# US 10,246,361 B2 · Method for manufacturing molten glass, method for manufacturing glass product, and device for manufacturing molten glass

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- Number: US 10,246,361 B2
- Document ID: US10246361B2
- Status: Granted
- Kind: B2
- Application number: 15/370,424
- Filed: 2016-12-06
- Published: 2017-03-23
- Granted: 2019-04-02
- Earliest claimed: 2014-06-12
- Assignees: AGC Inc.
- Applicants: AGC Inc.
- Inventors: Shingo Urata; Takashi Enomoto; Kazuhiro Suzuki; Kensuke Nagai
- Web page: https://patentgrep.com/patent/US10246361B2

## CPC

- C03B 5/193: using gas, e.g. bubblers
- C03B 5/2252: {under reduced pressure, e.g. with vacuum refiners}
- C03B 5/237: Regenerators or recuperators specially adapted for glass-melting furnaces
- C03B 5/235: Heating the glass (C03B5/02, C03B5/18, C03B5/225 take precedence)
- C03B 5/2356: {Submerged heating, e.g. by using heat pipes, hot gas or submerged combustion burners (bubblers C03B5/193)}
- Y02P 40/50: Glass production, e.g. reusing waste heat during processing or shaping
- C03B: MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

There is provided a process for producing molten glass, which is capable of easily increasing the H2O content in glass melt with excessive generation of convection of the glass melt being reduced. One mode of the process for producing molten glass according to the present invention is characterized to include a material melting step for melting a raw glass material in a melting furnace to prepare glass melt; a water-molecules supply step for supplying a water-molecules supply gas into the glass melt flowing from an upstream end of the melting furnace toward a downstream end of the melting furnace; and a refining step for degassing, under a reduced pressure atmosphere, the glass melt flowing out of the downstream end; wherein a position where the water-molecules supply gas is supplied in the water-molecules supply step includes a first position and a second position from downstream to upstream in a flowing direction of the glass melt in this order; the first position is a position away from both of the upstream end and the downstream end; and the second position is a position closer to the upstream end than a center of a distance between the upstream end and the first position in the flowing direction of the glass melt.

## Claims

### Claim 1

A process for producing molten glass comprising:
melting a raw glass material in a melting furnace to prepare glass melt;
supplying a water-molecules supply gas into the glass melt flowing from an upstream end of the melting furnace toward a downstream end of the melting furnace; and
degassing, under a reduced pressure atmosphere, the glass melt flowing out of the downstream end;
wherein a position where the water-molecules supply gas is supplied in the water-molecules supply step includes a first position and a second position from downstream to upstream in a flowing direction of the glass melt in this order;
the first position is a position away from both of the upstream end and the downstream end; and
the second position is a position closer to the upstream end than a center of a distance between the upstream end and the first position in the flowing direction of the glass melt;
wherein the water-molecules supply gas supplied at the second position has a smaller floating force than the water-molecules supply gas supplied at the first position.

### Claim 2 (depends on 1)

The process according to claim 1, wherein the water-molecules supply gas supplied at each of the first position and the second position is ejected as bubbles by a bubbler; and the bubbles of the water-molecules supply gas supplied at the second position have a smaller bubble diameter than the bubbles of the water-molecules supply gas supplied at the first position.

### Claim 3 (depends on 1)

The process according to claim 1, wherein the water-molecules supply gas supplied at the second position has a smaller supply amount than the water-molecules supply gas supplied at the first position.

### Claim 4 (depends on 1)

The process according to claim 1, wherein no water-molecules supply gas is supplied between the first position and the center in the water-molecules supply step.

### Claim 5 (depends on 1)

The process according to claim 1, wherein no water-molecules supply gas is supplied between the first position and the downstream end in the water-molecules supply step.

### Claim 6 (depends on 1)

The process according to claim 1, wherein the first position is present close to a position where the glass melt has a highest temperature in the flowing direction of the glass melt and which is present in a portion of the glass melt close to the bottom of the melting furnace.

### Claim 7 (depends on 1)

The process according to claim 1, wherein the second position is present in a portion of the glass melt close to the bottom of the melting furnace.

### Claim 8 (depends on 1)

The process according to claim 1, wherein the second position is present in a portion of the glass melt close to a glass level.

### Claim 9 (depends on 1)

The process according to claim 1, wherein steam is supplied in a space in contact with the glass melt when the water-molecules are supplied.

### Claim 10 (depends on 1)

The process according to claim 1, wherein the raw glass material is made molten by air combustion when the water-molecules are supplied.

### Claim 11 (depends on 1)

The process according to claim 1, wherein the melting furnace is equipped with a burner for ejecting combustion flame into the melting furnace; the burner is supplied with a combustion gas through a regenerative furnace for storing heat in the melting furnace; and steam is supplied to the regenerative furnace when the raw material is molten.

### Claim 12 (depends on 1)

The process according to claim 1, wherein the water-molecules supply gas contains a gas having hydrogen atoms therein.

### Claim 13 (depends on 1)

A process for producing a glass product, comprising:
preparing molten glass by use of the molten glass producing process of claim 1; and
forming the molten glass to produce a glass product.
