Molecules having certain pesticidal utilities, and intermediates, compositions, and processes related thereto

A molecule having the following formula (“Formula One” and/or “Formula Two”)

• wherein:
• (A) Ar1 is selected from
• (1) furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, or thienyl, or
• (2) substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, or substituted thienyl,
• wherein said substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, or substituted thienyl, has one or more substituents independently selected from H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, OSO2—(C1-C8)alkyl, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy,
• wherein each alkyl, cycloalkyl, alkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy;
• (B) Het is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur, or oxygen, and where Ar1 and Ar2 are 1,3 for a 5-membered ring and 1,3 or 1,4 for a 6-membered ring, and where said heterocyclic ring may also be substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, oxo, (C1-C8)alkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)2—(C1-C8)alkyl, OSO2—(C1-C8)alkyl, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy,
• wherein each alkyl, cycloalkyl, alkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)—NRxRy, (C1-C8)alkyl-NR xRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy;
• (C) Ar2 is selected from
• (1) furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, or thienyl, or
• (2) substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, or substituted thienyl,
• wherein said substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, or substituted thienyl, has one or more substituents independently selected from H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, OSO2—(C1-C8)alkyl, C(O)—NRxRy, (C1-C8)alkyl-NR xRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy,
• wherein each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)—NR xRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy;
• (D) L is linker selected from
• (1) a saturated or unsaturated, substituted linear (C1-C4)hydrocarbyl linker, and
• (2) a saturated or unsaturated, substituted cyclic (C3-C8)hydrocarbyl group linker,
• wherein each of said linkers connects Ar2 to NY and
• wherein said substituted linear (C1-C4)hydrocarbyl linker and substituted cyclic (C3-C8)hydrocarbyl linker has one or more substituents independently selected from R8, R9, R10, R11, and R12, wherein each R8, R9, R10, R11, and R12, is selected from
• —NRAC(O)—RB, —NRAC(O)O—RB, —C(O)—OH, or —C(O)O—RB,
• where RA is H or (C1-C8)alkyl, and RB is (C1-C8)alkyl or (C1-C8)alkyl substituted with at least one phenyl;
• (E) R1 is selected from the group consisting of H, (C1-C8)alkyl, (C3-C8)cycloalkyl, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, C(O)—NR xRy, (C1-C8)alkyl-NRxRy, C(O)O—(C1-C8)alkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)—(C1-C8)alkyl, (C1-C8)alkyl-S(O)2—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)O—(C1-C8)alkyl, (C1-C8)alkyl-C(O)O—(C1-C8)alkyl, C(O)alkyl, (C1-C8)alkyl-C(O)—(C1-C8)alkyl, (C1-C8)alkylphenyl, and (C1-C8)alkyl-O-phenyl,
• wherein each alkyl, cycloalkyl, alkenyl, and alkynyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, oxo, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy;
• (F) Q and Q1 are each independently selected from the group consisting of O and S;
• (G) R2 is selected from the group consisting of (J), H, (C1-C8)alkyl, (C3-C8)cycloalkyl, (C2-C8)alkenyl, (C2-C8)alkynyl, C(O)—(C1-C8)alkyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, (C1-C8)alkylphenyl, (C1-C8)alkyl-O—phenyl, C(O)—(Het-1), (Het-1), (C1-C8)alkyl-(Het-1), (C1-C8)alkyl-OC(O)—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)O—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)—NR xRy, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl-(Het-1), (C1-C8)alkyl-C(O)—(Het-1), (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl(NRxRy)—C(O)OH, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl-NRxRy, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl-N(Rx)—C(O)O—(C1-C8)alkyl, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl(N(Rx)—(O)O—(C1-C8)alkyl)-C(O)OH, (C1-C8)alkyl-C(O)—(Het-1)—C(O)O—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)O—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)—(C3-C8)cycloalkyl, (C1-C8)alkyl-OC(O)-(Het-1), (C1-C8)alkyl-OC(O)—(C1-C8)alkyl-N(Rx)—C(O)O—(C1-C8)alkyl, (C1-C8)alkyl-NRxRy, (C1-C8)alkyl-S(O)n—(Het-1), and (C1-C8)alkyl-O—(Het-1),
• wherein each alkyl, cycloalkyl, alkenyl, alkynyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)H, C(O)OH, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl), phenyl, phenoxy, Si((C1-C8)alkyl)3, S(O)n—NRxRy, and (Het-1);
• (H) R3 is selected from the group consisting of (C3-C8)cycloalkyl, phenyl, (C1-C8)alkylphenyl, (C1-C8)alkyl-O—phenyl, (C2-C8)alkenyl-O—phenyl, (Het-1), (C1-C8)alkyl-(Het-1), and (C1-C8)alkyl-O—(Het-1),
• wherein each alkyl, cycloalkyl, alkenyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)H, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C1-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, O—(C1-C8)alkyl, S—(C1-C8)alkyl, (C1-C8)alkyl-O—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, phenoxy, and (Het-1),
• (I) R4 is selected from the group consisting of (J), H, (C1-C8)alkyl, (C3-C8)cycloalkyl, (C2-C8)alkenyl, (C2-C8)alkynyl, C(O)—(C1-C8)alkyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, (C1-C8)alkylphenyl, (C1-C8)alkyl-O—phenyl, C(O)—(Het-1), (Het-1), (C1-C8)alkyl-(Het-1), (C1-C8)alkyl-OC(O)—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)O—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)—NR xRy, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl-(Het-1), (C1-C8)alkyl-C(O)—(Het-1), (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl(NRxRy)—C(O)OH, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl-NRxRy, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl-N(Rx)—C(O)O—(C1-C8)alkyl, (C1-C8)alkyl-C(O)—N(Rx)(C1-C8)alkyl(N(Rx)—C(O)O—(C1-C8)alkyl)-C(O)OH, (C1-C8)alkyl-C(O)—(Het-1)-C(O)O—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)O—(C1-C8)alkyl, (C1-C8)alkyl-OC(O)—(C1-C8)alkyl, (C1-C8)alkyl -OC(O)—(C3-C8)cycloalkyl, (C1-C8)alkyl-OC(O)—(Het-1), (C1-C8)alkyl-OC(O)—(C1-C8)alkyl-N(Rx)—C(O)O—(C1-C8)alkyl, (C1-C8)alkyl-NRxRy, (C1-C8)alkyl-S(O)n—(Het-1), and (C1-C8)alkyl-O—(Het-1),
• wherein each alkyl, cycloalkyl, alkenyl, alkynyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)H, C(O)OH, C(O)—NR xRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, phenoxy, Si((C1-C8)alkyl)3, S(O)n—NRxRy, and (Het-1);
• (J) R2 and R4 together with Cx(Q1)(Nx), may form a 4- to 7-membered saturated or unsaturated, heterocyclic ring, which may further contain one or more heteroatoms selected from the group consisting of nitrogen, sulfur, and oxygen,
• wherein each heterocyclic ring may be optionally substituted with one or more substituents independently selected from the group consisting of R5, R6, and R7,
• wherein R5, R6, and R7 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, OH, NO2, NRxRy, oxo, thioxo, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)H, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n-—C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and (Het-1);
• (K) Rx and Ry are each independently selected from the group consisting of H, (C1-C8)alkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, OSO2—(C1-C8)alkyl, C(O)H, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, , C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and (C1-C8)alkylphenyl,
• wherein each alkyl, cycloalkyl, alkoxy, alkenyl, alkynyl, phenyl, and alkylphenyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)H, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and (Het-1);
• (L) (Het-1) is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen,
• wherein said heterocyclic ring may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, oxo, (C1-C8)alkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, OSO2—(C1-C8)alkyl, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C3-Cs)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-Cs)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy,
• wherein each alkyl, cycloalkyl, alkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C8)alkyl, (C1-C8)haloalkyl, (C3-C8)cycloalkyl, (C1-C8)alkoxy, (C1-C8)haloalkoxy, (C2-C8)alkenyl, (C2-C8)alkynyl, S(O)n—(C1-C8)alkyl, S(O)n—(C1-C8)haloalkyl, OSO2—(C1-C8)alkyl, OSO2—(C1-C8)haloalkyl, C(O)—NRxRy, (C1-C8)alkyl-NRxRy, C(O)—(C1-C8)alkyl, C(O)O—(C1-C8)alkyl, C(O)—(C1-C8)haloalkyl, C(O)O—(C1-C8)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C8)alkenyl, C(O)O—(C2-C8)alkenyl, (C1-C8)alkyl-O—(C1-C8)alkyl, (C1-C8)alkyl-S(O)n—(C1-C8)alkyl, C(O)—(C1-C8)alkyl-C(O)O—(C1-C8)alkyl, phenyl, and phenoxy;
• (M) n is each individually 0, 1, or 2;
• and
• N-oxides, agriculturally acceptable acid addition salts, salts, solvates, esters, crystal polymorphs, isotopes, resolved stereoisomers, and/or tautomers thereof.