Sulfonated fluorinated, non-fluorinated or partially fluorinated urethanes

A compound having 0 to about 1% reactive isocyanate groups comprising the reaction product of reagents comprising:

• (a) at least one isocyanate group-containing compound selected from diisocyanate, polyisocyanate, or mixture thereof;
• (b) at least one isocyanate-reactive compound selected from the group consisting of a fluorinated alcohol;
• a cyclic or acyclic sugar alcohol which is substituted with at least one R1, —C(O)R1, —(CH2CH2O)n(CH(CH3)CH2O)mR2, —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1, or mixtures thereof;
• and mixtures of a fluorinated alcohol and a cyclic or acyclic sugar alcohol which is substituted with at least one R1, —C(O)R1, —(CH2CH2O)n(CH(CH3)CH2O)mR2, —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1, or mixtures thereof;
• where the cyclic or acyclic sugar alcohol is selected from a saccharide, reduced sugar, aminosaccharide, aldonic acid, or aldonic acid lactone;
• wherein
• each n is independently 0 to 20;
• each m is independently 0 to 20;
• m+n is greater than 0;
• each R1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond;
• each R2 is independently —H, or a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof;
• (c) at least one isocyanate-reactive ethylenically unsaturated compound selected from allylic or methallylic polyether alcohols, aminoalkyl vinyl compounds, acrylic or methacrylic alkyl alcohols, acrylic or methacrylic polyether alcohols, or acrylic or methacrylic amines;
• and
• (d) a bisulfate source.