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US 10,208,210 B2Granted
Hydrophilic oil repellent and production method of same, surface coating material, coating film, resin composition, oil-water separation filter material, and porous body
AssigneesMitsubishi Materials Corporation, Mitsubishi Materials Electronic Chemicals Co., Ltd.
InventorsMasato Fujita, Masakazu Uotani, Takeshi Kamiya, Tsunetoshi Honda, Daisuke Takano
Life of this patent
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Abstract
The hydrophilic oil repellent includes one or more types of nitrogen-containing fluorine-based compounds. The nitrogen-containing fluorine-based compound includes any one hydrophilicity imparting group selected from the group consisting of anion type hydrophilicity imparting groups, cation type hydrophilicity imparting groups, and amphoteric type hydrophilicity imparting groups in the molecule.
Claims13
A hydrophilic oil repellent, comprising:
- one or more nitrogen-containing fluorine-based compounds represented by the following formulas (1) to (4):
- wherein in the above formulas (1) and (2), Rf1 and Rf2 each represent a linear or branched perfluoroalkyl group having 1 to 6 carbon atoms, which are the same as or different from each other, and Rf3 represents a linear or branched perfluoroalkylene group having 1 to 6 carbon atoms;
- in the above formulas (3) and (4), Rf4, Rf5, and Rf6 each represent a linear or branched perfluoroalkylene group having 1 to 6 carbon atoms, which are the same as or different from each other, and Z includes any one of an oxygen atom, a nitrogen atom, a CF2 group, and a CF group;
- in the above formulas (2) and (4), R represents a linking group which is a divalent organic group;
- and
- in the above formulas (1) to (4), X is:
- an anion type hydrophilic imparting group having “—CO2M1” “—SO3M1” “—OSO3M1”, “—OP(OH)O2M1”, “—OPO3M12”, “═O2PO2M1”, or “—PO(OH)y(OM1)2-y,” wherein M1 represents an alkali metal, an alkali earth metal, Mg, Al, or R1R2R3R4N+, and wherein R1 to R4 are each independently a hydrogen atom or a linear or branched alkyl group having 1 to 20 carbon atoms, and y represents an integer of 0 to 2, at a terminal, or
- a cation type hydrophilicity imparting group having “—N+R5R6R7.Cl−”, “—N+R5R6R7.Br−”, “—N+R5R6R7.I−”, “−N+R5R6R7.CH3SO3−”, “—N+R5R6R7.R7SO4−”, “−N+R5R6R7.NO3−”, “(−N+R5R6R7)2CO32−”, or “(−N+R5R6R7)2SO42−”, wherein R5 to R7 are hydrogen atoms or each independently a linear or branched alkyl group having 1 to 20 carbon atoms, at a terminal,
- or
- an amphoteric hydrophilicity imparting group having any one terminal of a carboxybetaine type, a sulfobetaine type, an amine oxide type, and a phosphobetaine type.
7 more elements
Dependencies are inferred from the claim text.