Flame-retardant poly lactic acid-containing film or sheet, and method for manufacturing thereof
AssigneeNitto Denko Corporation
InventorsHiroki Senda, Shigeki Ishiguro
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Abstract
A film or sheet composed of a resin composition including a poly lactic acid (A), an acidic functional group-modified olefinic polymer (B) including an acidic functional group and having an acid value of 10 to 70 mg KOH/g and a weight average molecular weight of 10,000 to 80,000, a tetrafluoroethylene polymer (C), and an aromatic cyclic phosphazene-containing flame retardant (D) including a compound of Formula (I) and in (D) is included in an amount of 10 to 70 parts by weight based on 100 parts by weight of (A), and a method for manufacturing the film or sheet by melt film formation.
Claims16
A method for manufacturing a film or sheet, comprising:
- forming the film from a resin composition by melt film formation,
- the resin composition comprising:
- a poly lactic acid (A);
- an acidic functional group-modified olefinic polymer (B) including an acidic functional group and having an acid value of 10 to 70 mg KOH/g and a weight average molecular weight of 10,000 to 80,000;
- a tetrafluoroethylene polymer (C);
- and
- an aromatic cyclic phosphazene-containing flame retardant (D) including a compound of Formula (I′),
- the aromatic cyclic phosphazene-containing flame retardant (D) being included in an amount of 10 to 70 parts by weight based on 100 parts by weight of the poly lactic acid (A),
- wherein each of X1 and X2 is independently an alkyl group having 1 to 4 carbon atoms;
- each of m1 and m2 is independently an integer of 0 to 4, and n is an integer of 3 to 6;
- the resin composition during the melt film formation having a temperature between a temperature 15° C. higher than a crystallization temperature (Tc) of the resin composition in a temperature drop process and a temperature 5° C. lower than a melting temperature (Tm) in a temperature rise process or
- the melt film formed resin composition being cooled and solidified after a crystallization accelerating step of keeping the resin composition between a temperature 25° C. lower than a crystallization temperature (Tc) of the resin composition in a temperature drop process and a temperature 10° C. higher than the crystallization temperature (Tc).
Dependencies are inferred from the claim text.