# US 10,246,665 B2 · Viscoelastic amphoteric surfactant based cleaning compositions

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- Number: US 10,246,665 B2
- Document ID: US10246665B2
- Status: Granted
- Kind: B2
- Application number: 15/674,237
- Filed: 2017-08-10
- Published: 2017-11-23
- Granted: 2019-04-02
- Earliest claimed: 2012-11-28
- Assignees: Ecolab USA Inc.
- Applicants: Ecolab USA Inc.
- Inventors: Victor Fuk-Pong Man; Michael Charles Denoma; Yvonne Marie Killeen; Susan Maloney Viall
- Web page: https://patentgrep.com/patent/US10246665B2

## CPC

- C11D 1/90: Betaines
- C11D 1/75: Amino oxides
- C11D 1/88: Ampholytes; Electroneutral compounds {(C11D1/002, C11D1/004, C11D1/008 take precedence)}
- C11D 1/92: Sulfobetaines {; Sulfitobetaines}
- C11D 1/94: Mixtures with anionic, cationic or non-ionic compounds
- C11D 3/044: {Hydroxides or bases}
- C11D 3/046: {Salts}
- C11D 3/06: Phosphates, including polyphosphates
- C11D 3/08: Silicates
- C11D 3/10: Carbonates {; Bicarbonates}
- C11D 3/2075: {Carboxylic acids-salts thereof}
- C11D 3/2079: {Monocarboxylic acids-salts thereof}
- C11D 3/33: Amino carboxylic acids
- C11D 3/361: {Phosphonates, phosphinates or phosphonites}
- C11D 3/364: {containing nitrogen}
- C11D 3/365: {containing carboxyl groups}
- C11D 17/003: {Colloidal solutions, e.g. gels; Thixotropic solutions or pastes}
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

Alkaline or neutral viscoelastic cleaning compositions are disclosed which use non polymer thickening agents. According to the invention, cleaning compositions have been developed using viscoelastic surfactants in a neutral, acidic or alkaline cleaning formulations. These provide the dual benefit of thickening as well as an additional cleaning, thereby improving performance. Applicants have also identified several pseudo linking agents which when, used with viscoelastic surfactants provide viscoelasticity in alkaline cleaning compositions.

## Claims

### Claim 1

A method of cleaning an object comprising:
contacting the object with a viscoelastic cleaning composition for a predetermined time,
wherein
the cleaning composition comprises:
(a) a source of alkalinity,
(b) a nonpolymer viscoelastic surfactant having the following formula:
wherein R1 represents a hydrophobic moiety of alkyl, alkylarylalkyl, alkoxyalkyl, alkylaminoalkyl and alkylamidoalkyl, wherein alkyl represents a group that contains from about 16 to about 22 carbon atoms which may be branched or straight chained and which may be saturated or unsaturated;
R2 and R3 are independently an aliphatic chain having from about 1 to about 30 atoms in which the aliphatic group can be branched or straight chained, saturated or unsaturated, a hydroxyalkyl chain or a carboxyalkyl chain; and
R4 is a hydrocarbyl radical (e.g. alkylene) with chain length 1 to 4; and
(c) from about 0.2 wt. % to about 5 wt. % by weight of said composition of a pseudolinker, wherein the pseudo linker is magnesium sulfate, magnesium acetate, aluminum sulfate, ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), sodium tripolyphosphate (STPP), neutralized aminotris(methylenephosphonic acid) (ATMP), neutralized 1-hydroxyethane 1,1-diphosphonic acid (HEDP), and/or neutralized 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC);
wherein said pseudo linker is present in a ratio greater than 1:1 of active percent
by weight of linker to active percent by weight of surfactant; and thereafter rinsing the cleaning composition from the object so that the cleaning composition and any soils or debris are washed away.

### Claim 2 (depends on 1)

The nonpolymer viscoelastic surfactant of claim 1 wherein said surfactant has the formula selected from the group consisting of:
wherein R1 has been previously defined herein.

### Claim 3 (depends on 1)

The method of claim 1 wherein said viscoelastic surfactant is present in an amount of from about 0.1 wt. % to about 2 wt. % by weight of said composition.

### Claim 4 (depends on 1)

The method of claim 1 wherein said object is a pipe or vessel in a food processing plant, wares, laundry, an oven, a grill, or a floor, a carpet, a medical device.

### Claim 5 (depends on 1)

The method of claim 1 wherein said composition is provided in a concentrate.

### Claim 6 (depends on 5)

The method of claim 5 further comprising the step of:
diluting said concentrate.

### Claim 7 (depends on 1)

The method of claim 1 wherein said step of contacting said object is by spraying said composition.