Adhesive composition for polarizing plate, polarizing plate including the same, and optical display including the same
AssigneeSamsung SDI Co., Ltd.
InventorsIrina Nam, Inga Tuzovskaya, Young Jong Kim, Il Jin Kim, Hwan Sung Cheon
Life of this patent
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Abstract
An adhesive composition for polarizing plates includes a (meth)acrylic copolymer prepared by copolymerization of a monomer mixture and a curing agent. The monomer mixture includes a hydroxyl group-containing (meth)acrylic monomer, a tertiary amine group-containing (meth)acrylic monomer and a monomer having a glass transition temperature (Tg) of about 100° C. or greater. The adhesive composition has a gel fraction of about 50% or greater after aging for 12 hours. An adhesive film is formed from the adhesive composition. An optical display includes the adhesive film.
Claims16
An adhesive composition for polarizing plates, comprising a (meth)acrylic copolymer and a curing agent,
- wherein the (meth)acrylic copolymer is prepared by copolymerization of a monomer mixture, the monomer mixture comprising:
- about 4 wt % to about 20 wt % of a hydroxyl group-containing (meth)acrylic monomer,
- a tertiary amine group-containing (meth)acrylic monomer, and
- a monomer having a homopolymer glass transition temperature (Tg) of about 100° C. or greater, the monomer having a homopolymer Tg of about 100° C. or greater comprising at least one of (meth)acryloyl morpholine or isobornyl (meth)acrylate and being present in the monomer mixture in an amount of about 5 wt % to about 19 wt %,
- wherein the monomer mixture comprises the hydroxyl group-containing (meth)acrylic monomer and the tertiary amine group-containing (meth)acrylic monomer in a weight ratio of about 500:1 to about 1:1,
- the adhesive composition having a gel fraction of about 50% or greater after aging for 12 hours, as calculated by Equation 1:
- Gel Fraction=(WC−WA)/(WB−WA)×100 Equation 1
- wherein:
- WA is a weight of a wire mesh (200 mesh);
- WB is a total weight of the wire mesh and a specimen of an adhesive film for polarizing plates, the adhesive film being obtained by depositing 1.0 g of the adhesive composition for polarizing plates to a thickness of 20 μm on a release film, followed by aging the adhesive composition for polarizing plates on the release film at 23° C. and 55% RH for a period of time;
- and
- WC is a total weight of the wire mesh and the adhesive film after placing the wire mesh and the adhesive film in a sample bottle, adding 50 cc of ethyl acetate to the sample bottle, allowing the sample bottle to stand for 1 day, and drying the sample bottle at 90° C. for 24 hours.
Dependencies are inferred from the claim text.