# US 10,246,796 B2 · RAMO4 substrate

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- Number: US 10,246,796 B2
- Document ID: US10246796B2
- Status: Granted
- Kind: B2
- Application number: 15/429,164
- Filed: 2017-02-10
- Published: 2017-09-28
- Granted: 2019-04-02
- Earliest claimed: 2016-03-25
- Assignees: Panasonic Intellectual Property Management Co., Ltd.
- Applicants: Panasonic Intellectual Property Management Co., Ltd.
- Inventors: Isao Tashiro; Hidenao Kataoka; Yoshio Okayama; Nobuyuki Yokoyama; Yoshifumi Takasu
- Web page: https://patentgrep.com/patent/US10246796B2

## CPC

- C30B 29/22: Complex oxides
- C01F 17/34: Aluminates, e.g. YAlO3 or Y3-xGdxAl5O12
- C30B: SINGLE-CRYSTAL GROWTH (by using ultra-high pressure, e.g. for the formation of diamonds, B01J3/06); UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL (zone-refining of metals or alloys C22B); PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (casting of metals, casting of other substances by the same processes or devices B22D; working of plastics B29; modifying the physical structure of metals or alloys C21D, C22F); SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (for producing semiconductor devices or parts thereof H10); APPARATUS THEREFOR
- C01F: COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS (metal hydrides {monoborane, diborane or addition complexes thereof} C01B6/00; salts of oxyacids of halogens C01B11/00; peroxides, salts of peroxyacids C01B15/00; sulfides or polysulfides of magnesium, calcium, strontium, or barium C01B17/42; thiosulfates, dithionites, polythionates C01B17/64; compounds containing selenium or tellurium C01B19/00; binary compounds of nitrogen with metals C01B21/06; azides C01B21/08; {compounds other than ammonia or cyanogen containing nitrogen and non-metals and optionally metals C01B21/082; amides or imides of silicon C01B21/087}; metal {imides or} amides C01B21/092, {C01B21/0923}; nitrites C01B21/50; {compounds of noble gases C01B23/0005}; phosphides C01B25/08; salts of oxyacids of phosphorus C01B25/16; carbides C01B32/90; compounds containing silicon C01B33/00; compounds containing boron C01B35/00; compounds having molecular sieve properties but not having base-exchange properties C01B37/00; compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites, C01B39/00; cyanides C01C3/08; salts of cyanic acid C01C3/14; salts of cyanamide C01C3/16; thiocyanates C01C3/20; {double sulfates of magnesium with sodium or potassium C01D5/12; with other alkali metals C01D15/00, C01D17/00})

## Abstract

A RAMO4 substrate containing an RAMO4 base material part containing a single crystal represented by the general formula RAMO4 (wherein R represents one or a plurality of trivalent elements selected from a group of elements including: Sc, In, Y, and a lanthanoid element, A represents one or a plurality of trivalent elements selected from a group of elements including: Fe(III), Ga, and Al, and M represents one or a plurality of divalent elements selected from a group of elements including: Mg, Mn, Fe(II), Co, Cu, Zn, and Cd), the RAMO4 base material part having a beveled portion at an edge portion thereof.

## Claims

### Claim 1

A RAMO4 substrate comprising a RAMO4 base material part containing a single crystal represented by the general formula RAMO4, where R represents one or a plurality of trivalent elements selected from a group of elements including: Sc, In, Y, and a lanthanoid element, A represents one or a plurality of trivalent elements selected from a group of elements including: Fe(III), Ga, and Al, and M represents one or a plurality of divalent elements selected from a group of elements including: Mg, Mn, Fe(II), Co, Cu, Zn, and Cd, wherein:
the RAMO4 base material part has a beveled portion at an edge portion of the RAMO4 base material part,
the RAMO4 base material part has a principal surface having an off angle θ with respect to a cleavage surface of the single crystal,
the beveled portion contains a first region having an angle θ1 with respect to the principal surface, and a second region formed outside the first region, having an angle θ2 with respect to the principal surface, and
the angles θ, θ1, and θ2 satisfy the relationship θ1<θ<θ2.

### Claim 2 (depends on 1)

The RAMO4 substrate according to claim 1, wherein
the off angle θ satisfies 0.09 deg≤θ≤45 deg, and
the angles θ and θ2 satisfy θ2<θ+45 deg.

### Claim 3 (depends on 1)

The RAMO4 substrate according to claim 1, wherein
assuming that w1 shows a length of the first region in a direction in parallel to the principal surface, and
w2 shows a length of the second region in a direction in parallel to the principal surface,
w1 is at least 0.1 mm and no greater than 5 mm, and w2 is at least 0.1 mm and no greater than 5 mm.

### Claim 4 (depends on 1)

The RAMO4 substrate according to claim 1, wherein
the principal surface does not have irregularities of 500 nm or more.

### Claim 5 (depends on 1)

The RAMO4 substrate according to claim 1, wherein
the single crystal contains ScAlMgO4.
