Production method for olefin-based polymer, and olefin polymerization catalyst
AssigneeIdemitsu Kosan Co., Ltd.
InventorsMasayuki Nishida, Kanako Samejima
Life of this patent
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Abstract
Provided is a production method for an olefin-based polymer, including polymerizing an olefin raw material using (A) a transition metal compound, (B) a boron compound capable of forming an ion pair with the component (A), (C) a specific organoaluminum compound, and (D) a specific aluminoxane in presence of at least one or more kinds of (N) a nonpolymerizable unsaturated hydrocarbon in the olefin raw material or a polymerization solvent.
Claims13
A method of producing an olefin-based polymer, the method comprising polymerizing an olefin raw material by contacting components (A) to (D) in the presence of component (N) in the olefin raw material or a polymerization solvent:
- (A) a transition metal compound;
- (B) a boron compound capable of forming an ion pair with the component (A);
- (C) an organoaluminum compound represented by a formula (VIII):
- R17vAlJ3-v (VIII)
- (D) an aluminoxane represented by a formula (i) or (ii):
- (N) a nonpolymerizable unsaturated hydrocarbon;
- wherein:
- i
- R17 represents an alkyl group having 1 to 20 carbon atoms;
- J represents a hydrogen atom, an alkoxy group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or a halogen atom;
- v represents an integer of from 1 to 3, and when v represents 2 or more, R17's may be identical to or different from each other, provided that at least one R17 represents an alkyl group having 1 to 20 carbon atoms;
- Ra represents an alkyl group having 1 to 20 carbon atoms, Ra's may be identical to or different from each other;
- n represents an integer of from 1 to 50;
- the transition metal compound (A) is a double crosslinked metallocene complex represented by a formula (I):
- M represents a metal element of Groups 3 to 10 of the periodic table or the lanthanoid series;
- E1 and E2 each represent a ligand selected from a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a heterocyclopentadienyl group, a substituted heterocyclopentadienyl group, an amide group, a phosphide group, a hydrocarbon group, and a silicon-containing group, form a crosslinked structure via A1 and A2, and may be identical to or different from each other;
- X represents a σ-bonding ligand, and when a plurality of X's are present, the plurality of X's may be identical to or different from each other, and X may be crosslinked with any other X, E1, E2, or Y;
- Y represents a Lewis base, and when a plurality of Y's are present, the plurality of Y's may be identical to or different from each other, and Y may be crosslinked with any other Y, E1, E2, or X;
- A1 and A2 each represent a divalent crosslinking group for bonding two ligands, and each represent a hydrocarbon group having 1 to 20 carbon atoms, a halogen-containing hydrocarbon group having 1 to 20 carbon atoms, a silicon-containing group, a germanium-containing group, a tin-containing group, —O—, —CO—, —S—, —SO2—, —Se—, —NR1—, —PR1—, —P(O)R1—, —BR1—, or —AlR1—, wherein R1 represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, or a halogen-containing hydrocarbon group having 1 to 20 carbon atoms, and may be identical to or different from each other;
- q represents an integer of from 1 to 5 representing [(valence of M)−2];
- and
- r represents an integer of from 0 to 3.
An olefin polymerization catalyst, which is obtained by contacting components (A) to (D) with each other:
- (A) a transition metal compound;
- (B) a boron compound capable of forming an ion pair with the component (A);
- (C) an organoaluminum compound represented by a formula (VIII):
- R17vAlJ3-v (VIII)
- (D) an aluminoxane represented by a formula (i) or (ii):
- wherein:
- R17 represents an alkyl group having 1 to 20 carbon atoms;
- J represents a hydrogen atom, an alkoxy group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or a halogen atom;
- v represents an integer of from 1 to 3, and when v represents 2 or more, R17's may be identical to or different from each other, provided that at least one R17 represents an alkyl group having 1 to 20 carbon atoms;
- Ra represents an alkyl group having 1 to 20 carbon atoms, Ra's may be identical to or different from each other, and n represents an integer of from 1 to 50;
- the transition metal compound (A) is a double crosslinked metallocene complex represented by a formula (I):
- M represents a metal element of Groups 3 to 10 of the periodic table or the lanthanoid series;
- E1 and E2 each represent a ligand selected from a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a heterocyclopentadienyl group, a substituted heterocyclopentadienyl group, an amide group, a phosphide group, a hydrocarbon group, and a silicon-containing group, form a crosslinked structure via A1 and A2, and may be identical to or different from each other;
- X represents a α-bonding ligand, and when a plurality of X's are present, the plurality of X's may be identical to or different from each other, and X may be crosslinked with any other X, E1, E2 or Y;
- Y represents a Lewis base, and when a plurality of Y's are present, the plurality of Y's may be identical to or different from each other, and Y may be crosslinked with any other Y, E1, E2, or X;
- A1 and A2 each represent a divalent crosslinking group for bonding two ligands, and each represent a hydrocarbon group having 1 to 20 carbon atoms, a halogen-containing hydrocarbon group having 1 to 20 carbon atoms, a silicon-containing group, a germanium-containing group, a tin-containing group, —O—, —CO—, —S—, —SO2—, —Se—, —NR1—, —PR1—, —P(O)R1—, —BR1—, or —AlR1—, wherein R1 represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, or a halogen-containing hydrocarbon group having 1 to 20 carbon atoms, and may be identical to or different from each other;
- q represents an integer of from 1 to 5 representing [(valence of M)−2];
- and
- r represents an integer of from 0 to 3.
Dependencies are inferred from the claim text.