# US 10,308,849 B2 · Adhesive composition and structure comprising at least one layer of said composition

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- Number: US 10,308,849 B2
- Document ID: US10308849B2
- Status: Granted
- Kind: B2
- Application number: 14/763,381
- Filed: 2014-01-24
- Published: 2015-12-10
- Granted: 2019-06-04
- Earliest claimed: 2013-01-25
- Assignees: Arkema France
- Applicants: Arkema France
- Inventors: Thibaut Montanari; Alexandre Vermogen; Fabrice Montezin; Vincent Ferreiro
- Web page: https://patentgrep.com/patent/US10308849B2

## CPC

- C09J 177/06: Polyamides derived from polyamines and polycarboxylic acids (C09J177/10 takes precedence)
- B32B 1/08: Tubular products
- B32B 27/306: {comprising vinyl acetate or vinyl alcohol (co)polymers}
- B32B 27/34: comprising polyamides
- C08G 69/265: {from at least two different diamines or at least two different dicarboxylic acids}
- C08G 69/36: derived from amino acids, polyamines and polycarboxylic acids
- C08L 77/00: Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers
- C09J 177/00: Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain (based on polyhydrazides C09J179/06; based on polyamide-imides C09J179/08); Adhesives based on derivatives of such polymers
- F16L 11/04: made of rubber or flexible plastics
- C08L 2205/02: containing two or more polymers of the same C08L -group
- C09J 2477/00: Presence of polyamide
- Y10T 428/1352: Polymer or resin containing [i.e., natural or synthetic]
- Y10T 428/139: Open-ended, self-supporting conduit, cylinder, or tube-type article
- Y10T 428/2896: including nitrogen containing condensation polymer [e.g., polyurethane, polyisocyanate, etc.]
- Y10T 428/31725: Of polyamide
- C09J: ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES (preparation of glue or gelatine C09H)
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- F16L: PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

An adhesive composition including predominantly one or two polyamide(s) having units chosen from: at least one unit denoted A having an average number of carbon atoms per nitrogen atom, denoted CA, ranging from 4 to 8.5, advantageously from 4 to 7; at least one unit denoted B having an average number of carbon atoms per nitrogen atom, denoted CB, ranging from 7 to 10, advantageously from 7.5 to 9.5; and at least one unit denoted C having an average number of carbon atoms per nitrogen atom, denoted CC, ranging from 9 to 18, advantageously from 10 to 18, and to the use thereof.

## Claims

### Claim 1

A polyamide consisting of the following units:
at least one unit denoted A with a mean number of carbon atoms per nitrogen atom, denoted CA, ranging from 4 to 8.5;
at least one unit denoted B with a mean number of carbon atoms per nitrogen atom, denoted CB, ranging from 7 to 10;
at least one unit denoted C with a mean number of carbon atoms per nitrogen atom, denoted CC, ranging from 9 to 18; and
optionally at least one unit Z other than an amide unit;
one of the units A, B or C being in very predominant proportion in the polyamide and representing from 80% to 97% by weight relative to the total weight of the polyamide,
the mean number of carbon atoms per nitrogen atom of the units A, B and C also corresponding to the following strict inequality: CA<CB<CC,
the heat of fusion of the polyamide being greater than 25 J/g (DSC),
the melting point of the polyamide being greater than 150° C. (DSC), and
wherein unit B is the very predominant unit in the polyamide.

### Claim 2 (depends on 1)

The polyamide as claimed in claim 1, wherein the polyamide consists of only one unit A, only one unit B and only one unit C.
