Extra-fine fiber sheet
AssigneeKuraray Co., Ltd.
InventorsTakayoshi Hosoya, Tomohiro Hayakawa, Hiroyuki Kawai, Hideo Hayashi
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Abstract
Provided is an extra-fine fiber sheet including an extra-fine fiber assembly including extra-fine fibers having an average fiber diameter of 500 nm or smaller. The extra-fine fiber sheet includes an extra-fine fiber assembly. The assembly includes a solvent-spinnable polymer (A) having a weight average molecular weight of 5,000 to 100,000 as a main component and a polymer (B) having a weight average molecular weight equal to or more than 10 times as large as that of the polymer (A) as an accessory component; and the assembly includes constituent fibers having an average fiber diameter of 10 to 500 nm. The polymer (A) may be a non-conductive polymer, and the polymer (B) may be a thickening polymer.
Claims13
An extra-fine fiber sheet comprising an extra-fine fiber assembly, wherein the assembly includes a solvent-spinnable polymer (A) having a weight average molecular weight of 5,000 to 100,000 as a main component and a polymer (B) having a weight average molecular weight equal to or more than 10 times as large as that of the polymer (A) as an accessory component;
- the polymer (A) is (i) an ethylene-vinyl alcohol copolymer or (ii) a polyamide including a 1,9-nonanediamine unit, a 2-methyl-1,8-octanediamine unit or both, as a diamine unit;
- the polymer (B) is a polyethylene oxide, a polyethylene glycol or a polyacrylamide;
- the sheet has a composition ratio of the polymer (A) to the polymer (B) of (A):(B)=10:1 to 10,000:1;
- the assembly comprises constituent fibers having an average fiber diameter of 10 to 500 nm;
- and
- the assembly has 5 or fewer beads generated per 100 μm2 on a cross section of the extra-fine fiber assembly photographed at a magnification of 5,000, and the beads are unfiberized particulate material having a size equal to or greater than 5 times as large as the average fiber diameter.
An extra-fine fiber sheet comprising an extra-fine fiber assembly, wherein the assembly consists essentially of:
- a solvent-spinnable polymer (A) having a weight average molecular weight of 5,000 to 100,000 as a main component;
- a polymer (B) having a weight average molecular weight equal to or more than 10 times as large as that of the polymer (A) as an accessory component;
- and
- optionally one or more additives selected from the group consisting of a plasticizer, an antioxidant, a slip additive, an ultraviolet absorber, a light stabilizer, an antistatic agent, a flame retardant, a lubricant, a crystallization speed retarder, and a colorant;
- wherein:
- the polymer (A) is (i) an ethylene-vinyl alcohol copolymer or (ii) a polyamide including a 1,9-nonanediamine unit, a 2-methyl-1,8-octanediamine unit or both, as a diamine unit;
- the polymer (B) is a polyethylene oxide, a polyethylene glycol or a polyacrylamide;
- the sheet has a composition ratio of the polymer (A) to the polymer (B) of (A):(B)=10:1 to 10,000:1;
- the assembly comprises constituent fibers having an average fiber diameter of 10 to 500 nm;
- and
- the assembly has 5 or fewer beads generated per 100 μm2 on a cross section of the extra-fine fiber assembly photographed at a magnification of 5,000, and the beads are unfiberized particulate material having a size equal to or greater than 5 times as large as the average fiber diameter.
Dependencies are inferred from the claim text.