Optimized process for preparing methacrylic acid
AssigneeEvonik Röhm GmbH
InventorsSteffen Krill, Rudolf Burghardt, Melanie Raczek, Torsten Balduf
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Abstract
The present invention relates to an optimized process for preparing methacrylic acid, wherein methacrolein is prepared in a first stage from propionaldehyde and formaldehyde by means of a Mannich reaction and oxidized in a second stage to methacrylic acid. More particularly, the present invention relates to the reduction in the amounts of catalyst to be used in the first stage, especially to the reduction in the amounts of acid to be used here, by virtue of the additional installation of recycling streams suitable for the purpose.
Claims15
A process for continuously preparing methacrylic acid, comprising:
- a first process step comprising preparing methacrolein from formaldehyde and propionaldehyde with at least one acid and at least one organic base as catalysts in a reactor 1 to obtain a converted reaction solution comprising methacrolein and a catalyst-containing aqueous phase, then
- a second process step comprising:
- separating methacrolein from the catalyst-containing aqueous phase and oxidizing the methacrolein to methacrylic acid with a heterogeneous catalyst in the presence of oxygen and water in a reactor 2, to obtain a process gas, then
- condensing and quenching the process gas to produce an aqueous crude methacrylic acid, and then
- separating the methacrylic acid from an aqueous phase of the aqueous crude methacrylic acid with an extractant to obtain an extracted aqueous phase comprising carboxylic acids, and
- recycling the extracted aqueous phase into reactor 1.
Dependencies are inferred from the claim text.