A process for conversion of an acyclic C5 feedstock to a product comprising cyclic C5 compounds including cyclopentadiene, said process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product, wherein said catalyst composition comprises a microporous crystalline aluminosilicate having a constraint index of less than or equal to 5 selected from the group consisting of zeolite beta, mordenite, faujasite, zeolite L, and mixtures of two or more thereof, and a Group 10 metal in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal and, optionally, a Group 11 metal.