Method of reducing sulfur dioxide content in flue gas emanating from a circulating fluidized bed boiler plant
AssigneeSumitomo SHI FW Energia Oy
InventorAntti Rokka
Life of this patent
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Abstract
A method of reducing sulfur dioxide emissions of a circulating fluidized bed boiler plant. A first stream of sulfur-containing carbonaceous fuel is fed at a first feeding rate to a furnace of the boiler. A second stream of calcium carbonate containing absorbent having a predetermined d50 particle size is fed at a second feeding rate to the furnace. Oxygen containing gas is fed to the furnace for fluidizing a bed of particles forming in the furnace. Fuel is combusted with the oxygen and the sulfur in the fuel is oxidized to sulfur dioxide. The calcium carbonate is calcined to calcium oxide in the furnace. A portion of the calcium oxide is used to sulfate a first portion of the sulfur dioxide to calcium sulfate in the furnace.
Claims13
A method of reducing sulfur dioxide emissions of a circulating fluidized bed boiler plant, the method comprising the steps of:
- feeding a first stream of sulfur-containing carbonaceous fuel at a first feeding rate to a furnace of the boiler;
- feeding a second stream of calcium carbonate containing absorbent having a predetermined d50 particle size at a second feeding rate to the furnace;
- feeding oxygen containing gas to the furnace for fluidizing a bed of particles forming in the furnace;
- combusting the fuel with the oxygen, whereby the sulfur in the fuel is oxidized to sulfur dioxide;
- calcining the calcium carbonate to calcium oxide in the furnace and utilizing a portion of the calcium oxide to sulfate a first portion of the sulfur dioxide to calcium sulfate in the furnace;
- discharging flue gases, containing a second portion of the sulfur dioxide, and particles, including calcium oxide particles, entrained with the flue gases along a flue gas channel from the furnace;
- separating a first portion of the entrained particles, including a first portion of the entrained calcium oxide particles, from the flue gases in a particle separator having a cut-off size, and returning at least a portion of the separated particles via a return duct to the furnace;
- conveying a second portion of the entrained particles, including a second portion of the entrained calcium oxide particles, with the flue gases from the furnace to a semi-dry sulfur-reduction stage arranged downstream of the furnace;
- and
- reducing the sulfur dioxide content of the flue gases in the semi-dry sulfur-reduction stage,
- wherein the predetermined d50 particle size of the calcium carbonate containing absorbent is from 10 μm to 20 μm, and smaller than 50% of the cut-off size of the particle separator.
Dependencies are inferred from the claim text.