# US 10,122,049 B2 · Gelated ionic liquid film-coated surfaces and uses thereof > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,122,049 B2 - Document ID: US10122049B2 - Status: Granted - Kind: B2 - Application number: 15/116,802 - Filed: 2015-02-06 - Published: 2016-12-01 - Granted: 2018-11-06 - Earliest claimed: 2014-02-06 - Assignees: Gelion Technologies Pty Ltd - Applicants: Gelion Technologies Pty Ltd - Inventors: Thomas Maschmeyer; Max Easton; Antony Ward - Web page: https://patentgrep.com/patent/US10122049B2 ## CPC - H01M 10/365: {Zinc-halogen accumulators} - H01M 4/388: {Halogens} - H01M 4/661: {Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence)} - H01M 4/663: {containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres} - H01M 8/188: {by recharging of redox couples containing fluids; Redox flow type batteries} - H01M 10/36: Accumulators not provided for in groups H01M10/05-H01M10/34 - H01M 8/20: Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) - H01M 10/0565: Polymeric materials, e.g. gel-type or solid-type - H01M 2004/023: {Gel electrode} - H01M 2300/0085: Immobilising or gelification of electrolyte - Y02E 60/10: Energy storage using batteries - Y02E 60/50: Fuel cells - Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product - H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION - Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS ## Abstract The invention relates to an assembly comprising a first gelated ionic liquid film in contact with a first electrically conductive surface, wherein the first gelated ionic liquid film comprises a first ionic liquid encapsulated within a gel matrix; and a second gelated ionic liquid film in contact with a second electrically conductive surface, wherein the second gelated ionic liquid film comprises a second ionic liquid encapsulated within a gel matrix; wherein the first and second gelated ionic liquid films are in contact with each other. There is also described an electrochemical cell comprising an assembly according to the invention, and methods for producing same. ## Claims ### Claim 1 An electrochemical cell comprising: a first gelated ionic liquid film in contact with a first electrically conductive surface, wherein the first gelated ionic liquid film comprises a first ionic liquid encapsulated within a first gel matrix; and a second gelated ionic liquid film in contact with a second electrically conductive surface, wherein the second gelated ionic liquid film comprises a second ionic liquid encapsulated within a second gel matrix; wherein the first and second gelated ionic liquid films are in contact with each other, and wherein the first gelated ionic liquid film further comprises a dissolved redox species, wherein the dissolved redox species is a halogen. ### Claim 2 (depends on 1) The electrochemical cell of claim 1, wherein either or both of: (i) one or both of the first and second ionic liquid comprises one or more anions selected from the group consisting of a halogen, a sulfonylimide, a carboxylate, and a fluorinated phosphate anion; and (ii) one or both of the first and second ionic liquid comprises one or more cations selected from the group consisting of an alkylpyridinium, a dialkylimidazolium, a dialkylpyrrolidinium, a tetraalkylphosphonium, and a tetraalkylammonium cation. ### Claim 3 (depends on 2) The electrochemical cell of claim 2, wherein the first and second electrically conductive surfaces are inert electrodes. ### Claim 4 (depends on 3) The electrochemical cell of claim 3, wherein each inert electrode independently comprises one or more of graphite, doped carbon nanotubes, non-doped carbon nanotubes, doped graphene, non-doped graphene, a graphene composite, carbon paper, platinum, gold, or titanium. ### Claim 5 (depends on 3) The electrochemical cell of claim 3, wherein the first electrically conductive surface is an anode, and the second electrically conductive surface is a cathode. ### Claim 6 (depends on 1) The electrochemical cell of claim 1, wherein the first and second gelated ionic liquid films are immiscible when in contact with each other. ### Claim 7 (depends on 1) The electrochemical cell of claim 1, wherein the first and/or second gelated ionic liquid film has a thickness of between about 50 μm and about 10 mm. ### Claim 8 (depends on 1) The electrochemical cell of claim 1, wherein the first and/or second encapsulated ionic liquid comprises at least one of: (i) one or more anions selected from the group consisting of bromide, chloride, iodide, bis(trifluoromethyl-sulfonyl)imide, bis(fluorosulfonyl)imide, acetate, propionate, pentanoate, hexanoate, hexafluorophosphate, and tris(pentafluoro)trifluorophosphate; and (ii) one or more cations selected from the group consisting of 1-butylpyridinium, 1-octylpyridinium, 1-(2-hydroxyethyl)pyridinium, 1-ethyl-3-methylimidazolium, 1-butyl-3-methylimidazolium, 1-pentyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, 1-(2-methoxyethyl)-3-methylimidazolium, 1-(1-methoxymethyl)-3-methylimidazolium, 1-methyl-3-octylimidazolium, 1-methyl-1-ethylpyrolidinium, 1-methyl-1-butylpyrrolidinium, 1-methyl-1-hexylpyrolidinium, 1-(2-methoxyethyl)-1-methylpyrrolidinium, 1-(1-methoxymethyl)-1-methylpyrrolidinium, tetrabutylphosphonium, tributyloctylphosphonium, tributyl(2-methoxyethyl)phosphonium, tributyl-tert-butylphosphonium, tributyl(1-methoxymethyl)phosphonium, tetraethylammonium, tetrabutylammonium, tributyloctylammonium, tributyl(2-methoxyethyl)ammonium, tributyl(1-methoxymethyl)ammonium, and tributyl-tert-butylammonium. ### Claim 9 (depends on 1) The electrochemical cell of claim 1, wherein said first and second gel matrices are formed from a gelating agent selected from one or more of a hydroxy-substituted organic compound, a polysaccharide, a dipeptide, a protein, a polymer, a poly(vinylidene fluoride-co-hexafluoropropylene) polymer, carbon nanotubes, non-doped or doped graphene, functionalised silica nanospheres, and a silica sol-gel. ### Claim 10 (depends on 1) The electrochemical cell of claim 1, wherein the second gelated ionic liquid film further comprises a second dissolved redox species selected from the group consisting of: (a) an acetate, nitrate, sulfate, or triflate salt of Li+, Mg2+, Zn2+, Cu+/2+, Fe2+/3+, Co2+/3+, Mn2+, or Cr3+; (b) an oxygen, permanganate, dichromate, perchlorate, or halide salt of Li+, K+, Ca2+, Na+, or Mg2+; and (d) a mixture of (a) and (b). ### Claim 11 (depends on 1) The electrochemical cell of claim 1, wherein one or more of: either or both of the first and second gelated ionic liquid film comprises two or more different ionic liquids; (ii) either or both of the first and second gelated ionic liquid film comprises two or more cations and two or more anions that together form a eutectic mixture; and (iii) either or both of the first and second gelated ionic liquid film further comprises an electrolyte salt. ### Claim 12 (depends on 1) The electrochemical cell of claim 1, wherein either or both of the first and second gelated ionic liquid film further comprises an electrolyte salt. ### Claim 13 (depends on 12) The electrochemical cell of claim 12, wherein the electrolyte salt is soluble in at least one of the first ionic liquid and the second ionic liquid. ### Claim 14 (depends on 1) The electrochemical cell of claim 1, which further comprises: a third gelated ionic liquid film in contact with a third electrically conductive surface, wherein the third gelated ionic liquid film comprises a third ionic liquid encapsulated within a third gel matrix; and wherein the second and third gelated ionic liquid films are at least partially in contact with each other. ### Claim 15 (depends on 14) The electrochemical cell of claim 14, wherein at least one of: the second and third gelated ionic liquid films are immiscible with each other; and the first and third electrically conductive surfaces are anodes and the second electrically conductive surface is a cathode. ### Claim 16 (depends on 1) A method of producing the electrochemical cell of claim 1, comprising: providing a first gelated ionic liquid film comprising a first encapsulated ionic liquid in contact with a first electrically conductive surface; providing a second gelated ionic liquid film comprising a second encapsulated ionic liquid in contact with a second electrically conductive surface; and contacting the first and second gelated ionic liquid films with each other. ### Claim 17 (depends on 16) The method of claim 16, wherein at least one of said steps of providing comprises: combining a gelating agent with an ionic liquid at a suitable temperature to produce a mixture, and allowing the gelating agent to set and thereby form a gelated ionic liquid film in which the ionic liquid is encapsulated; and contacting the mixture or the gelated ionic liquid film with an electrically conductive surface. ### Claim 18 (depends on 17) The method of claim 17, wherein the mixture is contacted with the electrically conductive surface prior to allowing the gelating agent to set. ### Claim 19 (depends on 16) The method of claim 16 further comprising: providing a third gelated ionic liquid film comprising a third encapsulated ionic liquid in contact with a third electrically conductive surface; and contacting the second and third gelated ionic liquid films.