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US 10,240,037 B2Granted
Polycarbonate-based resin composition and molded article thereof
AssigneeLG Chem, Ltd.
InventorsJong Hyun Lee, Su Kyoung Lee, Min Ji Kim, Ryul Lee, Sung Tae Ahn
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Abstract
The present invention relates to a polycarbonate-based resin composition and a molded article thereof, and more particularly, to a polycarbonate-based resin composition exhibiting low deformation characteristic, excellent impact strength, excellent appearance surface characteristic, and excellent flame retardancy, and a molded article formed therefrom.
Claims14
A polycarbonate-based resin composition comprising:
- a polycarbonate resin including an aromatic polycarbonate-based first repeating unit,
- a copolycarbonate resin including an aromatic polycarbonate-based first repeating unit, and an aromatic polycarbonate-based second repeating unit having one or more siloxane bonds,
- a glass fiber,
- an impact-reinforcing agent including a rubber-modified vinyl-based graft copolymer, and
- a phosphorus-based flame retardant;
- wherein the first repeating unit each independently includes a repeating unit represented by Chemical Formula 1 below,
- the second repeating unit includes at least one repeating unit selected from the group consisting of Chemical Formula 3 below, and;
- the glass fiber has a rectangular, circular or elliptical cross section in a direction perpendicular to a longitudinal direction, and has an aspect ratio according to Equation 1 below of 100 to 500, a length (L) of 2 to 7 mm, and D of 5 to 20 μm:
- Aspect ratio (δ)=L/D [Equation 1]
- in Equation 1, L is a length of the glass fiber, D is a length of the longest side of the rectangular cross section, a length of a diameter of the circular cross section, or a length of the longest diameter of the elliptical cross section,
- in Chemical Formula 1,
- R1 to R4 are each independently hydrogen, C1-10 alkyl, C1-10 alkoxy, or halogen, and
- Z is C1-10 alkylene unsubstituted or substituted with phenyl, C3-15 cycloalkylene unsubstituted or substituted with C1-10 alkyl, O, S, SO, SO2, or CO;
- in Chemical Formula 3,
- X2 is each independently C1-10 alkylene,
- Y1 is each independently hydrogen, C1-6 alkyl, halogen, hydroxy, C1-6 alkoxy or C6-20 aryl,
- R6 is each independently hydrogen;
- C1-15 alkyl unsubstituted or substituted with oxiranyl, oxiranyl-substituted C1-10 alkoxy, or C6-20 aryl;
- halogen;
- C1-10 alkoxy;
- allyl;
- C1-10 haloalkyl;
- or C6-20 aryl, and
- n2 is an integer of 10 to 200.
21 more elements
Dependencies are inferred from the claim text.