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US 10,131,817 B2Granted
Cationically cross-linkable/polymerizable composition comprising an iodonium borate and releasing an acceptable odor
AssigneeElkem Silicones France SAS
InventorsJean-Marc Frances, Guillaume Pibre
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Abstract
A photoinitiator composition is described that includes a specific iodonium salt combined with a hydrogen donor that is a Guerbet alcohol that can also act as a solvent. This initiator system can solve problems concerning odor, in particular after the polymerization/cross-linking of conventional iodonium salts.
Claims65
A composition P comprising:
- 1) at least one iodonium salt A of formula (I)′ below:
- wherein:
- the symbols R1 and R2 are identical or different, and each represent a linear or branched alkyl radical having from 10 to 30 carbon atoms
- a and b are integers such that 0≤a≤3, 1≤b≤4 and a+b=4,
- c and c′ are integers, which are identical or different, ranging from 1 to 5,
- the symbols X, which are identical or different, represent:
- a chlorine or fluorine atom with 0≤a≤3, or
- an OH function with 0≤a≤2, and
- the symbols R3, which are identical or different, represent:
- a phenyl radical substituted with:
- at least 2 halogen atoms, or
- at least one electron-withdrawing group selected from the group consisting of:
- —CF3, —OCF3, —NO2, —CN, —SO2—CnF2n+, —(CO)—CnF2n+1, —O—CnF2n+1 and —CnF2n+1, with n being an integer from 1 to 20, or
- an aryl radical containing at least two aromatic nuclei, optionally substituted with at least one halogen atom, or an electron-withdrawing group selected from the group consisting of:
- —CF3, —OCF3, —NO2, —CN, —SO2—CnF2n+, —(CO)—CnF2n+1, —O—CnF2n+1 and —CnF2n+1, with n being an integer from 1 to 20,
- 2) at least one hydrogen donor B selected from the group consisting of Guerbet alcohols of formula (II) below:
- wherein:
- the symbols R4 and R5 are identical or different, and each represent an alkyl radical having from 4 to 12 carbon atoms, and
- with the additional condition that the total number of carbon atoms of said Guerbet alcohol is from 10 to 20 carbon atoms, and
- 3) optionally at least one thermal stabilizer C.
17 more elements
Dependencies are inferred from the claim text.