Bromide removal from aqueous solutions
AssigneeCase Western Reserve University
InventorDaniel A. Scherson
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Abstract
Systems and processes for removing and purifying bromide from an aqueous bromide solution are described. Electrochemistry is used to either convert bromide to bromine to allow its extraction in an organic phase, or to cause deposition of bromine onto an electrode. In either case, once removed from the aqueous bromide solution, the bromide can be recovered and purified.
Claims22
A process for removing and purifying bromide from an aqueous bromide solution, comprising the steps of:
- contacting an aqueous bromide solution with a suitable organic solvent and an electrode positioned between the aqueous bromide solution and the suitable organic solvent;
- applying a positive voltage to the electrode causing bromine to form and migrate into the suitable organic solvent to form a concentrated organic bromine solution;
- and
- removing the concentrated organic bromine solution from contact with the aqueous bromide solution and the electrode.
A system for removing and purifying bromide from an aqueous bromide solution, comprising:
- a first container configured to hold an aqueous bromide solution layer and a suitable organic solvent layer, and a first electrode positioned between the aqueous bromide solution layer and the suitable organic solvent layer, wherein the suitable organic solvent layer becomes a concentrated organic bromine solution layer upon applying a voltage to the first electrode;
- a second container configured to hold a concentrated organic bromine solution layer and a water solution layer, and a second electrode positioned between the concentrated organic bromine solution layer and the water solution layer;
- means for transferring the concentrated organic bromine solution layer from the first container to the second container;
- and
- a power source for applying a voltage to the first electrode and the second electrode.
A process for removing and purifying bromide from an aqueous bromide solution, comprising the steps of:
- contacting an aqueous bromide solution with an electrode;
- applying a positive voltage to the electrode to form a bromine-coated electrode as a result of bromine adsorption;
- moving the bromine-coated electrode to a water solution, and applying a negative voltage to the bromine-coated electrode to release bromide into the water solution, thereby forming a concentrated bromide solution.
A system for removing and purifying bromide from an aqueous bromide solution, comprising:
- a first container holding an aqueous bromide solution;
- an electrode;
- a second container holding water;
- and
- a power source for applying a voltage to the electrode;
- wherein the purified bromide solution is prepared by positioning the electrode in the first container and positively polarizing the electrode, providing sufficient time for bromine to adhere to the electrode, and then positioning the electrode in the second container and negatively polarizing the electrode to release bromide into the water to form a purified bromide solution.
Dependencies are inferred from the claim text.