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US 10,167,200 B2Granted
Synthesis of molecular sieve SSZ-41
AssigneeChevron U.S.A. Inc.
InventorsStacey Ian Zones, Cong-Yan Chen, Howard Steven Lacheen, Kaustav Chaudhuri
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Abstract
A method is disclosed for synthesizing zincoaluminosilicate molecular sieve SSZ-41 having high aluminum content from a combined source of silicon oxide and aluminum oxide selected from one or more a FAU framework type zeolite and a colloidal aluminosilicate.
Claims7
A method of synthesizing a zincoaluminosilicate molecular sieve having the framework structure of SSZ-41, the method comprising:
- (a) preparing a reaction mixture comprising:
- (1) a combined source of silicon oxide and aluminum oxide selected from a FAU framework type zeolite, a colloidal aluminosilicate, or a mixture thereof;
- (2) a source of zinc;
- (3) a source of a Group 1 or Group 2 metal (M);
- (4) a structure directing agent (Q) comprising 1,1′-(1,4-butanediyl)bis-4-aza-1-azoniabicyclo[2.2.2]octane dications;
- (5) hydroxide ions;
- and
- (6) water;
- and
- (b) subjecting the reaction mixture to crystallization conditions sufficient to form crystals of the molecular sieve;
- wherein the reaction mixture has a composition, in terms of molar ratios, as follows:
- SiO2/Al2O3
- 60 to 90
- SiO2/ZnO
- 15 to 40
- M/SiO2
- 0.10 to 0.30
- Q/SiO2
- 0.15 to 0.40
- OH/SiO2
- 0.15 to 0.40
- H2O/SiO2
- 15 to 45.
20 more elements
Dependencies are inferred from the claim text.