# US 10,120,035 B2 · Monitoring and control of electrochemical cell degradation via strain based battery testing

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- Number: US 10,120,035 B2
- Document ID: US10120035B2
- Status: Granted
- Kind: B2
- Application number: 14/956,011
- Filed: 2015-12-01
- Published: 2017-06-01
- Granted: 2018-11-06
- Earliest claimed: 2015-12-01
- Assignees: Southwest Research Institute
- Applicants: Southwest Research Institute
- Inventors: Joe Steiber; Jeff Qiang Xu
- Web page: https://patentgrep.com/patent/US10120035B2

## CPC

- G01R 31/392: Determining battery ageing or deterioration, e.g. state of health
- G01R 31/3648: {comprising digital calculation means, e.g. for performing an algorithm}
- G01R: MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES (indicating correct tuning of resonant circuits H03J3/12)

## Abstract

A method and system for the monitoring and control of electrochemical cell degradation by use of strain-based battery testing. Strain-based battery is employed to recognize and implement a battery revival cycle to reduce battery degradation rates.

## Claims

### Claim 1

A computer-implemented method for monitoring and control of electrochemical cell degradation and state of health (SOH) of a battery comprising:
applying a strain gauge to said battery;
measuring a first strain of said battery (S1) using said strain gauge at an initial state of said battery ε;
exposing said battery to charge/discharge cycling;
measuring a second strain ε of said battery (S2) after said charge/discharge cycling, using said strain gauge, wherein said second strain is equal to εo+Δε, where Δε is the measured change in strain;
determining, by a controller, said measured change in strain Δε based on said measured first (S1) strain and said measured second strain (S2) of said battery, wherein said measured change in strain Δε is a function of battery voltage and the rate of change of said battery SOH varies with respect to strain;
determining, by the controller, a change in the SOH of said battery after said charge/discharge cycling; and
subsequent to determining the change in the SOH of said battery after said charge/discharge cycling, exposing said battery to a revival cycle comprising thermal treatment based on the SOH of said battery.

### Claim 2 (depends on 1)

The method of claim 1, wherein said strain gauge is applied with direct physical contact to said battery.

### Claim 3 (depends on 1)

The method of claim 1, wherein said strain gauge is applied to a strap, said strap configured to secure one or more battery cells of said battery.

### Claim 4 (depends on 1)

The method of claim 1, wherein said strain gauge is applied to said battery along a selected dimension comprising at least one of a length, width or height of said battery, said selected dimension based on a response of said battery to a change from said initial state to said aged state.

### Claim 5 (depends on 1)

The method of claim 1, wherein said strain gauge is applied to said battery along a selected dimension comprising any combination of length, width and height of said battery, said selected dimension based on a response of said battery to a change from said initial state to said aged state.

### Claim 6 (depends on 1)

The method of claim 1, wherein said strain gauge is applied to said battery along a selected dimension to measure a change in volume of said battery.

### Claim 7 (depends on 1)

The method of claim 1 wherein said thermal treatment comprises heating said battery at a temperature of less than or equal to 55° C.

### Claim 8

A computer-implemented method for monitoring and control of electrochemical cell degradation and state of health (SOH) of a battery comprising:
applying a strain gauge to said battery;
measuring a first strain of said battery (S1) using said strain gauge at an initial state of said battery εo;
exposing said battery to charge/discharge cycling;
measuring a second strain ε of said battery (S2) after said charge/discharge cycling, using said strain gauge, wherein said second strain is equal to εo+Δε, where Δε is the measured change in strain;
determining, by a controller, said measured change in strain based on said measured first (S1) strain and said measured second strain (S2) of said battery, wherein said measured change in strain Δε is a function of battery voltage and the rate of change of said battery SOH varies with respect to strain;
determining, by the controller, a change in the SOH of said battery after said charge/discharge cycling; and
exposing said battery to a revival cycle comprising thermal treatment wherein said battery SOH is determined to be less than or equal to 2.0%.

### Claim 9 (depends on 8)

The method of claim 8 wherein said charge/discharge cycling comprising a plurality of cycles.

### Claim 10 (depends on 9)

The method of claim 9, wherein said plurality of charge/discharge cycles comprises up to 200 cycles.

### Claim 11 (depends on 8)

The method of claim 8 wherein subsequent to said battery revival cycle said battery SOH is determined to be less than or equal to 1.0%.

### Claim 12

A computer-readable medium having stored thereon a plurality of non-transitory instructions that when executed by a controller result in the following operations for monitoring and control of electrochemical cell degradation and state of health (SOH) of a battery, wherein said battery includes a strain gauge:
causing to be measured a first strain of said battery (S1) using said strain gauge at an initial state of said battery εo;
causing to be exposed said battery to charge/discharge cycling;
causing to be measured a second strain ε of said battery (S2) after said charge/discharge cycling, using said strain gauge, wherein said second strain is equal to εo+Δε, where Δε is the measured change in strain;
determining, by a controller, said measured change in strain Δε based on said measured first (S1) strain and said measured second strain (S2) of said battery, wherein said measured change in strain Δε is a function of battery voltage and the rate of change of said battery SOH varies with respect to strain;
determining a change in the SOH of said battery after said charge/discharge cycling; and
exposing said battery to a revival cycle comprising thermal treatment wherein said battery SOH is determined to be less than or equal to a predetermined value.

### Claim 13 (depends on 12)

The computer-readable medium of claim 12, wherein said predetermined value is 2.0%.
