Durable polyhydroxyalkanoate compositions
AssigneeSABIO Srl
InventorsAlessandro Carfagnini, Leonardo Bellomo
Life of this patent
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Abstract
A polyhydroxyalkanoate composition, having a an elongation at break (ASTM D648) greater than 3%, an impact resistance (IS0179 1 eA, 23° C., unnotched) greater than 18 KJ/m2 and a flexural modulus of at least 950 MPa, includes at least 25% wt of a polyhydroxyalkanoate component (I); from 5 to 40% wt of one or more thermoplastic polymers as a non-polyhydroxyalkanoate component (II); from 0 to 40% wt of one or more fillers (III); from 0 to 20% wt of one or more plasticizers (IV); and from 0 to 10% wt of one or more additives (V). The polyhydroxyalkanoate composition can be used for the preparation of durable goods that may be labelled as containing more than 20% non-fossil carbon, and for articles prepared therefrom.
Claims18
A polyhydroxyalkanoate composition having an elongation at break (ASTM D638) greater than 3%, an impact resistance (Charpy test;
- ISO179 1eU, 23° C., unnotched) greater than 18 kJ/m2 and a flexural modulus of at least 950 MPa comprising:
- at least 25% wt of a polyhydroxyalkanoate component (I), comprising one or more hydroxyalkanoate copolymers wherein the content of poly(3-hydroxybutyrate) homopolymer is and less than 5% wt;
- from 5 to 40% wt of a mixture (II) of a thermoplastic polyurethane (IIa) which is a block copolymer, and has a hardness lower than 56 Shore D, as measured according to ASTM D2240 in admixture with an acrylic polymer (IIb), which is thermoplastic, with a melting flow index according to ASTM D1238 at 175° C./2.16 kg higher than 0.25 g/10 min and/or a glass transition temperature less than 150° C.;
- wherein the acrylic polymer (IIb) is an acrylic terpolymer (IIb2) of ethylene, an alkyl acrylate or methacrylate, and glycidyl methacrylate or glycidyl acrylate,
- comprising no more than 5% wt biodegradable polymers (ASTM D6400);
- from 0 to 40% wt of one or more fillers (III);
- from 0 to 20% wt of one or more plasticizers (IV);
- and
- from 0 to 10% wt of one or more additives (V),
- wherein
- component (I) and mixture (II) together comprise at least 40% wt of the composition, and
- the % wt of the components is calculated on the total weight of components (I) to (V) of the composition and adds up to 100% wt.
Dependencies are inferred from the claim text.