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US 10,295,904 B2Granted
Resist composition and patterning process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun Hatakeyama, Masaki Ohashi
Life of this patent
Estimating the term…
Abstract
A resist composition comprising a base polymer and a sulfonium salt of iodized benzoic acid offers a high sensitivity and minimal LWR independent of whether it is of positive or negative tone.
Claims17
A resist composition comprising a base polymer and a sulfonium salt having the formula (A):
- wherein R1 is a C1-C6 straight, branched or cyclic alkyl or alkoxy group, C2-C6 straight, branched or cyclic acyloxy group, or C1-C4 straight, branched or cyclic alkylsulfonyloxy group, in which at least one hydrogen may be substituted by a halogen atom, or fluorine, chlorine, bromine, amino group, nitro group, cyano group, —NR5—C(═O)—R6, or —NR5—C(═O)—O—R6, wherein R5 is hydrogen or a C1-C6 straight, branched or cyclic alkyl group, R6 is a C1-C6 straight, branched or cyclic alkyl group or C2-C8 straight, branched or cyclic alkenyl group,
- X is a single bond or a (p+1)-valent C1-C20 linking group which may contain an ether, carbonyl, ester, amide, sultone, lactam, carbonate, halogen, hydroxy or carboxy moiety,
- R2, R3 and R4 are each independently fluorine, chlorine, bromine, iodine, or a C1-C12 straight, branched or cyclic alkyl group which may contain an oxo moiety, a C2-C12 straight, branched or cyclic alkenyl group which may contain an oxo moiety, C6-C20 aryl group, C7-C12 aralkyl group or C7-C12 aryloxyalkyl group, in which at least one hydrogen may be substituted by a hydroxy, carboxy, halogen, cyano, amide, nitro, sultone, sulfone or sulfonium salt-containing moiety, or in which an ether, ester, carbonyl, carbonate or sulfonic acid ester moiety may intervene between carbon atoms, or R2 and R3 may bond together to form a ring with the sulfur atom to which they are attached,
- m is an integer of 1 to 5, n is an integer of 0 to 3, and p is an integer of 1 to 3.
1 more element
A sulfonium salt having the formula (A-1):
- wherein R1′ is iodine, R2′, R3′ and R4′ are each independently a C1-C12 straight, branched or cyclic alkyl group which may contain an oxo moiety, a C2-C12 straight, branched or cyclic alkenyl group which may contain an oxo moiety, C6-C20 aryl group, C7-C12 aralkyl group or C7-C12 aryloxyalkyl group, in which at least one hydrogen may be substituted by a hydroxy, carboxy, halogen, cyano, amide, nitro, sultone, sulfone or sulfonium salt-containing moiety, or in which an ether, ester, carbonyl, carbonate or sulfonic acid ester moiety may intervene between carbon atoms, or R2′ and R3′ may bond together to form a ring with the sulfur atom to which they are attached.
A resist composition comprising a base polymer and a sulfonium salt having the formula (A):
- wherein R1 is hydroxyl, a C1-C6 straight, branched or cyclic alkyl or alkoxy group, C2-C6 straight, branched or cyclic acyloxy group, or C1-C4 straight, branched or cyclic alkylsulfonyloxy group, in which at least one hydrogen may be substituted by a halogen atom, or fluorine, chlorine, bromine, amino group, nitro group, cyano group, —NR5—C(═O)—R6, or —NR5—C(═O)—O—R6, wherein R5 is hydrogen or a C1-C6 straight, branched or cyclic alkyl group, R6 is a C1-C6 straight, branched or cyclic alkyl group or C2-C8 straight, branched or cyclic alkenyl group,
- X is a (p+1)-valent C1-C20 linking group which may contain an ether, carbonyl, ester, amide, sultone, lactam, carbonate, halogen, hydroxy or carboxy moiety,
- R2, R3 and R4 are each independently fluorine, chlorine, bromine, iodine, or a C1-C12 straight, branched or cyclic alkyl group which may contain an oxo moiety, a C2-C12 straight, branched or cyclic alkenyl group which may contain an oxo moiety, C6-C20 aryl group, C7-C12 aralkyl group or C7-C12 aryloxyalkyl group, in which at least one hydrogen may be substituted by a hydroxy, carboxy, halogen, cyano, amide, nitro, sultone, sulfone or sulfonium salt-containing moiety, or in which an ether, ester, carbonyl, carbonate or sulfonic acid ester moiety may intervene between carbon atoms, or R2 and R3 may bond together to form a ring with the sulfur atom to which they are attached,
- m is an integer of 1 to 5, n is an integer of 0 to 3, and p is an integer of 1 to 3.
1 more element
Dependencies are inferred from the claim text.