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US 10,294,614 B2Granted
Low viscosity kraft fiber having an enhanced carboxyl content and methods of making and using the same
AssigneeGP Cellulose GmbH
InventorsArthur J. Nonni, Charles E. Courchene, Blair R. Carter
Life of this patent
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Abstract
A pulp fiber with an enhanced carboxyl content resulting in improved antimicrobial, anti-yellowing and absorptive properties. Methods for making the kraft pulp fiber and products made from it are also described.
Claims20
A method of making an oxidized acid-treated kraft fiber comprising:
- subjecting cellulose fiber to a kraft pulping step;
- oxygen delignifying the cellulose fiber following the kraft pulping step;
- and
- bleaching the cellulose fiber following oxygen delignification using a multi-stage bleaching process;
- oxidizing the cellulose fiber with a peroxide and a catalyst under acidic conditions in at least one stage of the multi-stage bleaching process;
- treating the fiber with a carboxylating acid comprising the addition of a combination of either sodium chlorite and hydrogen peroxide or chlorine dioxide and hydrogen peroxide in at least one stage of the multi-stage bleaching process prior to the at least one oxidation stage;
- and
- treating the fiber with a carboxylating acid comprising the addition of a combination of either sodium chlorite and hydrogen peroxide or chlorine dioxide and hydrogen peroxide in at least one stage of the multi-stage bleaching process following the at least one oxidation stage
- wherein the multi-stage bleaching process is a five-stage bleaching process comprising a sequence chosen from one of (C/A)(OX)(C/A)E2D2, (C/A)(OX)D1E2(C/A), (C/A)(OX)(C/A)E2(C/A), (C/A)E1D1(OX)(C/A), D0E1(C/A)(OX)(C/A), (C/A)E1(C/A)(OX)(C/A), (C/A)(OX)(C/A)(OX)D2, or (C/A)(OX)D1(OX)(C/A),
- where C/A refers to a carboxylating acid stage, OX refers to an oxidation stage, D refers to a chlorine dioxide stage without the addition of hydrogen peroxide, and E refers to an E, EO, Ep, or EoP bleaching stage.
7 more elements
Dependencies are inferred from the claim text.