Functionalized calcium phosphate artificial bone and joint compositions and methods of use and manufacture

A functionalized composition consisting of:

• at least one nonirradiated resorbable heat treated calcium phosphate non-metal substrate in the form of a monolith that is functionalized either on the surface of said calcium phosphate non-metal substrate or within an interface of at least one pore of a porous resorbable scaffold of said calcium phosphate non-metal substrate with a bidentate bond of C—O or P—O to said calcium phosphate non-metal substrate with a carbon chain, and one or more of another chemical moiety and/or one or more of a biologically active moiety, wherein said bidentate bond anchors said another chemical moiety or said biologically active moiety to said surface providing reactive locations for the attachment of either of said another chemical moiety or said biologically active moiety, or both, to said calcium phosphate non-metal substrate, wherein said functionalized calcium phosphate non-metal substrate has a surface area and modulus of rupture of cancellous bone, and wherein said functionalized calcium phosphate has a plastic consistency, wherein said porous resorbable scaffold has a macro-porosity to achieve vascularity, and wherein the hardness of said calcium phosphate non-metal substrate and natural bone are equal and abrasion is reduced, and wherein said functionalized composition is non-toxic and resists infection.