Methane conversion apparatus and process using a supersonic flow reactor
AssigneeUop LLC
InventorsRobert L. Bedard, Christopher Naunheimer, Gavin P. Towler, Laura E. Leonard, Gregory O. Woodcock, Donald L. Mittendorf, Aziz Sattar, Christopher D. Gatto, Robert S. Murray
Life of this patent
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Abstract
Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.
Claims19
An apparatus for producing acetylene from a feed stream comprising methane comprising:
- a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;
- a reactor shell of the supersonic reactor for defining a reactor chamber;
- a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
- an outer layer of the reactor shell for providing structural support thereto;
- an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof;
- and
- a coating comprising nickel metal, an alloy of nickel, chromium metal, an alloy of chromium, platinum metal, an alloy of platinum, palladium, or an alloy of palladium, or mixtures thereof applied to an inner surface of the inner layer of the reactor shell.
A process for producing acetylene from a feed stream comprising methane comprising:
- introducing the feed stream to a supersonic reactor wherein the supersonic reactor comprises:
- a reactor shell of the supersonic reactor for defining a reactor chamber;
- a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
- an outer layer of the reactor shell for providing structural support thereto;
- an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof;
- and
- a coating comprising a coating comprising nickel metal, an alloy of nickel, chromium metal, an alloy of chromium, platinum metal, an alloy of platinum, palladium, or an alloy of palladium, or mixtures thereof applied to an inner surface of the inner layer of the reactor shell;
- combusting a fuel source to provide a high temperature carrier gas passing through the reactor at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature, wherein upon heating and accelerating the methane stream, acetylene is generated;
- and
- preventing formation of acetylides in the reactor by employing the coating that prevents the acetylene from contacting the copper of the inner layer of the reactor.
Dependencies are inferred from the claim text.