# US 10,119,078 B2 · Method for converting carbon and hydrocarbon cracking and apparatus for hydrocarbon cracking

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- Number: US 10,119,078 B2
- Document ID: US10119078B2
- Status: Granted
- Kind: B2
- Application number: 15/623,957
- Filed: 2017-06-15
- Published: 2017-10-05
- Granted: 2018-11-06
- Earliest claimed: 2010-06-28
- Assignees: General Electric Company
- Applicants: General Electric Company
- Inventors: Zhigang Deng; Wenqing Peng; Chuan Lin; Shizhong Wang; Qijia Fu; Yanfei Gu; Zhaoping Wu; Yangang Liang; Minggang She
- Web page: https://patentgrep.com/patent/US10119078B2

## CPC

- C10G 9/00: Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- B01J 19/24: Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02)
- C01B 32/40: Carbon monoxide
- C01B 32/50: Carbon dioxide
- C10G 9/12: Removing incrustation
- C10G 9/36: with heated gases or vapours
- C10G 75/00: Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general (C10G7/10, C10G9/16 take precedence)
- B01J 2219/00245: Avoiding undesirable reactions or side-effects
- B01J 2219/24: Stationary reactors without moving elements inside
- C10G 2300/1044: Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
- C10G 2300/1059: Gasoil having a boiling range of about 330 - 427 °C
- C10G 2300/1081: Alkanes
- C10G 2300/807: Steam
- C10G 2400/20: C2-C4 olefins
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}

## Abstract

A method for converting carbon into a carbon oxide, comprises: contacting carbon with steam in presence of a carnegieite-like material of formula (Na2O)xNa2[Al2Si2O8], wherein 0<x≤1. Method and apparatus for hydrocarbon cracking are also described herein.

## Claims

### Claim 1

A method for hydrocarbon-cracking, comprising: contacting at least one hydrocarbon with steam in an apparatus having a contact surface accessible to the at least one hydrocarbon, the contact surface comprising a material of formula (Na2O)xNa2[Al2Si2O8] with carnegieite structure wherein 0<x<1.

### Claim 2 (depends on 1)

The method of claim 1, wherein the material is of formula Na4Al2Si2O9.

### Claim 3 (depends on 1)

The method of claim 1, wherein the contacting occurs at a temperature in a range from about 500° C. to about 870° C. and wherein the at least one hydrocarbon comprises at least one of ethane, propane, butane, heptane, liquid petroleum gas, naphtha, and gas oil.

### Claim 4 (depends on 1)

The method of claim 1, wherein the contacting occurs at a temperature in a range from about 800° C. to about 860° C. and wherein the at least one hydrocarbon comprises at least one of ethane, propane, butane, heptane, liquid petroleum gas, naphtha, and gas oil.

### Claim 5 (depends on 1)

The method of claim 1, wherein the material is a mixture of materials of formula (Na2O)xNa2[Al2Si2O3].
