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US 10,131,792 B2Granted
Method for treating the surface of particles, the thus obtained particles and use thereof
AssigneeHuntsman P&A Germany GmbH
InventorsPetra Fritzen, Bernd Rohe, Jörg Hocken
Life of this patent
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Abstract
A method for producing surface-treated particles includes surface treatment of titanium dioxide, barium sulfate, zinc sulfide or lithopone particles, and to mixtures of the particles with alkoxylated siloxanes and phthalate-free plasticizers for improving dispersion in plastics.
Claims15
Particles comprising:
- TiO2, BaSO4, ZnS or lithopone with a coating comprising at least one compound of formula (I)
- in which
- R is methyl,
- R1 is a polyether group of formula (II):
- —Z—(O—CmH2m-(n-1))o—[O-(EOx,POy,BOz)—R3]n (II),
- in which
- Z is equal to an unbranched alkylene group having 2 to 4 carbon atoms,
- m is 2 to 4
- n is 1 to 3,
- o is 0,
- EOx, POy, BOz is an oxyalkylene group, containing oxyethylene (EO), oxypropylene (PO) and/or oxybutylene (BO) units, wherein x is 3 to 5, y is 10 to 25 and z is 0,
- R3 is hydrogen,
- and with the provision that in R1 the sum of carbon and oxygen atoms is at least 70,
- a is 80 to 95,
- b is 5 to 8, and
- comprising at least one phthalate-free plasticiser,
- wherein the at least one compound of formula (I) is present with a proportion of from 0.01 to 2% by weight, and at least one phthalate-free plasticiser is present with a proportion of from 0.01 to 4.0% by weight, wherein the values in % by weight relate to the weight of the used dried primary particles,
- wherein the at least one phthalate-free plasticiser comprises:
- esters of aliphatic hydrocarbons having 6 to 21 carbon atoms with at least one acid group selected from the group consisting of a carboxyl group, a sulfonyl group, and a sulfinyl group, with a monovalent or polyvalent aliphatic alcohol having 6 to 20 carbon atoms or a monovalent or bivalent aromatic alcohol, or
- esters of aromatic 1,4-(para)dicarboxylic acids or aromatic tricarboxylic acids with a monovalent or polyvalent aliphatic alcohol having 6 to 20 carbon atoms.
17 more elements
Dependencies are inferred from the claim text.