# US 10,118,426 B2 · Nanoporous stamp for flexographic printing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,118,426 B2 - Document ID: US10118426B2 - Status: Granted - Kind: B2 - Application number: 14/951,854 - Filed: 2015-11-25 - Published: 2016-06-02 - Granted: 2018-11-06 - Earliest claimed: 2014-11-25 - Assignees: Massachusetts Institute of Technology - Applicants: Massachusetts Institute of Technology - Inventors: Anastasios John Hart; Sanha Kim; Hossein Sojoudi; Karen K. Gleason - Web page: https://patentgrep.com/patent/US10118426B2 ## CPC - B41K 3/62: Details or accessories - B41C 1/00: Forme preparation - B41F 5/24: for flexographic printing - B41M 1/04: Flexographic printing - G03F 7/0002: {Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping} - G03F 7/0015: {Production of aperture devices, microporous systems or stamps} - B41C 1/05: Heat-generating engraving heads, e.g. laser beam, electron beam - B41N 1/12: non-metallic other than stone {, e.g. printing plates or foils comprising inorganic materials in an organic matrix (B41N1/003, B41N1/006 take precedence)} - B41K: STAMPS; STAMPING OR NUMBERING APPARATUS OR DEVICES (marking meat A22C17/10; embossing combined with printing B41F19/00; selective printing mechanisms B41J; embossing decorations or marks B44B5/00; marking or coding completed packages B65B61/26; ticket printing and issuing, fare registering, nonprinting aspects of franking apparatus G07B) - B41C: PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES (photomechanical processes for producing printing surfaces G03F; photoelectrical processes for producing printing surfaces G03G) - B41F: PRINTING MACHINES OR PRESSES (manifolding devices or office printing machines B41L) - B41M: PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING, (correction of typographical errors B41J; processes for applying transfer pictures or the like B44C1/16; fluid media for correction of typographical errors by coating C09D10/00; printing textiles D06P) - G03F: PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR; (phototypographic composing devices B41B; photosensitive materials or processes for photographic purposes G03C; electrophotography, sensitive layers or processes therefor G03G) - B41N: PRINTING PLATES OR FOILS (photosensitive material G03); MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM ## Abstract A nanoporous stamp for printing a variety of materials is disclosed. The nanoporous stamp may include a substrate and an array of carbon nanotubes disposed on and attached to the substrate. The array of carbon nanotubes can have an etched top surface and a wettable, nanoporous structure, and may include a coating thereon. The nanoporous stamp can be used in a variety of printing applications, and can print, among other things, colloidal and non-colloidal inks on a variety of substrates with a high degree of accuracy and fidelity. ## Claims ### Claim 1 A method of flexographic nanoporous stamp printing, the method comprising: loading a patterned nanoporous stamp with ink, the patterned nanoporous stamp having a plurality of micro-scale features, wherein during the loading, ink is drawn into microstructures via capillary wicking; contacting the loaded patterned nanoporous stamp with a nanoporous scour to remove excess ink from the patterned nanoporous stamp; and printing a pattern on a target substrate with the loaded patterned nanoporous stamp by conformally contacting the patterned nanoporous stamp to the target substrate to form nanoscale contact points between the target substrate and the plurality of micro-scale features of the nanoporous stamp such that ink is drawn out of the microstructures and onto the target substrate, wherein loading the patterned nanoporous stamp with the ink includes loading the ink into each micro-scale feature in the plurality of micro-scale features, each micro-scale feature including a plurality of carbon nanotubes disposed on and attached to a substrate. ### Claim 2 (depends on 1) The method of claim 1, wherein the printing includes applying pressure during printing such that printed features of the pattern on the target substrate substantially match the plurality of micro-scale features of the patterned nanoporous stamp. ### Claim 3 (depends on 1) The method of claim 1, wherein the pressure applied is greater than about 0.5 kPa and less than about 200 kPa. ### Claim 4 (depends on 1) The method of claim 1, wherein the ink comprises a solvent having a surface tension less than 100 mN/m. ### Claim 5 (depends on 1) The method of claim 1, wherein the ink is a colloidal ink comprising functional nanoparticles. ### Claim 6 (depends on 5) The method of claim 5, wherein average pore size of the patterned nanoporous stamp is (a) substantially larger than the average size of the functional nanoparticles of the ink, and (b) smaller than the micro-scale features. ### Claim 7 (depends on 1) The method of claim 1, wherein at least a portion of printed features of the pattern on the target substrate have an average line edge roughness of less than 2 μm. ### Claim 8 (depends on 1) The method of claim 1, wherein at least a portion of the printed features of the pattern on the target substrate have a linewidth less than 10 μm. ### Claim 9 (depends on 1) The method of claim 1, wherein at least a portion of the printed features of the pattern on the target substrate have an average thickness of less than 100 nm. ### Claim 10 (depends on 1) The method of claim 1, wherein the printed features of the pattern on the target substrate have a substantially uniform thickness with a tolerance less than 20 nm. ### Claim 11 (depends on 1) The method of claim 1, wherein the nanoporous scour is an unpatterned nanoporous stamp. ### Claim 12 (depends on 1) The method of claim 1, wherein the average porosity of the nanoporous stamp is substantially the same as the average porosity of the nanoporous scour. ### Claim 13 A method, comprising: printing using a nanoporous print stamp, wherein the nanoporous print stamp is configured for flexographic printing and comprises: a substrate; a patterned arrangement of carbon nanotubes disposed on and attached to the substrate, the arrangement of carbon nanotubes having a top surface having an average pore size of 100 nm or less, and a wettable, nanoporous structure; and a secondary material disposed on the carbon nanotubes whereby the secondary material adjoins at least portions of the carbon nanotubes and is configured to reduced capillary-induced deformation of the arrangement of carbon nanotubes when in use, the printing including: loading the nanoporous print stamp with ink such that ink is drawn into microstructures of the patterned arrangement of carbon nanotubes via capillary wicking; contacting the nanoporous print stamp to a non-porous roller such that ink from the nanoporous print stamp drawn out of microstructures of the patterned arrangement of carbon nanotubes and transferred to the non-porous roller; and contacting the non-porous roller to a target substrate such that the ink is printed on the target substrate by the non-porous roller. ### Claim 14 (depends on 1) The method of claim 1, wherein the plurality of carbon nanotubes defines an average pore size of about 100 nm or less. ### Claim 15 (depends on 1) The method of claim 1, further comprising: reducing capillary-induced deformation of the plurality of carbon nanotubes during loading the ink using a second material disposed on the plurality of carbon nanotubes, the secondary material adjoining at least portions of the carbon nanotubes. ### Claim 16 (depends on 1) The method of claim 1, wherein loading the patterned nanoporous stamp with the ink includes: contacting a top surface of the plurality of carbon nanotubes with the ink so as to draw the ink into each micro-scale feature via capillary wicking. ### Claim 17 (depends on 1) The method of claim 1, wherein the plurality of carbon nanotubes is at least partially oriented substantially perpendicular to the substrate surface.