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US 10,239,963 B2Granted
Mixed salt suspension polymerization process and resins and catalysts produced thereof
AssigneeRohm and Haas Company
InventorsTakashi Masudo, Robert J. Olsen, Garth R. Parker, Jr., Jose A. Trejo
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Abstract
This invention relates to no-salt and mixed salt suspension polymerization processes for water-soluble monomers and resins and relates to catalysts produced from the same.
Claims2
A process for preparing a resin by suspension polymerization comprising:
- i) forming an aqueous suspension, wherein the aqueous suspension comprises an aqueous phase and an organic phase, wherein the organic phase comprises:
- a) a monomer phase;
- b) from 0.1 to 5 weight percent of a polymerization initiator;
- and
- wherein the monomer phase comprises at least 50 weight percent of vinyl pyridine and from 0.1 to 50 weight percent of divinylbenzene;
- ii) establishing polymerization conditions in the suspension,
- iii) allowing the monomers to polymerize until they have formed water-insoluble particles, and
- iv) separating the particles from the aqueous phase;
- further wherein the aqueous phase comprises water and also comprises a mixture comprising from about 1 to about 2.5 weight percent sodium nitrite and about 5 weight percent sodium bicarbonate, based on the water in the aqueous phase.
6 more elements
Dependencies are inferred from the claim text.