# US 10,308,472 B2 · Carbon fiber precursor fiber bundle, production method and production device therefor, and carbon fiber and production method therefor > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,308,472 B2 - Document ID: US10308472B2 - Status: Granted - Kind: B2 - Application number: 13/082,232 - Filed: 2011-04-07 - Published: 2011-10-13 - Granted: 2019-06-04 - Earliest claimed: 2004-02-13 - Assignees: Mitsubishi Chemical Corporation - Applicants: Katsuhiko Ikeda; Nobuyuki Shimozawa - Inventors: Katsuhiko Ikeda; Nobuyuki Shimozawa - Web page: https://patentgrep.com/patent/US10308472B2 ## CPC - B65H 54/76: Depositing materials in cans or receptacles - D01D 5/16: using rollers, or like mechanical devices, e.g. snubbing pins - D01D 7/00: Collecting the newly-spun products ({D01D5/0076 takes precedence;} collecting newly-spun products with the imparting of twist D01H) - D01F 6/18: from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide - D01F 9/14: by decomposition of organic filaments - D01F 9/22: from polyacrylonitriles - D02J 1/08: Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams - D02J 1/223: {Stretching in a liquid bath} - D02J 1/228: {Stretching in two or more steps, with or without intermediate steps} - Y10T 428/2918: including free carbon or carbide or therewith [not as steel] - B65H: HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES - D01D: MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS - D01F: CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS - D02J: FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE (curling or crimping D02G; by treatment with liquids, gases or vapours D06B; finishing other than by liquid treatment, of yarns in warp or sheet form D06C; for chemical matters, see D06L, D06M, D06P, D06Q; treatment during rope-making, apparatus for treating ropes auxiliary to rope-making D07B) - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract A carbon fiber precursor fiber bundle which permits easy bundling of a plurality of small tows into one bundle, is provided with a dividing capability to divide into the original small tows spontaneously at the time of firing, and is suitable for obtaining a carbon fiber that is excellent in productivity and quality. A carbon fiber precursor fiber bundle that has a degree of intermingle of 1 m−1 or less between small tows, consists of substantially straight fibers without imparted crimp, a tow of which straight fibers has a moisture content of less than 10% by mass when housed in a container, and has a widthwise dividing capability to maintain a form of a single aggregate of tows when housed in a container, taken out from the container and guided into a firing step, and to divide into a plurality of small tows in the firing step by the tension generated in the firing step. ## Claims ### Claim 1 A carbon fiber precursor fiber bundle, said carbon fiber precursor fiber bundle: having 1 m−1 or less of a degree of intermingle between a plurality of small tows based on the hook drop method with a 10 g weight; and consisting of substantially straight fibers without imparted crimp, a tow of which straight fibers has a moisture content of 2.0% by mass or more and 5% by mass or less when housed in a container; wherein: the carbon fiber precursor fiber bundle has a widthwise dividing capability to maintain a form of a single aggregate of tows when housed in a container, such that when taken out from the container and guided into a firing step, the carbon fiber precursor fiber bundle spontaneously divides widthwise in the firing step into the plurality of small tows only by a tension generated in the firing step, the aggregate of tows is formed by intermingling monofilaments between a widthwise end of a small tow and a widthwise end of an adjacent small tow by air flow, a number of the monofilaments in each of the plurality of small tows is from 50,000 to 150,000, and the straight fibers consist of acrylonitrile-based polymers. ### Claim 2 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein a fineness of the monofilaments is in a range of from 0.7 dtex to 1.3 dtex, and a total number of monofilaments in the aggregate of tows is 100,000 or more and 600,000 or less. ### Claim 3 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein a number of monofilaments undergoing adhesion between the monofilaments is 5 per 50,000 of monofilaments or less and a size of a crystal region in a direction perpendicular to the fiber axis is 1.1×10−8 m or more. ### Claim 4 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein a strength of the monofilament is 5.0 cN/dtex or more, and a fineness unevenness (CV value) of the monofilament is 10% or less. ### Claim 5 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein an oiling agent adhesion unevenness (CV value) along a lengthwise direction is 10% or less. ### Claim 6 (depends on 1) A carbon fiber bundle obtained by firing the carbon fiber precursor fiber bundle according to claim 1. ### Claim 7 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein the carbon fiber precursor fiber bundle is made of three or more small tows. ### Claim 8 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein said widthwise dividing capacity is capable of dividing the carbon fiber precursor fiber bundle into a plurality of small tows by the tension generated in a flame retarding step of the firing step. ### Claim 9 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein the small tows of the plurality of small tows are not intermingled. ### Claim 10 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein the small tows of the plurality of small tows are in contact with one another only at the widthwise ends thereof. ### Claim 11 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein the widthwise ends of the small tows do not overlap. ### Claim 12 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein the fibers of the carbon fiber precursor fiber bundle are non-oxidized fibers. ### Claim 13 (depends on 1) The carbon fiber precursor fiber bundle according to claim 1, wherein the tow of straight fibers has a moisture content of more than 1.0% by mass and 5% by mass or less when housed in a container.