Use of composition comprising titanium or zirconium alkoxide or aryloxide in aromatic carbonate preparation process
AssigneeShell Oil Company
InventorsGaro Garbis Vaporciyan, Kunquan Yu
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Abstract
The invention relates to a process for preparing an aromatic carbonate, comprising reacting a dialkyl carbonate or an alkyl aryl carbonate with an aryl alcohol or an alkyl aryl carbonate, resulting in an aromatic carbonate which is an alkyl aryl carbonate or a diaryl carbonate.
Claims12
A process for preparing an aromatic carbonate, comprising reacting a dialkyl carbonate or an alkyl aryl carbonate with an aryl alcohol or an alkyl aryl carbonate, resulting in an aromatic carbonate which is an alkyl aryl carbonate or a diaryl carbonate, wherein a composition comprising a titanium or zirconium alkoxide, wherein the alkoxy group in the titanium or zirconium alkoxide is a group of formula R—O− wherein R is selected from the group consisting of methyl, ethyl, n-propyl and isopropyl, and wherein the composition additionally comprises 0.1 to 50 wt. % of an alcohol, based on the total weight of the composition, is mixed with an alcohol or an organic carbonate, and the mixture thus obtained is contacted with said dialkyl carbonate or alkyl aryl carbonate and aryl alcohol or alkyl aryl carbonate to catalyze the preparation of the aromatic carbonate.
Dependencies are inferred from the claim text.