# US 10,119,340 B2 · Cutting elements, methods for manufacturing such cutting elements, and tools incorporating such cutting elements

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- Number: US 10,119,340 B2
- Document ID: US10119340B2
- Status: Granted
- Kind: B2
- Application number: 14/152,065
- Filed: 2014-01-10
- Published: 2014-05-08
- Granted: 2018-11-06
- Earliest claimed: 2009-05-20
- Assignees: Smith International, Inc.
- Applicants: Smith International, Inc.
- Inventors: J. Daniel Belnap; Georgiy Voronin; Feng Yu; Peter T. Cariveau; Youhe Zhang; Yuelin Shen; Guodong Zhan
- Web page: https://patentgrep.com/patent/US10119340B2

## CPC

- E21B 10/55: with preformed cutting elements
- E21B 10/567: with preformed cutting elements mounted on a distinct support, e.g. polycrystalline inserts
- B01J 3/062: {characterised by the composition of the materials to be processed}
- B01J 2203/062: Diamond
- B01J 2203/0655: Diamond
- B01J 2203/0685: Crystal sintering
- B22F 2003/244: {Leaching}
- B22F 2005/001: {Cutting tools, earth boring or grinding tool other than table ware}
- B22F 2998/10: Processes characterised by the sequence of their steps
- B22F 2999/00: Aspects linked to processes or compositions used in powder metallurgy
- B24D 3/10: for porous or cellular structure, e.g. for use with diamonds as abrasives
- C22C 26/00: Alloys containing diamond {or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes}
- C22C 2026/006: {with additional metal compounds being carbides}
- E21B 10/5735: {Interface between the substrate and the cutting element}
- E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B22F: WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER (making alloys by powder metallurgy C22C); APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B24D: TOOLS FOR GRINDING, BUFFING OR SHARPENING (abrading-bodies specially designed for tumbling apparatus, e.g. abrading-balls B24B31/14; honing tools B24B33/08; lapping tools B24B37/11)
- C22C: ALLOYS (treatment of alloys C21D, C22F)

## Abstract

The present disclosure relates to cutting elements incorporating polycrystalline diamond bodies used for subterranean drilling applications, and more particularly, to polycrystalline diamond bodies having a high diamond content which are configured to provide improved properties of thermal stability and wear resistance, while maintaining a desired degree of impact resistance, when compared to prior polycrystalline diamond bodies. In various embodiments disclosed herein, a cutting element with high diamond content includes a modified PCD structure and/or a modified interface (between the PCD body and a substrate), to provide superior performance.

## Claims

### Claim 1

A cutting element comprising:
a substrate comprising a substrate interface surface, the substrate interface surface comprising a protrusion; and
a polycrystalline diamond body comprising,
a diamond interface surface interfacing with the substrate interface surface,
a top surface opposite the diamond interface surface,
a cutting edge meeting the top surface, and
a material microstructure comprising a plurality of bonded-together diamond grains having an average grain size and interstitial regions between the diamond grains;
wherein at least a region of the polycrystalline diamond body has the following properties:
a diamond volume fraction, as measured by electron backscatter diffraction, greater than (0.9077)·(the diamond average grain size ^0.0221), with the diamond average grain size provided in microns, and
the diamond average grain size is not greater than 8 microns.

### Claim 2 (depends on 1)

The cutting element as recited in claim 1 wherein the substrate interface surface comprises an annular surface portion and wherein the protrusion is a step protrusion and comprises a diameter and a height as measured from the annular surface portion.

### Claim 3 (depends on 2)

The cutting element as recited in claim 2 wherein the substrate comprises a diameter and wherein the diameter of the protrusion is less than about 0.7 times the diameter of the substrate.

### Claim 4 (depends on 2)

The cutting element as recited in claim 2 wherein the substrate comprises a diameter and wherein the diameter of the protrusion is less than the diameter of the substrate but greater than half the diameter of the substrate.

### Claim 5 (depends on 2)

The cutting element as recited in claim 2 wherein the ratio of the height to the diameter of the protrusion is less than about 0.1.

### Claim 6 (depends on 1)

The cutting element as recited in claim 1 wherein the at least a region comprises a plurality of the interstitial regions that are substantially free of a catalyst material, and the at least a region extends from the cutting edge to a depth of at least 300 microns.

### Claim 7 (depends on 1)

The cutting element as recited in claim 1 wherein the at least a region comprises a plurality of the interstitial regions that are substantially free of a catalyst material, and wherein the at least a region extends from the cutting edge to a depth of at least 500 microns.

### Claim 8 (depends on 1)

The cutting element as recited in claim 1 wherein the at least a region has the following property:
the diamond volume fraction is greater than (0.9187)·(the average grain size ^ 0.0183).

### Claim 9 (depends on 1)

The cutting element as recited in claim 1 wherein the at least a region has the following property:
the diamond volume fraction is greater than (0.9291)·(the average grain size ^ 0.0148).

### Claim 10 (depends on 1)

The cutting element as recited in claim 1, wherein the diamond average grain size is not greater than 6 microns.

### Claim 11 (depends on 1)

A drill bit comprising a bit body and at least one cutting element as recited in claim 1 disposed on the bit body.

### Claim 12

A cutting element comprising:
a substrate comprising a substrate interface surface, the substrate interface surface comprising a protrusion; and
a polycrystalline diamond body formed by sintering at a cold cell pressure greater than 5.4 GPa, the polycrystalline diamond body comprising,
a diamond interface surface interfacing with the substrate interface surface,
a top surface opposite the diamond interface surface;
a cutting edge meeting the top surface; and
a material microstructure comprising a plurality of bonded-together diamond grains having an average grain size and interstitial regions between the diamond grains;
wherein at least a region of the polycrystalline diamond body satisfies one of the following conditions:
an average grain size within the range of 2-4 microns, and a diamond volume fraction greater than 93%, or
an average grain size within the range of 4-6 microns, and a diamond volume fraction greater than 94%, or
an average grain size within the range of 6-8 microns, and a diamond volume fraction greater than 95%, and
wherein the diamond volume fraction is that which is determined by electron backscatter diffraction.

### Claim 13 (depends on 12)

The cutting element as recited in claim 12 wherein the substrate interface surface comprises an annular surface portion and wherein the protrusion is a step protrusion and comprises a diameter and a height as measured from the annular surface portion.

### Claim 14 (depends on 13)

The cutting element as recited in claim 13 wherein the substrate comprises a diameter and wherein the diameter of the protrusion is less than about 0.7 times the diameter of the substrate.

### Claim 15 (depends on 13)

The cutting element as recited in claim 13 wherein the substrate comprises a diameter and wherein the diameter of the protrusion is less than the diameter of the substrate but greater than half the diameter of the substrate.

### Claim 16 (depends on 13)

The cutting element as recited in claim 13 wherein the ratio of the height to the diameter of the protrusion is less than about 0.1.

### Claim 17 (depends on 12)

The cutting element as recited in claim 12 wherein the at least a region comprises a plurality of the interstitial regions that are substantially free of a catalyst material, and wherein the at least a region extends from the cutting edge to a depth of at least 300 microns.

### Claim 18 (depends on 12)

The cutting element as recited in claim 12 wherein the at least a region comprises a plurality of the interstitial regions that are substantially free of a catalyst material, and wherein the at least a region extends from the cutting edge to a depth of at least 500 microns.

### Claim 19 (depends on 12)

A drill comprising a bit body and at least one cutting element as recited in claim 12 disposed on the bit body.
