Functionalized ketone-aldehyde condensation resins
AssigneeEvonik Degussa GmbH
InventorsChristoph Juergen Duerr, Bettina Burian, Daniel Engelke, Michael Ewald, Tanja Joerres, Erika Retzlaff
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Abstract
A functionalized ketone-aldehyde condensation resin is produced by condensing a ketone and an aldehyde in the presence of at least one alcohol or alkoxylate thereof, wherein the alcohol comprises amino alcohols and derivatives thereof, hydroxybutyl vinyl ether, OH-functional acrylates, OH-functional terpenes, OH-functional halogen compounds, hydroxycarboxylic acids, sulphur-containing alcohols, hydroxyl-containing urea derivatives, carbohydrates, siloxanes, OH-functional phosphorus compounds or unsaturated alcohols.
Claims11
A process for preparing a functionalized resin, comprising:
- condensing a ketone selected from the group consisting of:
- acetone;
- acetophenone;
- ortho-, meta- or para-phenylacetophenone;
- methyl ethyl ketone;
- 3-pentanone;
- 2-heptanone;
- 3-heptanone;
- 4-heptanone;
- 2-octanone;
- 3-octanone;
- 2-undecanone;
- 5-methylhexan-2-one;
- 4-methylpentan-2-one;
- cyclopentanone;
- cyclododecanone;
- mixtures of 2,2,4- and 2,4,4-trimethylcyclopentanone;
- cycloheptanone;
- cyclooctanone;
- cyclohexanone;
- o-, m- or p-methoxyacetophenone;
- o-, m- or p-[N,N-dialkylaminophenyl]ethanone;
- alkyl-substituted cyclohexanones or diones or mixtures thereof
- and an aldehyde in the presence of at least one amino alcohol selected from the group consisting of:
- N,N-dimethylaminoethanol, trimethylaminoethylethanolamine, 3-dimethylaminopropan-1-ol, butyldiethanolamine, butylethanolamine, dibutylethanolamine, diethylethanolamine, ethylethanolamine, dimethylaminoethoxyethanol, methyldiethanolamine, N,N-dimethylisopropanolamine, N-methylethanolamine, diethanolamine, diisopropanolamine, triisopropanolamine, N-(2-hydroxyethyl)piperidine, diisopropanol-p-toluidine, N,N-di(2-hydroxyethyl)aniline, N-(2-hydroxyethyl)aniline, 2-(2-aminoethoxy)ethanol, 3-amino-1-propanol, 5-amino-1-pentanol, monoethanolamine, N-(2-aminoethyl)ethanolamine, isopropanolamine, 2,2′-(phenylamino)diethanol, 1-(2-hydroxyethyl)piperazine, 4-(2-hydroxyethyl)morpholine, or derivatives or mixtures thereof,
- wherein said aldehyde used is a 20% to 40% by weight aqueous formaldehyde solution, said amino alcohol is incorporated covalently into said resin and said condensation is conducted in situ.
Dependencies are inferred from the claim text.