# US 10,246,724 B2 · Production of hydrogen using an anaerobic biological process

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- Number: US 10,246,724 B2
- Document ID: US10246724B2
- Status: Granted
- Kind: B2
- Application number: 15/358,008
- Filed: 2016-11-21
- Published: 2017-07-27
- Granted: 2019-04-02
- Earliest claimed: 2012-05-10
- Assignees: Purdue Research Foundation
- Applicants: Purdue Research Foundation
- Inventors: Robert Kramer; Libbie S. Pelter; John A. Patterson
- Web page: https://patentgrep.com/patent/US10246724B2

## CPC

- C12P 3/00: Preparation of elements or inorganic compounds except carbon dioxide {(recovery of carbon dioxides as by-products C12F3/02)}
- C12M 21/04: {for producing gas, e.g. biogas (digesters for manure with production of biogas A01C3/028, biological treatment of water, waste water or sewage C02F3/00, C02F11/02, preparation of natural gas or syngas C10L3/06, C10L3/10)}
- C12M 43/00: {Combinations of bioreactors or fermenters with other apparatus}
- C12M 43/08: {Bioreactors or fermenters combined with devices or plants for production of electricity}
- C12P 7/06: Ethanol, i.e. non-beverage
- F03G 6/003: {having a Rankine cycle (F03G6/065 takes precedence)}
- F03G 6/0055: {having other power cycles, e.g. Stirling or transcritical, supercritical cycles; combined with other power sources, e.g. wind, gas or nuclear}
- F03G 6/071: {with energy storage devices}
- C02F 11/04: Anaerobic treatment; Production of methane by such processes
- C02F 2303/10: Energy recovery
- H01M 2250/40: Combination of fuel cells with other energy production systems
- Y02E 10/46: Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines
- Y02E 50/10: Biofuels, e.g. bio-diesel
- Y02E 50/30: Fuel from waste, e.g. synthetic alcohol or diesel
- Y02E 60/50: Fuel cells
- Y02P 20/133: Renewable energy sources, e.g. sunlight
- Y02P 20/59: Biological synthesis; Biological purification
- Y02W 10/30: Wastewater or sewage treatment systems using renewable energies
- Y02W 10/37: using solar energy
- C12P: FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE {(brewing of beer C12C; producing vinegar C12J; producing specific peptides or proteins C07K; producing enzymes C12N9/00; DNA or RNA concerning genetic engineering, vectors, e.g. plasmids, or their isolation, preparation or purification C12N15/00; measuring or testing processes involving enzymes or microorganisms C12Q; measuring or testing processes involving nucleic acid amplification reactions C12Q1/6844; fermentation processes to form a food composition, A21 or A23; compounds in general, see the relevant compound class, e.g. C01, C07)}
- C12M: APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; {APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS}
- F03G: SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR (arrangements in connection with power supply in vehicles from force of nature B60K16/00; electric propulsion with power supply in vehicles from force of nature B60L8/00)
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT

## Abstract

Various embodiments of the present invention pertain to methods for biological production of hydrogen. More specifically, embodiments of the present invention pertain to a modular energy system and related methods for producing hydrogen using organic waste as a feed stock.

## Claims

### Claim 1

A modular renewable energy system comprising:
a solar collector system for generating heat energy;
a bioreactor including a chamber for fermenting organic waste; and
one of a fuel cell and a heat engine in gaseous communication with the bioreactor;
wherein anaerobic fermentation of organic waste in the chamber generates hydrogen gas, the hydrogen gas being directed to the one of a fuel cell and a heat engine; and
wherein heat energy effective for sterilization is applied to the organic waste subsequent to fermentation, the heat energy being generated by the solar collector system.

### Claim 2 (depends on 1)

The modular renewable energy system of claim 1, further comprising a housing having an interior and an exterior, wherein the bioreactor is located in the interior of the housing, the one of a fuel cell and a heat engine is located in the interior of the housing, and the solar collector system is located on the exterior of the housing.

### Claim 3 (depends on 1)

The modular renewable energy system of claim 1, wherein heat energy effective to substantially inactivate methane-producing microorganisms is applied to the organic waste prior to fermentation, the heat energy being generated by the solar collector system.

### Claim 4 (depends on 1)

The modular renewable energy system of claim 1, further comprising an apparatus for distilling water using heat energy generated by the solar collector system.

### Claim 5 (depends on 1)

The modular renewable energy system of claim 1, further comprising a controller for controlling the temperature and pH within the bioreactor chamber.

### Claim 6 (depends on 1)

The modular renewable energy system of claim 1, wherein the heat engine combusts the hydrogen in a cylinder to drive a piston.

### Claim 7 (depends on 1)

The modular renewable energy system of claim 1, wherein the heat engine combusts the hydrogen in the combustor of a gas turbine.

### Claim 8 (depends on 1)

The modular renewable energy system of claim 1, wherein the one of a fuel cell and a heat engine is connected to the bioreactor.

### Claim 9 (depends on 1)

The modular renewable energy system of claim 1, wherein the solar collector system is connected to the bioreactor.

### Claim 10 (depends on 1)

The modular renewable energy system of claim 1, further comprising a gas conditioner for separating hydrogen from other gases, wherein hydrogen is directed to the gas conditioner prior to being directed to the one of a fuel cell and a heat engine.

### Claim 11

A modular renewable energy system comprising:
a bioreactor including a chamber for fermenting organic waste; and
one of a fuel cell and a heat engine in gaseous communication with the bioreactor;
wherein anaerobic fermentation of organic waste in the chamber generates hydrogen gas, the hydrogen gas being directed to the one of a fuel cell and a heat engine; and
wherein heat energy effective for sterilization is applied to the organic waste subsequent to fermentation.

### Claim 12 (depends on 11)

The modular renewable energy system of claim 11, further comprising a solar collector system for generating heat energy, wherein the heat energy effective for sterilization applied to the organic waste subsequent to fermentation is generated by the solar collector system.

### Claim 13 (depends on 12)

The modular renewable energy system of claim 12, further comprising a housing having an interior and an exterior, wherein the bioreactor is located in the interior of the housing, the one of a fuel cell and a heat engine is located in the interior of the housing, and the solar collector system is located on the exterior of the housing.

### Claim 14

A modular renewable energy system comprising:
a solar collector system for generating heat energy;
a bioreactor including a chamber for fermenting organic waste; and
a post-processing unit in liquid communication with the bioreactor;
wherein heat energy effective for sterilization is applied to the organic waste in the post-processing unit subsequent to fermentation of the organic waste in the chamber.

### Claim 15 (depends on 14)

The modular renewable energy system of claim 14, further comprising one of a fuel cell and a heat engine in gaseous communication with the bioreactor, wherein anaerobic fermentation of organic waste in the chamber generates hydrogen gas, the hydrogen gas being directed to the one of a fuel cell and a heat engine.
