Process for producing (meth)acrylic acid
AssigneeArkema France
InventorsSandeep Jain, Christian Lacroix, Michel Jean Fauconet
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Abstract
The invention is directed to a process for recovering/purifying (meth)acrylic acid which does not use azeotropic solvent and is based on the use of two columns for purifying a reaction mixture comprising (meth)acrylic acid. The process according to the invention includes a dry vacuum pump condensation system, which makes it possible to reduce the amount of final aqueous discharges.
Claims12
A process for recovering (meth)acrylic acid without using azeotropic solvent, starting from a gaseous reaction mixture comprising (meth)acrylic acid obtained by gas-phase oxidation of a precursor of the (meth)acrylic acid, comprising at least the following steps:
- i) subjecting the gaseous reaction mixture to dehydration without using azeotropic solvent in a dehydration column, resulting in a dehydration column overhead stream, at least a portion of which is condensed and sent back to the dehydration column in the form of reflux, and in a dehydration column bottom stream;
- ii) subjecting the dehydration column bottom stream, at least in part, to a distillation at a pressure below atmospheric pressure in a finishing column, resulting in a finishing column overhead stream and in a finishing column bottom stream containing heavy compounds;
- iii) recovering a (meth)acrylic acid stream by drawing off as a sidestream from the finishing column, and/or as bottoms from the finishing column;
- subjecting the finishing column overhead gaseous stream, at least in part, to a dry vacuum pump condensation system such that the finishing column operates under vacuum, thereby eliminating or reducing generation of aqueous discharge and forming a condensate comprising light compounds that is recycled back to the dehydration column, and a final gaseous effluent.
Dependencies are inferred from the claim text.