having an interior and an exterior; a shell comprising a first chamber and a second chamber disposed in the interior and composed of a second material, the second material of the at least one shell being breachable; at least one activating agent comprising a first agent disposed in the first chamber and a second agent disposed in the second chamber, a division dividing the first chamber from the second chamber and breaching between the first chamber and the second chamber to place the first agent in contact with the second agent, the first material of the body being degradable by the at least one activating agent acting from the interior of the body toward the exterior of the body. ### Claim 28 A plug for downhole deployment, comprising: a body of the plug composed of a first material and having an interior and an exterior; at least one shell comprising a first shell and a second shell disposed in the interior, at least the second shell being composed of a second material being breachable; at least one activating agent comprising a first agent disposed in the first shell and a second agent disposed in the second shell, the second agent breaches the first shell, the first material of the body being degradable by the at least one activating agent acting from the interior of the body toward the exterior of the body. ### Claim 29 (depends on 28) The plug of claim 28, wherein the first agent in the first shell interacts with the first material of the body. ### Claim 30 (depends on 28) The plug of claim 28, wherein the second agent interacts in contact with the first agent in the first shell.