# US 10,122,009 B2 · Co-extrusion print head for multi-layer battery structures

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- Number: US 10,122,009 B2
- Document ID: US10122009B2
- Status: Granted
- Kind: B2
- Application number: 15/098,735
- Filed: 2016-04-14
- Published: 2016-08-04
- Granted: 2018-11-06
- Earliest claimed: 2012-12-27
- Assignees: Palo Alto Research Center Incorporated
- Applicants: Palo Alto Research Center Incorporated
- Inventors: Corie Lynn Cobb
- Web page: https://patentgrep.com/patent/US10122009B2

## CPC

- B29C 48/07: Flat, e.g. panels
- B05C 5/02: {the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g.} from an outlet device in contact or almost in contact, with the work
- B29C 48/21: the layers being joined at their surfaces
- B29C 48/307: {specially adapted for bringing together components, e.g. melts within the die}
- H01M 4/0411: {by extrusion}
- H01M 4/0483: {by methods including the handling of a melt (H01M4/0438, take precedence)}
- H01M 10/0404: {Machines for assembling batteries}
- B29C 48/08: flexible, e.g. films
- B29C 48/154: Coating solid articles, i.e. non-hollow articles
- B29L 2031/3468: {Batteries, accumulators or fuel cells (battery cases B29L2031/7146)}
- H01M 4/0435: {Rolling or calendering}
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B05C: APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL (spraying apparatus, atomising apparatus, nozzles B05B; plant for applying liquids or other fluent materials to objects by electrostatic spraying B05B5/08)
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- B29L: INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A co-extrusion print head capable of extruding at least two layers vertically in a single pass having a first inlet port connected to a first manifold, a first series of channels connected to the first inlet port arranged to receive a first fluid from the first inlet port, a second inlet port connected to one of either a second manifold or the first manifold, a second series of channels connected to the second inlet port arranged to receive a second fluid from the second inlet port, a merge portion of the print head connected to the first and second series of channels, the merge portion arranged to receive the first and second fluids, and an outlet port connected to the merge portion, the outlet port arranged to deposit the first and second fluids from the merge portion as a vertical stack on a substrate.

## Claims

### Claim 1

A method of manufacturing a vertically stacked electrical structure, comprising:
receiving a first material slurry at a first inlet port in a multi-layer co-extrusion print head comprising a set of plates stacked together, the first inlet port connected to a first manifold and a first series of channels arranged to receive the first material slurry from the first fluid inlet port;
receiving a second material slurry at a second inlet port in the print head, the second inlet port connected to one of either a second manifold or the first manifold, the second inlet port connected to a second series of channels arranged to receive the second material slurry from the second inlet port;
receiving a third material slurry at a third inlet port in the print head, a third series of channels connected to the third inlet port arranged to receive the third material slurry from the third inlet port;
receiving the first material slurry from the first series of channels at a merge portion and receiving the third material slurry from the third series of channels at the merge portion;
merging the first material slurry and the third material slurry inside the print head to form a horizontally interdigitated layer;
receiving the second material slurry at the merge portion from the second series of channels, wherein the second series of channels are arranged vertically to the first and third series of channels;
merging the interdigitated layer and the second material slurry vertically inside the print head; and
depositing the interdigitated layer and the second material slurry simultaneously onto a substrate in a vertical stack.

### Claim 2 (depends on 1)

The method of claim 1, further comprising calendaring the vertical stack.

### Claim 3 (depends on 1)

The method of claim 1, wherein depositing the interdigitated layer and the second material slurry comprises depositing at a flow rate sufficient to evenly distribute layers for each material.

### Claim 4 (depends on 1)

The method of claim 1, wherein depositing comprises moving the substrate past the multi-layer co-extrusion print head, wherein the print head is fixed in place.

### Claim 5 (depends on 1)

The method of claim 1, wherein depositing comprises moving the print head relative to the substrate, wherein the substrate is fixed in place.