Antimicrobial polymer
AssigneeFachhochschule Münster
InventorsMartin Kreyenschmidt, Reinhard Lorenz, Björn Fischer, Judith Kreyenschmidt, Florian Brodkorb, Katrin Kalbfleisch, Tobias Blang, Adrian Geschwentner
Life of this patent
Estimating the term…
Abstract
The invention is directed to an antimicrobial polymer that can preferably be processed thermoplastically, a method for the preparation of said antimicrobial polymer and its use in antimicrobial treatment. The invention is further directed to polymer blends containing antimicrobial polymers and the use of special monomers in the preparation of antimicrobial polymers that can be processed thermoplastically.
Claims20
A composition consisting essentially of an antimicrobial polymer obtainable by polymerizing a monomer, whereby the monomer is represented by the structural formulas IIa to IIc or mixtures thereof,
- wherein the residue R is ethyl, propyl, butyl, pentyl, hexyl and heptyl, cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl isopropyl, sec-butyl, iso-butyl, tert-butyl, 2-pentyl (sec. pentyl), 3-pentyl, 2-methyl-butyl, 3-methyl-butyl (isopentyl), 3-methyl-but-2-yl, 2-methylbut-2-yl, 2,2-dimethylpropyl (neopentyl), 2-methylpentyl, 3-methylpentyl, 2,3-dimethylbutyl, 2,2-dimethylbutyl (neohexyl) or 3-ethylpentyl,
- wherein the antimicrobial polymer's glass temperature is 60° C. to 200° C., and
- wherein the composition is a thermoplastic.
A composition comprising an antimicrobial copolymer obtainable by reacting at least one monomer of formulas IIa to IIc,
- wherein the residue R is ethyl, propyl, butyl, pentyl, hexyl and heptyl, cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl isopropyl, sec-butyl, iso-butyl, tert-butyl, 2-pentyl (sec. pentyl), 3-pentyl, 2-methyl-butyl, 3-methyl-butyl (isopentyl), 3-methyl-but-2-yl, 2-methylbut-2-yl, 2,2-dimethylpropyl (neopentyl), 2-methylpentyl, 3-methylpentyl, 2,3-dimethylbutyl, 2,2-dimethylbutyl (neohexyl) or 3-ethylpentyl,
- with at least one further monomer,
- wherein the copolymer's glass temperature TG is 65° C. to 230° C., and
- wherein the composition is a thermoplastic.
An antimicrobial polymer blend containing an antimicrobial polymer obtainable by polymerizing a monomer having a structure according to formula I
- A-B-C′-D (I),
- wherein
- A is a radically polymerizable group of the formula —CRV1═CRV2RV3, wherein RV1, RV2 and RV3, independently of each other, are hydrogen, methyl, chloride, cyano or ester groups,
- B is an aromatic spacer,
- C′ is an aliphatic spacer of the formula —CRS1RS2—, wherein RS1 and RS2, independently of each other, are hydrogen or methyl, and
- D is an amine of the formula —NRA1RA2, wherein
- RA1 is a non-aromatic group with 2 to 7 carbon atoms, and
- RA2 is hydrogen, methyl or a non-aromatic group with 2 to 7 carbon atoms, wherein
- RA1 and RA2 are connected to each other and form a ring together with the nitrogen, wherein the ring includes 3 to 6 carbon atoms, wherein the ring formed can carry up to 4 methyl groups, wherein the polymer's glass temperature TG is 60° C. to 200° C.,
- and/or
- a copolymer obtainable by reacting at least one monomer of the formula I, wherein groups A, B, C′ and D are defined as set out above and at least one further monomer,
- wherein the copolymer's glass temperature TG is 65° C. to 230° C.,
- and
- at least one blend polymer, and
- wherein the polymer blend is a thermoplastic.
Dependencies are inferred from the claim text.