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US 10,155,735 B2Granted
Synthesis of novel ionic liquids from lignin-derived compounds
AssigneesThe Regents of the University of California, National Technology & Engineering Solutions of Sandia, LLC
InventorsAaron Socha, Seema Singh, Blake A. Simmons, Maxime Bergeron
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Abstract
Methods and compositions are provided for synthesizing ionic liquids from lignin. Methods and compositions are also provided for treating lignin with ionic liquids.
Claims13
A compound selected from:
- wherein two of the R groups of each nitrogen are CH2CH3;
- one of the R groups of each nitrogen is H;
- R′, R″, and R′″ are independently selected from the group consisting of H, OH, and OCH3;
- R4 is selected from the group consisting of H, OH, and CH2OH;
- and
- X is an acid anion selected from the group consisting of acetate, dihydrogen phosphate, and hydrogen sulfate.
3 more elements
A lignin-derived ionic liquid prepared by
- contacting a starting material comprising lignin with a depolymerization agent to depolymerize the lignin and form a mixture of aldehyde containing compounds;
- contacting the mixture of aldehyde containing compounds with an amine under conditions suitable to convert the mixture of aldehyde containing compounds to a mixture of amine containing compounds;
- and
- contacting the mixture of amine containing compounds with a mineral acid under conditions suitable to form an ammonium salt, thereby preparing the lignin-derived ionic liquid,
- wherein the lignin-derived ionic liquid is selected from:
- wherein two the R groups of each nitrogen are CH2CH3;
- one of the R groups of each nitrogen is H;
- R′, R″, and R′″ are independently selected from the group consisting of H, OH, and OCH3;
- R4 is selected from the group consisting of H, OH, and CH2OH;
- and
- X is an acid anion selected from the group consisting of acetate, dihydrogen phosphate, and hydrogen sulfate.
8 more elements
Dependencies are inferred from the claim text.