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AssigneeRohm and Haas Company
InventorsJon Busick, Philippe P. Maillot, Joy L. Mendoza
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The present invention provides materials for improving the ignition of gaseous reactants in metal catalyzed oxidation reactions comprising a metal catalyst gauze, preferably, a platinum/rhodium catalyst gauze, having in contact therewith, from 0.25 to 1.5 wt. %, based on the weight of the metal catalyst gauze, of one or more pieces of previously used metal catalyst gauze. Further, methods of making the metal catalyst materials comprise shaping the pieces of previously used metal catalyst gauze and placing them equidistant from each other in contact with or on the surface of the metal catalyst gauze. And methods of using the materials comprise feeding into the reactor a gas mixture of oxygen or air and one or more reactant gases, and igniting the gas mixture at the surface of one or more or all of the pieces of previously used metal catalyst.
A metal catalyst material comprising a metal catalyst gauze having in contact therewith, from 0.5 to 1.5 wt. %, based on the weight of the metal catalyst gauze, of one or more pieces of previously used and untreated metal catalyst gauze, that have not been contaminated with iron and that have not been contaminated with foreign debris, hydrocarbons, or oil as tested by visual inspection, the one or more pieces placed equidistant from each other on the surface of the metal catalyst gauze, or, if one piece, placed in contact with or concentrically with the center of the metal catalyst gauze, wherein the previously used and untreated metal catalyst gauze does not contain a metal coating treatment.
Dependencies are inferred from the claim text.