# US 10,307,506 B2 · Process for producing water-absorbing resin

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- Number: US 10,307,506 B2
- Document ID: US10307506B2
- Status: Granted
- Kind: B2
- Application number: 13/634,128
- Filed: 2011-03-14
- Published: 2013-01-03
- Granted: 2019-06-04
- Earliest claimed: 2010-03-12
- Assignees: Nippon Shokubai Co., Ltd.
- Applicants: Syuji Kanzaki; Sumio Okuda; Kunihiko Ishizaki; Satoshi Matsumoto
- Inventors: Syuji Kanzaki; Sumio Okuda; Kunihiko Ishizaki; Satoshi Matsumoto
- Web page: https://patentgrep.com/patent/US10307506B2

## CPC

- A61L 15/56: Wetness-indicators or colourants
- A61L 15/60: Liquid-swellable gel-forming materials, e.g. super-absorbents
- B01J 20/261: {obtained by reactions only involving carbon to carbon unsaturated bonds (macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds per se C08F)}
- B01J 20/267: {Cross-linked polymers}
- C08F 6/008: {Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes}
- C08J 3/12: Powdering or granulating
- C08J 3/122: {Pulverisation by spraying}
- C08J 3/245: {Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking}
- B01J 2220/68: Superabsorbents
- C08J 2300/14: Water soluble or water swellable polymers, e.g. aqueous gels
- C08J 2333/02: Homopolymers or copolymers of acids; Metal or ammonium salts thereof
- A61L: METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES (preservation of bodies or disinfecting characterised by the agents employed A01N; preserving, e.g. sterilising, food or foodstuffs A23; preparations for medical, dental or toiletry purposes A61K)
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)

## Abstract

The disclosed process for continuously producing a water-absorbing resin comprising a plurality of joined continuous steps; a polymerization step of polymerizing an aqueous unsaturated monomer solution, a drying step of drying a particulated water-containing gel-like crosslinked polymer obtained in a finely crushing step during the polymerization or after the polymerization, a pulverizing step after the drying, a classification step after the drying, and a surface treatment step for the water-absorbing resin powder after the classification step. In the process, with some of the above steps kept running, the other steps are interrupted, and subsequently all the steps are restarted.

## Claims

### Claim 1

A process for producing a water-absorbing resin comprising a plurality of joined continuous steps; a polymerization step of polymerizing an aqueous unsaturated monomer solution, a drying step of drying a particulated water-containing gel-like crosslinked polymer obtained in a finely crushing step during the polymerization or after the polymerization, a pulverizing step after the drying, a classification step after the drying, and a surface treatment step for the water-absorbing resin powder after the classification step, wherein
with some of the above steps kept running continuously, the other steps are interrupted, and subsequently the interrupted steps are restarted,
the interruption of the steps are at least one selected from the group of an interruption at the time of periodic maintenance and a temporal trouble, at least one of the interrupted steps is selected from the group consisting of the polymerization step, the drying step, the pulverizing step, the classification step, and the surface treatment step, a particulated water-containing gel-like crosslinked polymer, a dried material thereof, or a water-absorbing resin powder is substantially absent from an apparatus for the at least one interrupted step, the apparatus is kept in a heated state during the interruption of the step, or dry air having a dew point of not higher than 0° C. is injected into the apparatus for the interrupted step, wherein substantially absent means the particulated water-containing gel-like crosslinked polymer, dried material thereof, or water-absorbing resin powder is taken out of the apparatus for the interrupted step in an amount of not less than 95 mass % based on the entire retention capability of the apparatus;
the continuously running steps before the interrupted steps are kept running by storing the water-absorbing resin to be charged to the interrupted steps by installing a storage step for temporarily storing the water-absorbing resin,
the storage step comprising an un-filled hopper or a hopper with a low filling ratio for temporarily storing the water-absorbing resin, the unfilled hopper or the hopper with the low filling ratio is installed between the drying step and either the pulverizing step or the classification step after the drying to temporarily store the water-absorbing resin after the drying at the time of interrupting the pulverizing step or the steps after the classification step,
the filling ratio of the un-filled hopper or the hopper with a low filling ratio is 0 to 50%,
the interrupted steps are restarted after countermeasures for the periodic maintenance and the temporal trouble are made.

### Claim 2 (depends on 1)

The production process according to claim 1, wherein the step to be interrupted is the classification step or the pulverizing step.

### Claim 3 (depends on 1)

The production process according to claim 1, wherein the water-absorbing resin is produced at not less than 1 ton/hr.

### Claim 4 (depends on 1)

The production process according to claim 1, wherein the respective steps after the drying step are interrupted while apparatuses used in the respective interrupted steps being kept in a heated state and subsequently, the respective interrupted steps are restarted.

### Claim 5 (depends on 1)

The production process according to claim 1, wherein a surface-crosslinking agent to be used in the surface treatment step is a dehydration reactive surface-crosslinking agent.

### Claim 6 (depends on 1)

The process of claim 1, wherein said dry air is injected into the apparatus for the at least one interrupted step.

### Claim 7 (depends on 1)

The process of claim 1, wherein the apparatus for the at least one interrupted step is maintained in a heated state during the interruption of the respective step.

### Claim 8 (depends on 1)

The process of claim 1, wherein the apparatus for the at least one interrupted step is kept in a heated state without heating the classification apparatus for the classification step.

### Claim 9 (depends on 1)

The production process according to claim 1, wherein the apparatus for at least one of the interrupted steps is stopped while kept in a heated state during the interruption of the step.

### Claim 10 (depends on 1)

The production process according to claim 1, wherein the apparatus for the polymerization is a polymerization apparatus, the apparatus for the drying step is a dryer, the apparatus for the pulverizing step is a pulverizer, the apparatus for the classification step is a classification apparatus, and the apparatus for the surface treatment step is a heating treatment apparatus and/or a cooling apparatus.

### Claim 11

A process for producing a water-absorbing resin comprising a plurality of joined continuous steps; a polymerization step of polymerizing an aqueous unsaturated monomer solution, a drying step of drying a particulated water-containing gel-like crosslinked polymer obtained in a finely crushing step during the polymerization or after the polymerization, a pulverizing step after the drying, a classification step after the drying, and a surface treatment step for the water-absorbing resin powder after the classification step, wherein
with some of the above steps kept running continuously, the other steps are interrupted, and subsequently the interrupted steps are restarted,
the interruption of the steps are at least one selected from the group of an interruption at the time of periodic maintenance and a temporal trouble, at least one of the interrupted steps is selected from the group consisting of the polymerization step, the drying step, the pulverizing step, the classification step, and the surface treatment step, a articulated water-containing gel-like crosslinked polymer, a dried material thereof, or a water absorbing resin powder is substantially absent from an apparatus for the at least one interrupted step, the apparatus is kept in a heated state during the interruption of the step, or dry air having a dew point of not higher than 0° C. is injected into the apparatus for the interrupted step,
wherein substantially absent means the particulated water-containing gel-like crosslinked polymer, dried material thereof, or water-absorbing resin powder is taken out of the apparatus for the interrupted step in an amount not less than 95 mass % based on the entire retention capability of the apparatus;
the continuously running steps before the interrupted steps are kept running by storing the water-absorbing resin to be charged to the interrupted steps by a storage step for temporarily storing the water-absorbing resin,
the storage step comprising an un-filled hopper or a hopper with a low filling ratio for temporarily storing the water-absorbing resin, the unfilled hopper or the hoper with the low filling ratio is installed between the classification step and the surface treatment step to temporarily store the water-absorbing resin after the classification at the time of interrupting the steps after the surface treatment step,
the filling ratio of the un-filled hopper or the hopper with the low filling ratio is 0 to 50%,
the interrupted steps are restarted after countermeasures for the periodic maintenance and the temporal trouble are made.

### Claim 12 (depends on 11)

The production process according to claim 11, wherein the capacity of the hopper is not less than 20% of the production quantity of the water-absorbing resin per hour.

### Claim 13 (depends on 12)

The production process according to claim 12, wherein the hopper is heated to not lower than 40° C.

### Claim 14 (depends on 11)

The process of claim 11, wherein said dry air in injected into the apparatus for the at least one interrupted step.

### Claim 15 (depends on 11)

The process of claim 11, wherein the apparatus for the at least one interrupted step is maintained in a heated state during the interruption of the respective step.

### Claim 16 (depends on 11)

The process of claim 11, wherein the apparatus for the at least one interrupted step is kept in a heated state without heating the classification apparatus for the classification step.