# US 10,119,076 B2 · Gasifier and method of using the same for gasification of biomass and solid waste

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- Number: US 10,119,076 B2
- Document ID: US10119076B2
- Status: Granted
- Kind: B2
- Application number: 14/315,304
- Filed: 2014-06-25
- Published: 2014-10-16
- Granted: 2018-11-06
- Earliest claimed: 2011-12-29
- Assignees: Wuhan Kaidi General Research Institute of Engineering & Technology Co., Ltd.
- Applicants: Wuhan Kaidi General Research Institute of Engineering & Technology Co., Ltd.
- Inventors: Yilong Chen; Yanfeng Zhang; Minggui Xia; Liang Zhang
- Web page: https://patentgrep.com/patent/US10119076B2

## CPC

- C10B 21/10: Regulating and controlling the combustion
- C01B 3/26: using catalysts
- C10J 3/18: using electricity
- C10J 3/84: with means for removing dust or tar from the gas
- C01B 2203/0277: containing a catalytic decomposition step
- C01B 2203/0861: by plasma
- C10J 2300/0916: Biomass
- C10J 2300/0946: Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
- C10J 2300/0969: Carbon dioxide
- C10J 2300/0976: as steam
- C10J 2300/0993: Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
- C10J 2300/1238: by plasma
- C10J 2300/1246: by external or indirect heating
- C10J 2300/1631: Ash recycling
- C10J 2300/1637: Char combustion
- C10J 2300/1807: Recycle loops, e.g. gas, solids, heating medium, water
- Y02P 20/133: Renewable energy sources, e.g. sunlight
- Y02P 20/145: the feedstock being materials of biological origin
- C10B: DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS (cracking oils C10G; underground gasification of minerals E21B43/295)
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- C10J: PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES (synthesis gas from liquid or gaseous hydrocarbons C01B; underground gasification of minerals E21B43/295); CARBURETTING AIR OR OTHER GASES
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A gasifier including a vertically disposed furnace body, a feeder disposed in a middle part of the furnace body and communicating with the furnace body, one or two layers of microwave plasma generators, an external heater configured to supply external thermal energy for the gasifier, and a monitoring unit. The furnace body includes an upper nozzle for spraying vapor, a lower nozzle for spraying CO2/vapor, a syngas outlet disposed at a top of the furnace body. The upper nozzle for spraying vapor is disposed in a clearance zone of the furnace body, and the lower nozzle for spraying CO2/vapor is disposed in a bed zone of the furnace body. The monitoring unit is disposed close to the syngas outlet. The one or two layers of microwave plasma generators are disposed above the upper nozzle in the clearance zone of the gasifier.

## Claims

### Claim 1

A gasifier, comprising:
a vertically disposed furnace body, the furnace body comprising an upper nozzle for spraying vapor, a lower nozzle for spraying CO2/vapor, and a syngas outlet disposed at the top of the furnace body, the lower nozzle comprising a nozzle opening;
bed materials;
a feeder, the feeder being disposed in the middle part of the furnace body and communicating with the furnace body;
one or two layers of microwave plasma generators;
an external heater configured to supply external thermal energy for the gasifier;
a circulating material outlet;
a circulating material inlet; and
a monitoring unit;
wherein
the upper nozzle is disposed in a clearance zone of the furnace body;
the lower nozzle and the bed materials are disposed at the bottom of the furnace body;
the nozzle opening is disposed toward the bed materials;
the monitoring unit is disposed in a close proximity to the syngas outlet;
the one or two layers of microwave plasma generators are disposed above the upper nozzle in the clearance zone of the gasifier, each layer of the microwave plasma generators comprises three or four working gas inlets, the microwave plasma generators are adapted to spray plasma into the clearance zone of the gasifier horizontally/tangentially;
the external heater is separated from the furnace body;
the circulating material outlet is disposed at the bottom of the furnace body and the circulating material inlet is disposed at the top of the furnace body, or the circulating material outlet and the circulating material inlet are both disposed at a sidewall of the furnace body;
the external heater is disposed between the circulating material outlet and the circulating material inlet;
when in use, circulating materials are transferred through the circulating material outlet to the external heater and then back to the furnace body via the circulating material inlet; and
the external heater comprises a slag outlet for discharging slags.

### Claim 2 (depends on 1)

The gasifier of claim 1, wherein
a heat source of the external heater is microwave, microwave plasma, laser, plasma arc, solar energy, or a combination thereof.

### Claim 3 (depends on 1)

The gasifier of claim 1, wherein a microwave power source of the microwave plasma generators has a basic frequency of 2.45 GHz, and a power of a single microwave plasma generator is less than or equal to 200 kW.

### Claim 4 (depends on 2)

The gasifier of claim 2, wherein a microwave power source of the microwave plasma generators has a basic frequency of 2.45 GHz, and a power of a single microwave plasma generator is less than or equal to 200 kW.

### Claim 5 (depends on 1)

A method of gasification using a gasifier of claim 1, the method employing external thermal energy to gasify biomass fuel, and the method comprising the following steps:
1) introducing feedstock comprising biomass fuel and solid waste into the furnace body via the feeder, gasifying and pyrolyzing the feedstock in the bed zone to yield syngas comprising a large amount of CO, H2, CO2 and a small amount of CH4 and tar;
2) allowing the syngas to flow upward to the clearance zone of the gasifier, starting up the microwave plasma generators to generate plasma oxidizers having high activity, high degree of ionization in nonequilibrium state, so that the syngas mixes with the plasma oxidizers and cracks, spraying vapor into the furnace body from the upper nozzle, controlling the clearance zone at a temperature of between 1000 and 1200° C., regulating a flow rate of the plasma oxidizers to ensure the syngas to stay at a plasma atmosphere for between 3 and 10 seconds, agitating the plasma flow to strength the heat and mass transfer, and collecting a final syngas product from the syngas outlet disposed at the top of the furnace body;
3) spraying heated CO2 and vapor from the lower nozzle into the furnace body so that carbon residues in the bed zone are reduced or oxidized;
4) transporting unreacted carbon residues and bed materials to the external heater via the circulating material outlet, where the carbon residues are combusted, the bed materials are heated and separated from slags, and discharging the slags from the slag outlet;
5) returning the separated bed materials to the furnace body from the circulating material inlet, the bed materials flowing downward, exchanging heat with syngas flowing reversely, and releasing thermal energy in the bed zone to have a temperature of between 600 and 1000° C.; transporting the cooled bed materials to the external heater for heating again, and repeating the circulation for several times as needed; a temperature of the circulating material outlet being between 750 and 1200° C., and the temperature of the heated bed materials being higher than that in the bed zone; and
6) monitoring by the monitoring unit the temperature and components of the syngas, regulating CO2 flow rate, vapor flow rate, and microwave power to ensure the operation of the gasification.

### Claim 6 (depends on 5)

The method of claim 5, wherein in step 2), a retention time of the syngas staying at the plasma atmosphere in the clearance zone is between 3 and 6 seconds.

### Claim 7 (depends on 6)

The method of claim 6, wherein in step 2), a retention time of the syngas staying at the plasma atmosphere in the clearance zone is between 4 and 6 seconds.

### Claim 8 (depends on 7)

The method of claim 7, wherein a reaction temperature in the bed zone of the gasifier is controlled at between 600 and 850° C.

### Claim 9 (depends on 1)

A method of gasification using a gasifier of claim 1, the method employing external thermal energy to gasify biomass fuel, and the method comprising the following steps:
1) introducing feedstock comprising biomass fuel and solid waste into the furnace body via the feeder, gasifying and pyrolyzing the feedstock in the bed zone to yield syngas comprising a large amount of CO, H2, CO2 and a small amount of CH4 and tar;
2) allowing the syngas to flow upward to the clearance zone of the gasifier, starting up the microwave plasma generators to generate plasma oxidizers having high activity, high degree of ionization in nonequilibrium state, so that the syngas mixes with the plasma oxidizers and cracks, spraying vapor into the furnace body from the upper nozzle, controlling the clearance zone at a temperature of between 1000 and 1200° C., regulating a flow rate of the plasma oxidizers to ensure the syngas to stay at a plasma atmosphere for between 3 and 10 seconds, agitating the plasma flow to strength the heat and mass transfer, and collecting a final syngas product from the syngas outlet disposed at the top of the furnace body;
3) heating the gasifier by the external heater disposed at the bottom of the gasifier to maintain a temperature in the bed zone to be between 600 and 1000° C., and a temperature in clearance zone to be between 750 and 1600° C.; and
4) monitoring by the monitoring unit the temperature and components of the syngas, regulating CO2 flow rate, vapor flow rate, and microwave power to ensure the operation of the gasification, and controlling a temperature of the syngas outlet to be between 750 and 1200° C.