# US 10,122,055 B2 · Johnson ambient-heat engine

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- Number: US 10,122,055 B2
- Document ID: US10122055B2
- Status: Granted
- Kind: B2
- Application number: 15/175,708
- Filed: 2016-06-07
- Published: 2016-09-29
- Granted: 2018-11-06
- Earliest claimed: 2010-09-09
- Assignees: Johnson IP Holding, LLC
- Applicants: Johnson IP Holding, LLC
- Inventors: Lonnie G. Johnson
- Web page: https://patentgrep.com/patent/US10122055B2

## CPC

- H01M 8/04104: {Regulation of differential pressures}
- B01J 19/088: {giving rise to electric discharges (for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00)}
- H01M 8/04074: {Heat exchange unit structures specially adapted for fuel cell}
- H01M 8/04201: {Reactant storage and supply, e.g. means for feeding, pipes}
- H01M 8/04208: {Cartridges, cryogenic media or cryogenic reservoirs}
- H01M 8/04216: {characterised by the choice for a specific material, e.g. carbon, hydride, absorbent}
- H01M 8/04365: {of other components of a fuel cell or fuel cell stacks}
- H01M 8/04388: {of anode reactants at the inlet or inside the fuel cell}
- H01M 8/04552: {of the individual fuel cell}
- H01M 8/04955: Shut-off or shut-down of fuel cells
- H01M 8/065: by dissolution of metals or alloys; by dehydriding metallic substances
- H01M 14/00: Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
- H01M 16/003: {of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers}
- H01M 16/006: {of fuel cells with rechargeable batteries}
- B01J 2219/0805: giving rise to electric discharges
- H02J 7/345: {using capacitors as storage or buffering devices}
- H02J 7/63: against overdischarge
- Y02E 60/10: Energy storage using batteries
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- H02J: ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An ambient-heat engine has a substantially thermally-conductive housing whose interior is divided into a high-pressure chamber and a low-pressure chamber by a substantially gas-impermeable barrier. An ionically-conductive, electrical-energy-generating mechanism forms at least a portion of the barrier. First hydrogen-storage medium is disposed within the high-pressure chamber and second hydrogen-storage medium is disposed within the low-pressure chamber. An electrical-energy storage device connected to the ionically-conductive, electrical-energy-generating mechanism is operable between a charge condition and a discharge condition. In a charge condition, hydrogen atoms within the high-pressure chamber are converted to hydrogen ions and conducted through the electrical-energy-generating mechanism to the low-pressure chamber causing electrical-energy to be generated to the electrical-energy storage device. When the electrical-energy storage device is in a discharge condition an electric current is passed through the electrical-energy-generating mechanism causing hydrogen in the low-pressure chamber to convert to hydrogen ions and conduct through the electrical-energy-generating mechanism to the high-pressure chamber.

## Claims

### Claim 1

A rechargeable hydrogen electrochemical energy storage system comprising:
a housing defining an interior;
a substantially gas-impermeable barrier dividing said interior into a high-pressure hydrogen storage chamber and a low-pressure hydrogen storage chamber, at least a portion of said substantially gas-impermeable barrier comprising a proton conductive membrane electrode assembly, the proton conductive membrane electrode assembly comprising at least one pair of opposing electrodes and a proton conductive membrane sandwiched between the opposing electrodes;
a quantity of hydrogen disposed within said housing wherein at least a first portion of said quantity of hydrogen is initially disposed within said high-pressure chamber at a higher pressure than a second portion of said quantity of hydrogen disposed within said low-pressure chamber, the proton conductive membrane electrode assembly being configured to facilitate the conduction of hydrogen between the high pressure hydrogen storage chamber and the low pressure hydrogen storage chamber;
a first metal hydride storage material disposed within said high-pressure chamber and a second metal hydride storage material disposed within said low-pressure chamber; and
a controller system coupled to the electrodes of the proton conductive membrane electrode assembly,
wherein, in a first state of the storage system, the storage system is discharged whereby electrical power is generated as hydrogen is released by the first metal hydride storage material in said high-pressure hydrogen storage chamber and conducted through said proton conductive membrane electrode assembly to said low-pressure hydrogen storage chamber wherein it is absorbed by the second metal hydride storage material contained therein, the electrical power being generated as hydrogen molecules are separated in to protons and electrons, the electrons being conducted externally between the electrodes of the proton conductive membrane electrode assembly and the protons being conducted through the proton conductive membrane of the proton conductive membrane electrode assembly,
wherein, in a second state of the storage system, the storage system is recharged by the application of electrical power to the proton conductive membrane electrode assembly to pump hydrogen from the low-pressure hydrogen storage chamber to said high-pressure hydrogen storage chamber wherein it is absorbed by the first metal hydride storage material contained therein, and
wherein the controller system is configured to selectively place the storage system in one of the first state in which the storage system is discharged by the controller system extracting electrical power from the proton conductive membrane electrode assembly and the second state in which the storage system is charged by the controller system supplying electrical power to the proton conductive membrane electrode assembly.

### Claim 2 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein the housing comprises a substantially thermally-conductive material.

### Claim 3 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein each of the opposing electrodes includes a porous current collector.

### Claim 4 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein each of the opposing electrodes includes a catalyst.

### Claim 5 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein said first metal hydride storage material and said second metal hydride storage material each comprises one of MnNi3Co2, LaNi4.7Al0.3, TiCo, and Pd0.7Ag0.3.

### Claim 6 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein said first metal hydride storage material comprises one of MnNi3Co2 and LaNi4.7Al0.3 and said second metal hydride storage material comprises one of TiCo and Pd0.7Ag0.3.

### Claim 7 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein said first metal hydride storage material comprises MnNi3Co2 and said second metal hydride storage material comprises one of Pd0.7Ag0.3 and LaNi4.7Al0.3.

### Claim 8 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein said first metal hydride storage material comprises TiCo and said second metal hydride storage material comprises Pd0.7Ag0.3.

### Claim 9 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein a portion of said substantially gas-impermeable barrier comprises a thermally-conductive interface separating said first metal hydride storage material from said second metal hydride storage material.

### Claim 10 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein at any given temperature, the first metal-hydride storage material stores hydrogen at a first average storage pressure that is higher than a second average storage pressure at which the second metal hydride storage material stores hydrogen.

### Claim 11 (depends on 1)

The rechargeable hydrogen electrochemical energy storage system of claim 1, wherein the first metal-hydride storage material, the second metal-hydride storage material and an ambient environment are thermally coupled.

### Claim 12 (depends on 11)

The rechargeable hydrogen electrochemical energy storage system of claim 11, wherein as one of the first and second metal-hydride storage materials undergoes an endothermic process of releasing hydrogen or an exothermic process of absorbing hydrogen, thermal energy needed or removed to maintain a uniform temperature of the system is thermal energy supplied to or from the ambient environment.