# US 10,246,642 B2 · Process to produce blown asphalt

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- Number: US 10,246,642 B2
- Document ID: US10246642B2
- Status: Granted
- Kind: B2
- Application number: 15/686,381
- Filed: 2017-08-25
- Published: 2019-02-28
- Granted: 2019-04-02
- Earliest claimed: 2017-08-25
- Assignees: Saudi Arabian Oil Company
- Applicants: Saudi Arabian Oil Company
- Inventors: Ki-Hyouk Choi; Mazin M. Fathi
- Web page: https://patentgrep.com/patent/US10246642B2

## CPC

- C10C 3/04: by blowing or oxidising {, e.g. air, ozone}
- C10C 3/005: {by mixing several fractions (also coaltar fractions with petroleum fractions)}
- C10G 21/02: with two or more solvents, which are introduced or withdrawn separately
- C10G 31/08: by treating with water
- C10G 53/14: including at least one oxidation step
- C08J 2495/00: Bituminous materials, e.g. asphalt, tar or pitch
- C08L 95/00: Compositions of bituminous materials, e.g. asphalt, tar, pitch
- C10G 2300/805: Water
- Y02P 20/54: using solvents, e.g. supercritical solvents or ionic liquids
- C10C: WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID (compositions of bituminous materials C08L95/00; carbon filaments by decomposition of organic filaments D01F9/14)
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A process for producing blown asphalt comprising the steps of mixing a heated hydrocarbon stream and a supercritical water in to produce a mixed stream, operating the supercritical water reactor to produce a reactor effluent, reducing the temperature of the reactor effluent in the cooler to produce a cooled effluent, feeding the cooled effluent through a depressurizing device to produce a depressurized stream, separating the depressurized stream in the flash drum to produce a light fraction stream and a heavy fraction stream, the heavy fraction stream contains a maltene fraction, an asphaltene fraction, and water, introducing the heavy fraction stream to a storage tank, withdrawing an oxidizing reactor feed from the storage tank, introducing the oxidizing reactor feed to an oxidation reactor, and operating the oxidation reactor at an oxidation temperature and an oxidation pressure to produce a product effluent that comprises an oxidized asphaltene fraction.

## Claims

### Claim 1

A process for producing blown asphalt, the process comprising the steps of:
mixing a heated hydrocarbon stream and a supercritical water in a mixer to produce a mixed stream, where the heated hydrocarbon stream has a temperature less than the temperature of the critical temperature of water and a pressure between 23 MPa and 35 MPa, where the supercritical water has a temperature between the critical temperature of water and 600 deg C. and a pressure of 23 MPa to 35 MPa, where the mixed stream comprises water and hydrocarbons having an asphaltene fraction;
introducing the mixed stream to a supercritical water reactor;
operating the supercritical water reactor at a reaction temperature and a reaction pressure for a residence time to produce a reactor effluent;
introducing the reactor effluent to a cooler;
reducing the temperature of the reactor effluent in the cooler to produce a cooled effluent;
feeding the cooled effluent through a depressurizing device to produce a depressurized stream;
introducing the depressurized stream to a flash drum;
separating the depressurized stream in the flash drum to produce a light fraction stream and a heavy fraction stream, where the light fraction stream contains light hydrocarbons and water, where the heavy fraction stream contains a maltene fraction, an asphaltene fraction, and water;
introducing the heavy fraction stream to a storage tank, the storage tank configured to store the heavy fraction stream;
withdrawing an oxidizing reactor feed from the storage tank;
introducing the oxidizing reactor feed to an oxidation reactor;
introducing an oxygen source to the oxidation reactor, where the oxidation source comprises molecular oxygen; and
operating the oxidation reactor at an oxidation temperature and an oxidation pressure to produce a product effluent, where the product effluent comprises an oxidized asphaltene fraction.

### Claim 2 (depends on 1)

The process of claim 1, further comprising the steps of:
introducing a hydrocarbon feedstock to a feedstock pump;
increasing a pressure of the hydrocarbon feedstock to produce a pressurized feedstock;
introducing the pressurized feedstock to a feedstock exchanger;
increasing the temperature of the pressurized feedstock to produce the heated hydrocarbon stream;
introducing a water feed to a water pump;
increasing a pressure of the water feed to produce a pressurized water;
introducing the pressurized water to a water heater; and
increasing the temperature of the pressurized water to produce the supercritical water.

### Claim 3 (depends on 1)

The process of claim 1, further comprising the steps of:
introducing the light fraction stream to a lights cooler;
reducing the temperature of the light fraction stream in the lights cooler to produce a cooled light fraction;
introducing the cooled light fraction to a vapor separator;
separating the cooled light fraction in the vapor separator to produce a vapor stream and a liquid stream;
introducing the liquid stream into an oil separator; and
separating the liquid stream in the oil separator to produce an upgraded hydrocarbon stream and a water stream, where the upgraded hydrocarbon stream comprises upgraded hydrocarbons.

### Claim 4 (depends on 1)

The process of claim 1, further comprising the steps of:
introducing the heavy fraction stream to a solvent deasphalting unit prior to the step of introducing the heavy fraction stream to the storage tank;
separating the heavy fraction stream in the solvent deasphalting unit to produce an asphaltene stream and a maltene stream;
introducing the asphaltene stream to the storage tank;
withdrawing a reactor feed from the storage tank; and
introducing the reactor feed to the oxidation reactor at an oxidation temperature and an oxidation pressure to produce an asphaltene product, where the asphaltene product comprises an oxidized asphaltene fraction.

### Claim 5 (depends on 1)

The process of claim 1, where a hydrocarbon feedstock of the heated hydrocarbon feedstock is selected from the group consisting of whole range crude oil, reduced crude oil, atmospheric distillates, atmospheric residue, vacuum distillates, vacuum residue, cracked product streams, produced oils, decanted oil, heavy hydrocarbon streams from an ethylene plant, liquefied coal, biomaterial-derivatives and combinations thereof.

### Claim 6 (depends on 1)

The process of claim 1, where a ratio of the volumetric flow rate of the heated hydrocarbon stream to the volumetric flow rate of supercritical water is between 1:10 and 10:1 at SATP.

### Claim 7 (depends on 1)

The process of claim 1, where the reaction temperature is greater than the critical temperature of water, the reaction pressure is between 23 MPa and 35 MPa, and the residence time is between 5 seconds and 30 minutes.

### Claim 8 (depends on 1)

The process of claim 1, where the oxidation reactor is a semi-batch reactor.

### Claim 9 (depends on 1)

The process of claim 1, where the oxidation temperature is between 150 deg C. and 300 deg C., the oxidation pressure is between 1 psig and 100 psig, and the reaction time is between 10 minutes and 240 minutes.