# US 10,118,129 B2 · Natural-gas purification apparatus

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 10,118,129 B2
- Document ID: US10118129B2
- Status: Granted
- Kind: B2
- Application number: 15/475,974
- Filed: 2017-03-31
- Published: 2018-10-04
- Granted: 2018-11-06
- Earliest claimed: 2017-03-31
- Assignees: Mitsubishi Heavy Industries, Ltd.
- Applicants: Mitsubishi Heavy Industries, Ltd.
- Inventors: Masayuki Eda; Wataru Matsubara; Shintaro Honjo; Susumu Okino; Hiromi Nakatani; Masaki Yushima
- Web page: https://patentgrep.com/patent/US10118129B2

## CPC

- F25J 3/08: Separating gaseous impurities from gases or gaseous mixtures {or from liquefied gases or liquefied gaseous mixtures}(cold traps B01D8/00)
- B01D 53/002: {by condensation}
- B01D 53/226: {in serial connexion}
- B01D 53/229: {Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)}
- B01D 53/30: Controlling by gas-analysis apparatus (regulating non electrical variables in general G05D)
- C10L 3/101: {Removal of contaminants}
- C10L 3/104: {Carbon dioxide}
- B01D 2053/221: {Devices}
- B01D 2256/24: Hydrocarbons
- B01D 2257/504: Carbon dioxide
- C10L 2290/06: Heat exchange, direct or indirect
- C10L 2290/548: Membrane- or permeation-treatment for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L 2290/58: Control or regulation of the fuel preparation of upgrading process
- C10L 2290/60: Measuring or analysing fractions, components or impurities or process conditions during preparation or upgrading of a fuel
- F25J 2205/02: using simple phase separation in a vessel or drum
- F25J 2205/80: using membrane, i.e. including a permeation step
- F25J 2210/60: Natural gas or synthetic natural gas [SNG]
- F25J 2210/80: Carbon dioxide
- F25J 2215/04: Recovery of liquid products
- F25J 2215/64: Propane or propylene
- F25J 2215/66: Butane or mixed butanes
- F25J 2220/66: Separating acid gases, e.g. CO2, SO2, H2S or RSH
- F25J 2230/30: Compression of the feed stream
- F25J 2230/60: the fluid being hydrocarbons or a mixture of hydrocarbons
- F25J 2280/50: Advanced process control, e.g. adaptive or multivariable control
- Y02C 20/40: of CO2
- F25J: LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS {OR LIQUEFIED GASEOUS} MIXTURES BY PRESSURE AND COLD TREATMENT {OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE (cryogenic pumps F04B37/08; gas storage vessels, gas holders F17; filing vessels with, or discharging from vessels, compressed, liquefied or solidified gases F17C; refrigeration machines, plants, or systems F25B)}
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- Y02C: CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]

## Abstract

A natural-gas purification apparatus includes: a compressor; a cooling unit that liquefies and separates a part of natural-gas liquid; a heating unit; first to third carbon-dioxide separation units that separate carbon dioxide through carbon-dioxide separation membranes; a detection carbon-dioxide separation unit that further separates carbon dioxide through a carbon-dioxide separation membrane; a carbon-dioxide-flow-rate sensor that detects the amount of carbon dioxide separated by the detection carbon-dioxide separation unit; an arithmetic control device that adjusts and controls at least one of the pressure to be applied by the compressor, the cooling temperature of the cooling unit, and the heating temperature of the heat unit based on information from the carbon-dioxide-flow-rate sensor such that the amount of carbon dioxide to be separated by the detection carbon-dioxide separation unit will be higher than or equal to a prescribed amount.

## Claims

### Claim 1

A natural-gas purification apparatus for purifying natural gas from ground by separating carbon dioxide from the natural gas, comprising:
a pressure adjuster that adjusts a pressure of the natural gas from the ground;
a natural-gas-liquid separator that liquefies and separates a part of natural-gas liquid by cooling the natural gas after the pressure adjustment by the pressure adjuster;
a heater that heats the natural gas after the separation of the part of the natural-gas liquid by the natural-gas-liquid separator;
a carbon-dioxide separator that separates carbon dioxide from the natural gas heated by the heater through a carbon-dioxide separation membrane;
a detection carbon-dioxide separator that further separates carbon dioxide from purified gas obtained as a result of the carbon-dioxide separation by the carbon-dioxide separator through a carbon-dioxide separation membrane;
a carbon-dioxide-amount detector that detects an amount of carbon dioxide separated by the detection carbon-dioxide separator; and
a controller that adjusts and controls at least one of:
a pressure of the natural gas to be achieved by the pressure adjuster,
a temperature to which the natural gas is to be cooled by the natural-gas-liquid separator, and
a temperature to which the natural gas is to be heated by the heater based on information from the carbon-dioxide-amount detector such that the amount of carbon dioxide to be separated by the detection carbon-dioxide separator is higher than or equal to a prescribed amount.

### Claim 2 (depends on 1)

The natural-gas purification apparatus according to claim 1, wherein the controller controls actuation of the heater so as to raise a heating temperature of the heater if a detected amount Cd detected by the carbon-dioxide-amount detector is lower than a prescribed amount Cs which has been determined and inputted in advance (Cd<Cs).

### Claim 3 (depends on 2)

The natural-gas purification apparatus according to claim 2, wherein the controller controls the actuation of the heater so as to shift the heating temperature of the heater to an initial heating temperature if the detected amount Cd reaches or exceeds the prescribed amount Cs (Cd≥Cs).

### Claim 4 (depends on 2)

The natural-gas purification apparatus according to claim 2, wherein the controller controls actuation of the natural-gas-liquid separator so as to lower a cooling temperature of the natural-gas-liquid separator if the heating temperature of the heater reaches a limit value without the detected amount Cd reaching or exceeding the prescribed amount Cs.

### Claim 5 (depends on 4)

The natural-gas purification apparatus according to claim 4, wherein the controller controls the actuation of the natural-gas-liquid separator so as to shift the cooling temperature of the natural-gas-liquid separator to an initial cooling temperature if the detected amount Cd reaches or exceeds the prescribed amount Cs (Cd≥Cs).

### Claim 6 (depends on 4)

The natural-gas purification apparatus according to claim 4, wherein the controller controls actuation of the pressure adjuster so as to lower a pressure to be applied by the pressure adjuster if the cooling temperature of the natural-gas-liquid separator reaches a limit value without the detected amount Cd reaching or exceeding the prescribed amount Cs.

### Claim 7 (depends on 6)

The natural-gas purification apparatus according to claim 6, wherein the controller controls the actuation of the pressure adjuster so as to shift the pressure to be applied by the pressure adjuster to an initial pressure if the detected amount Cd reaches or exceeds the prescribed amount Cs (Cd≥Cs).

### Claim 8 (depends on 1)

The natural-gas purification apparatus according to claim 1, wherein
the natural-gas purification apparatus comprises a plurality of the detection carbon-dioxide separators and a plurality of the carbon-dioxide-amount detectors,
the natural-gas purification apparatus further comprises a flow-path switcher that switches a flow path of purified gas from the carbon-dioxide separator such that the purified gas from the carbon-dioxide separator is supplied to one of the plurality of detection carbon-dioxide separators, and
if the amount of carbon dioxide separated by one of the detection carbon-dioxide separators to which the purified gas from the carbon-dioxide separator is being supplied falls below a prescribed amount, the controller controls switching of the flow-path switcher based on information from the corresponding one of the carbon-dioxide-amount detectors so as to supply the purified gas from the carbon-dioxide separator to another one of the detection carbon-dioxide separators.

### Claim 9 (depends on 8)

The natural-gas purification apparatus according to claim 8, further comprising a restoration heater capable of heating each of the carbon-dioxide separation membranes of the plurality of detection carbon-dioxide separators,
wherein when controlling the switching of the flow-path switcher so as to supply the purified gas from the carbon-dioxide separator to the other one of the detection carbon-dioxide separators, the controller simultaneously controls actuation of the restoration heater so as to heat the carbon-dioxide separation membrane of the one of the detection carbon-dioxide separators with which the amount of carbon dioxide separated has fallen below the prescribed amount.

### Claim 10 (depends on 9)

The natural-gas purification apparatus according to claim 9, wherein
when controlling the switching of the flow-path switcher so as to supply the purified gas from the carbon-dioxide separator to the one of the detection carbon-dioxide separators whose carbon-dioxide separation membrane is being heated by the restoration heater, the controller simultaneously controls the actuation of the restoration heater so as to stop the heating of the carbon-dioxide separation membrane of the one of the detection carbon-dioxide separators.