# US 10,245,834 B2 · Manufacturing method for a fluid-ejection device, and fluid-ejection device > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,245,834 B2 - Document ID: US10245834B2 - Status: Granted - Kind: B2 - Application number: 15/812,960 - Filed: 2017-11-14 - Published: 2018-03-08 - Granted: 2019-04-02 - Earliest claimed: 2015-12-29 - Assignees: STMicroelectronics S.r.l. - Applicants: Stmicroelectronics S.R.L. - Inventors: Mauro Cattaneo; Carlo Luigi Prelini; Lorenzo Colombo; Dino Faralli; Alessandra Sciutti; Lorenzo Tentori - Web page: https://patentgrep.com/patent/US10245834B2 ## CPC - B41J 2/1626: {etching} - B41J 2/01: Ink jet - B41J 2/135: Nozzles - B41J 2/16: Production of nozzles - B41J 2/1607: {Production of print heads with piezoelectric elements (B41J2/1606, B41J2/162 take precedence)} - B41J 2/161: {of film type, deformed by bending and disposed on a diaphragm} - B41J 2/162: {Manufacturing of the nozzle plates} - B41J 2/1621: {Manufacturing processes} - B41J 2/1628: {dry etching} - B41J 2/1629: {wet etching} - B41J 2/1631: {photolithography} - B41J 2/1632: {machining} - Y10T 29/49401: Fluid pattern dispersing device making, e.g., ink jet - B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract A method for manufacturing a device for ejecting a fluid, including producing a nozzle plate including: forming a first nozzle cavity, having a first diameter, in a first semiconductor body; forming a hydrophilic layer at least in part in the first nozzle cavity; forming a structural layer on the hydrophilic layer; etching the structural layer to form a second nozzle cavity aligned to the first nozzle cavity in a fluid-ejection direction and having a second diameter larger than the first diameter; proceeding with etching of the structural layer for removing portions thereof in the first nozzle cavity, to reach the hydrophilic layer and arranged in fluid communication the first and second nozzle cavities; and coupling the nozzle plate with a chamber for containing the fluid. ## Claims ### Claim 1 A fluid ejection device, comprising: a nozzle plate including: a first nozzle cavity, having a first diameter, in a first semiconductor body; a first hydrophilic layer on the first semiconductor body and on inner walls of said first nozzle cavity; a structural layer on the first hydrophilic layer, the first hydrophilic layer being positioned between the structural layer and the first semiconductor body; and a second nozzle cavity in the structural layer, the first and second nozzle cavities being in mutual fluidic communication, the second nozzle cavity being aligned to the first nozzle cavity in a fluid-ejection direction and having a second diameter larger than the first diameter; and a containment chamber coupled to the nozzle plate and configured to contain said fluid so that the first and second nozzle cavities are in fluidic connection with the containment chamber. ### Claim 2 (depends on 1) The fluid ejection device according to claim 1, wherein the first hydrophilic layer completely coats the inner walls of the first nozzle cavity. ### Claim 3 (depends on 1) The fluid ejection device according to claim 1, wherein said first hydrophilic layer has a contact angle equal to or less than 40°. ### Claim 4 (depends on 1) The fluid ejection device according to claim 1, wherein the first hydrophilic layer is positioned on a first surface of the first semiconductor body, the fluid ejection device further comprising: a second hydrophilic layer on a second surface of the first semiconductor body, the second surface being opposite to the first surface. ### Claim 5 (depends on 1) The fluid ejection device according to claim 1, wherein the first hydrophilic layer is positioned on a first surface of the first semiconductor body, the fluid ejection device further comprising an anti-wetting layer, having a contact angle greater than 90°, on a second surface of the first semiconductor body, the second surface being opposite to the first surface. ### Claim 6 (depends on 1) The fluid ejection device according to claim 1, wherein said nozzle cavity has a cylindrical or frustoconical shape. ### Claim 7 (depends on 1) The fluid ejection device according to claim 1, further comprising: a second semiconductor body having first and second faces; a membrane layer on the first face of the second semiconductor body; and a piezoelectric actuator on the membrane layer; wherein: the containment chamber includes a recess formed in the second face of the second semiconductor body, opposite to the first face in said fluid-ejection direction, wherein the membrane layer is partially suspended on the recess. ### Claim 8 (depends on 1) The fluid ejection device according to claim 1, further comprising: a third semiconductor body coupled to the membrane layer and having a first inlet through hole, wherein said membrane layer includes a second inlet through hole that fluidly connects the first inlet through hole to the containment chamber. ### Claim 9 (depends on 1) The fluid ejection device according to claim 1, further comprising a bonding layer or a layer of bi-adhesive tape affixing the second semiconductor layer to the structural layer. ### Claim 10 A nozzle plate, comprising: a first semiconductor body that includes a first nozzle cavity, having a first diameter; a first hydrophilic layer on the first semiconductor body and on inner walls of said first nozzle cavity; a structural layer on the first hydrophilic layer such that the first hydrophilic layer is between the structural layer and the first semiconductor body, the structural layer including a second nozzle cavity in mutual fluidic communication with the first nozzle cavity, the second nozzle cavity extending to the first hydrophilic layer, being aligned to the first nozzle cavity in a fluid-ejection direction, and having a second diameter larger than the first diameter. ### Claim 11 (depends on 10) The nozzle plate according to claim 10, wherein the first hydrophilic layer is positioned on a first surface of the first semiconductor body, the nozzle plate further comprising a second hydrophilic layer on a second surface of the first semiconductor body. ### Claim 12 (depends on 10) The nozzle plate according to claim 10, wherein the first hydrophilic layer is positioned on a first surface of the first semiconductor body, nozzle plate further comprising: an anti-wetting layer, having a contact angle greater than 90°, on a second surface of the first semiconductor body, the second surface being opposite to the first surface. ### Claim 13 A fluid ejection device, comprising: a first structural body that includes a first nozzle cavity for ejecting a fluid, the first nozzle cavity having a first diameter; a second structural body including a containment chamber configured to contain said fluid; and a second nozzle cavity aligned to the first nozzle cavity in a fluid-ejection direction and having a second diameter larger than the first diameter; and a first hydrophilic layer extending between the first and second structural bodies and coating inner walls of the first nozzle cavity. ### Claim 14 (depends on 13) The fluid ejection device according to claim 13, wherein: the first structural body includes a first semiconductor body through which said first nozzle cavity extends; the second structural layer includes a second semiconductor body and a structural layer that extends between the second semiconductor body and the first hydrophilic layer, the containment chamber being positioned in the second semiconductor body and the second nozzle chamber being positioned in the structural layer. ### Claim 15 (depends on 13) The fluid ejection device according to claim 13, further comprising: a membrane layer suspended on the containment chamber; a piezoelectric actuator on the membrane layer. ### Claim 16 (depends on 15) The fluid ejection device according to claim 15, further comprising: a third structural body coupled to the membrane layer and having a first inlet through hole, wherein said membrane layer includes a second inlet through hole that fluidly connects the first inlet through hole to the containment chamber. ### Claim 17 The fluid ejection device according to 13, wherein said first hydrophilic layer has a contact angle equal to or less than 40°. ### Claim 18 (depends on 13) The fluid ejection device according to claim 13, wherein the first hydrophilic layer is positioned on a first surface of the first structural body, the fluid ejection device further comprising: a second hydrophilic layer on a second surface of the first structural body, the second surface being opposite to the first surface. ### Claim 19 (depends on 13) The fluid ejection device according to claim 13, wherein the first hydrophilic layer is positioned on a first surface of the first structural body, the fluid ejection device further comprising an anti-wetting layer, having a contact angle greater than 90°, on a second surface of the first structural body, the second surface being opposite to the first surface. ### Claim 20 (depends on 13) The fluid ejection device according to claim 13, wherein said nozzle cavity has a cylindrical or frustoconical shape.